Updated on 2025/06/13

写真a

 
Yamakata Akira
 
Organization
Scheduled update Professor
Position
Professor
External link

Degree

  • 博士 ( 理学 )

Research Interests

  • 化学反応ダイナミクス

  • 触媒化学

  • 光触媒

  • 表面化学

  • 超高速赤外分光

  • Photocatalyst

  • surface dynamics

  • surface spectroscopy

Research Areas

  • Nanotechnology/Materials / Functional solid state chemistry

  • Nanotechnology/Materials / Analytical chemistry

  • Nanotechnology/Materials / Fundamental physical chemistry

Education

  • Tokyo Institute of Technology   大学院総合理工学研究科電子化学専攻博士後期課程  

    1996.4 - 1999.3

      More details

  • Tokyo Institute of Technology   大学院総合理工学研究科   電子化学専攻修士課程

    1994.4 - 1996.3

      More details

    Country: Japan

    researchmap

  • Tokyo University of Science   理学部   第一部・応用化学科

    1990.4 - 1994.3

      More details

    Country: Japan

    researchmap

Research History

  • Okayama University   The Graduate School of Natural Science and Technology   Professor

    2022.4

      More details

  • JST/PRESTO

    2011.10 - 2017.3

      More details

  • Toyota Technological Institute   Graduate School of Engineering   Associate Professor

    2010.8 - 2022.3

      More details

  • Department of Chemical Physics of Fritz-Haber-Institut der・派遣研究員(兼任)

    2006.6 - 2006.8

      More details

  • Hokkaido University   Catalysis Research Center   Assistant Professor

    2003.10 - 2010.8

      More details

  • (財)神奈川科学技術アカデミー・極限表面反応プロジェクト・研究員

    1999.4 - 2003.9

      More details

  • 日本学術振興会・特別研究員・DC2 研究員(研究場所:東京工業大学)

    1998.4 - 1999.3

      More details

▼display all

Professional Memberships

▼display all

Committee Memberships

  • J. Photochemistry and Photobiolgy C   Dupty Editor  

    2024.4   

      More details

    Committee type:Academic society

    researchmap

  • 触媒学会・西日本支部   代議員  

    2023.3   

      More details

  • 触媒学会「光触媒研究会」   世話人代表  

    2023.3   

      More details

    Committee type:Academic society

    researchmap

  • 日本化学会:資源・エネルギー・地球化学・核化学・放射化学 ディビジョン   主査  

    2022.3   

      More details

  • J. Photochemistry and Photobiolgy C   Associate Editor  

    2021.1 - 2024.3   

      More details

    Committee type:Academic society

    researchmap

  • The Chemical Society of Japan, Division of Energy   committee member  

    2020.3 - 2022.2   

      More details

    Committee type:Academic society

    researchmap

  • International Workshop on Crystalline Materials and Applications (IWCMA-2019)   Advisory Board  

    2019   

      More details

    Committee type:Academic society

    researchmap

  • International Conference on Photochemistry and Sustainable Energy (ICPSE 2019)   Advisory Board  

    2019   

      More details

    Committee type:Academic society

    researchmap

  • Meeting of Japanese Photochemical Association, 2019   committee member  

    2019   

      More details

    Committee type:Academic society

    researchmap

  • The 24th International Conference on Semiconductor Photocatalysis and Solar Energy Conversion (SPASEC-24)   Advisory Board  

    2019   

      More details

    Committee type:Academic society

    researchmap

  • The 22nd International Conference on Semiconductor Photocatalysis & Solar Energy Conversion (SPASEC-22)   Advisory Board  

    2017   

      More details

    Committee type:Academic society

    researchmap

  • International Conference on Photochemistry and Its Applications (ICPA 2017)   Advisory Board  

    2017   

      More details

    Committee type:Academic society

    researchmap

  • Catalysis Society of Japan, Board of Photocatalysis   committee member  

    2014.4   

      More details

    Committee type:Academic society

    researchmap

  • The Japan Society of Vacuum and Surface Science   committee member  

    2014.4   

      More details

    Committee type:Academic society

    researchmap

  • The Surface Science Society of Japan, Chubu-Branch   General affairs  

    2011.4 - 2014.3   

      More details

    Committee type:Academic society

    researchmap

  • Catalysis Society of Japan, Board of Surface Science   committee member  

    2009.4   

      More details

    Committee type:Academic society

    researchmap

  • Surface Spectroscopy 2009   executive committee  

    2009   

      More details

    Committee type:Other

    researchmap

  • The Electrochemical Society of Japan, Board of Nano-Surface   committee member  

    2004.4   

      More details

    Committee type:Academic society

    researchmap

  •   committee member  

    2004.4 - 2010.8   

      More details

▼display all

 

Papers

  • Molecular-Level Tailoring of Energy Structure in Ternary Conjugated Polymers with a Built-in Ru-Complex Catalyst for Efficient CO2 Reduction Photocatalysis

    Kotaro Ishihara, Akinobu Nakada, Hajime Suzuki, Akira Yamakata, Osamu Tomita, Akinori Saeki, Ryu Abe

    Journal of the American Chemical Society   2025.6

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jacs.5c04222

    researchmap

  • Designing and Understanding Biphasic TiO2 Composites for a Long-Lasting Photocatalytic Air Purification Reviewed

    Ulfi Muliane, Shi Nee Lou, Shinbi Lee, Fei He, Shen Zhao, Kosaku Kato, Akira Yamakata, Wonyong Choi

    ACS ES&T Engineering   2025.4

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsestengg.4c00738

    researchmap

  • Boosted Photocatalytic Water Oxidation over BaTaO2N Produced from Perovskite Oxides Based on Photoinduced Charge Carriers

    Junie Jhon M. Vequizo, Kosaku Kato, Shanshan Chen, Takashi Hisatomi, Zheng Wang, Tsuyoshi Takata, Akira Yamakata, Kazunari Domen

    Energy & Fuels   2025.4

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.energyfuels.4c06364

    researchmap

  • A meta-linked isomer of ITIC: influence of aggregation patterns on open-circuit voltage in organic solar cells

    Kai Wang, Seihou Jinnai, Kaito Uesaka, Akira Yamakata, Yutaka Ie

    Journal of Materials Chemistry A   2025

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D5TA00178A

    researchmap

  • Conduction Band and Defect Engineering for the Prominent Visible‐Light Responsive Photocatalysts Reviewed

    Akira Yamakata, Kosaku Kato, Takafumi Ogawa, Kanta Ogawa, Makoto Ogawa, Daichi Kato, Chengchao Zhong, Akihide Kuwabara, Ryu Abe, Hiroshi Kageyama

    Angewandte Chemie International Edition   2024.12

     More details

    Authorship:Lead author, Corresponding author   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    Controlling trap depth is crucial to improve photocatalytic activity, but designing such crystal structures has been challenging. In this study, we discovered that in 2D materials like BiOCl and Bi4NbO8Cl, composed of interleaved [Bi2O2]2+ and Cl‐ slabs, the trap depth can be controlled by manipulating the slab stacking structure. In BiOCl, oxygen vacancies (VO) create deep electron traps, while chlorine vacancies (VCl) produce shallow traps. The depth is determined by the coordination around anion vacancies: VO forms strong σ bonds with Bi‐6p dangling bonds below the conduction band minimum (CBM), while those around Cl are parallel, forming weak π‐bonding. The strong re‐hybridization makes the trap depth deeper. In Bi4NbO8Cl, VCl also creates shallow traps, but VO does not produce deep traps although Bi‐6p orbitals are also forming strong σ bonding. This difference is attributed to the difference of energy level of CBM. In both cases, CBM consists of Bi‐6p orbitals extending into the Cl layers. However, these orbitals are isolated in BiOCl, but those in Bi4NbO8Cl are bonded with each other between neighboring [Bi2O2]2+ layers. This unique bonding‐based CBM prevents the formation of deep electron traps, and significantly enhances H2 evolution activity by prolonging lifetime of highly reactive free electrons.

    DOI: 10.1002/anie.202419624

    researchmap

  • Zeolite-decorated black TiOx quantum dots for photocatalytic degradation of organic cationic dyes under LED light irradiation Reviewed

    Mohammad Rahim Pour, Mohammad Fereidooni, Supareak Praserthdam, Piyasan Praserthdam, Victor Marquez, Kaito Uesaka, Akira Yamakata, C.V. Paz, Nattawut kamjam, Pongsakorn kanjanaboos

    Journal of Alloys and Compounds   1008   176797 - 176797   2024.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.jallcom.2024.176797

    researchmap

  • Surface Modifications of Layered Perovskite Oxysulfide Photocatalyst Y2Ti2O5S2 to Enhance Visible‐Light‐Driven Water Splitting Reviewed

    Xizhuang Liang, Junie Jhon M. Vequizo, Lihua Lin, Xiaoping Tao, Qiulian Zhu, Mamiko Nakabayashi, Daling Lu, Hiroaki Yoshida, Akira Yamakata, Takashi Hisatomi, Tsuyoshi Takata, Kazunari Domen

    Advanced Science   2024.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    Abstract

    Increasing the efficiency of visible‐light‐driven water splitting systems will require improvements in the charge separation characteristics and redox reaction kinetics associated with narrow‐bandgap photocatalysts. Although the traditional approach of loading a single cocatalyst on selective facets provides reaction sites and reduces the reaction overpotential, pronounced surface charge carrier recombination still results in limited efficiency increases. The present study demonstrates a significant improvement in the hydrogen evolution activity of the layered single‐crystal photocatalyst Y2Ti2O5S2. Increased performance is obtained through sequential loading of Pt cocatalysts using a two‐step process followed by photodeposition of Cr2O3 nanolayers. The stepwise deposition of Pt involved an impregnation‐reduction pretreatment with subsequent photodeposition and produced numerous hydrogen production sites while promoting electron capture. The Cr2O3 shells formed on Pt nanoparticles further promoted electron transfer from the Pt to the water and inhibited surface carrier recombination. Importantly, it is also possible to construct a Z‐scheme overall water splitting system using the optimized Y2Ti2O5S2 in combination with surface‐modified BiVO4 in the presence of [Fe(CN)6]3−/4−, yielding a solar‐to‐hydrogen energy conversion efficiency of 0.19%. This work provides insights into precise surface modifications of narrow‐bandgap photocatalysts as a means of improving the solar water splitting process.

    DOI: 10.1002/advs.202412326

    researchmap

  • Simultaneous Structural and Electronic Engineering on Bi‐ and Rh‐co‐doped SrTiO3 for Promoting Photocatalytic Water Splitting Reviewed

    Zhenhua Pan, Junie Jhon M. Vequizo, Hiroaki Yoshida, Jianuo Li, Xiaoshan zheng, Chiheng Chu, Qian Wang, Mengdie Cai, Song Sun, Kenji Katayama, Akira Yamakata, Kazunari Domen

    Angewandte Chemie International Edition   2024.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    <jats:p>Activating metal ion‐doped oxides as visible‐light‐responsive photocatalysts requires intricate structural and electronic engineering, a task with inherent challenges. In this study, we employed a solid (template)‐molten (dopants) reaction to synthesize Bi‐ and Rh‐codoped SrTiO3 (SrTiO3:Bi,Rh) particles. Our investigation reveals that SrTiO3:Bi,Rh manifests as single‐crystalline particles in a core (undoped)/shell (doped) structure. Furthermore, it exhibits a well‐stabilized Rh3+ energy state for visible‐light response without introducing undesirable trapping states. This precisely engineered structure and electronic configuration promoted the generation of high‐concentration and long‐lived free electrons, as well as facilitated their transfer to cocatalysts for H2 evolution. Impressively, SrTiO3:Bi,Rh achieved an exceptional apparent quantum yield (AQY) of 18.9% at 420 nm, setting a new benchmark among Rh‐doped‐based SrTiO3 materials. Furthermore, when integrated into an all‐solid‐state Z‐scheme system with Mo‐doped BiVO4 and reduced graphene oxide, SrTiO3:Bi,Rh enabled water splitting with an AQY of 7.1% at 420 nm. This work underscores the significance of simultaneous structural and electronic engineering and introduces the solid‐molten reaction as a viable approach for this purpose.</jats:p>

    DOI: 10.1002/anie.202414628

    researchmap

  • Nonfullerene Acceptors Bearing Spiro-Substituted Bithiophene Units in Organic Solar Cells: Tuning the Frontier Molecular Orbital Distribution to Reduce Exciton Binding Energy. Reviewed International journal

    Kai Wang, Seihou Jinnai, Takumi Urakami, Hirofumi Sato, Masahiro Higashi, Sota Tsujimura, Yasuhiro Kobori, Rintaro Adachi, Akira Yamakata, Yutaka Ie

    Angewandte Chemie (International ed. in English)   e202412691   2024.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    The development of nonfullerene acceptors (NFAs), represented by ITIC, has contributed to improving the power conversion efficiency (PCE) of organic solar cells (OSCs). Although tuning the electronic structures to reduce the exciton binding energy (Eb) is considered to promote photocharge generation, a rational molecular design for NFAs has not been established. In this study, we designed and developed two ITIC-based NFAs bearing spiro-substituted bithiophene or biphenyl units (named SpiroT-DCI and SpiroF-DCI) to tune the frontier molecular orbital (FMO) distribution of NFAs. While the highest occupied molecular orbitals (HOMOs) of SpiroF-DCI and ITIC are delocalized in the main π-conjugated framework, the HOMO of SpiroT-DCI is distributed on the bithiophene unit. Reflecting this difference, SpiroT-DCI exhibits a smaller Eb than either SpiroF-DCI or ITIC, and exhibits greater external quantum efficiency in single-component OSCs. Furthermore, SpiroT-DCI shows improved PCEs for bulk-heterojunction OSCs with a donor of PBDB-T, compared with that of either SpiroT-DCI or ITIC. Time-resolved spectroscopy measurements show that the photo-induced intermolecular charge separation is effective even in pristine SpiroT-DCI films. This study highlights the introduction of spiro-substituted bithiophene units that are effective in tuning the FMOs of ITIC, which is desirable for reducing the Eb and improving the PCE in OSCs.

    DOI: 10.1002/anie.202412691

    PubMed

    researchmap

  • Development of Non-Fullerene Acceptors with π-Extended Central Unit for Organic Photovoltaic Devices Reviewed

    Tomokazu Umeyama, Motohisa Kubota, Haoxuan Zhang, Rintaro Adachi, Akira Yamakata, Tomoyuki Koganezawa, Hiroshi Imahori

    Journal of Photopolymer Science and Technology   37 ( 2 )   197 - 204   2024.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Technical Association of Photopolymers, Japan  

    DOI: 10.2494/photopolymer.37.197

    researchmap

  • Atomically dispersed low-valent Au boosts photocatalytic hydroxyl radical production Reviewed

    Zhenyuan Teng, Hongbin Yang, Qitao Zhang, Wenan Cai, Ying-Rui Lu, Kosaku Kato, Zhenzong Zhang, Jie Ding, Han Sun, Sixiao Liu, Chengyin Wang, Peng Chen, Akira Yamakata, Ting-Shan Chan, Chenliang Su, Teruhisa Ohno, Bin Liu

    Nature Chemistry   16 ( 8 )   1250 - 1260   2024.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Springer Science and Business Media LLC  

    DOI: 10.1038/s41557-024-01553-6

    Scopus

    researchmap

    Other Link: https://www.nature.com/articles/s41557-024-01553-6

  • Double‐Hollow Au@CdS Yolk@Shell Nanostructures as Superior Plasmonic Photocatalysts for Solar Hydrogen Production Reviewed

    Yi‐An Chen, Yuhi Nakayasu, Yu‐Chang Lin, Jui‐Cheng Kao, Kai‐Chi Hsiao, Quang‐Tuyen Le, Kao‐Der Chang, Ming‐Chung Wu, Jyh‐Pin Chou, Chun‐Wei Pao, Tso‐Fu Mark Chang, Masato Sone, Chun‐Yi Chen, Yu‐Chieh Lo, Yan‐Gu Lin, Akira Yamakata, Yung‐Jung Hsu

    Advanced Functional Materials   2024.6

     More details

    Authorship:Corresponding author   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    Abstract

    Structural engineering has proven effective in tailoring the photocatalytic properties of semiconductor nanostructures. In this work, a sophisticated double‐hollow yolk@shell nanostructure composed of a plasmonic, mobile, hollow Au nanosphere (HGN) yolk and a permeable, hollow CdS shell is proposed to achieve remarkable solar hydrogen production. The shell thickness of HGN@CdS is finely adjusted from 7.7, 18.4 to 24.5 nm to investigate its influence on the photocatalytic performance. Compared with pure HGN, pure CdS, a physical mixture of HGN and CdS, and a counterpart single‐hollow cit‐Au@CdS yolk@shell nanostructure, HGN@CdS exhibits superior hydrogen production under visible light illumination (λ = 400–700 nm). The apparent quantum yield of hydrogen production reaches 8.2% at 320 nm, 6.2% at 420 nm, and 4.4% at 660 nm. The plasmon‐enhanced activity at 660 nm is exceptional, surpassing the plasmon‐induced photoactivities of the state‐of‐the‐art plasmonic photocatalysts ever reported. The superiority of HGN@CdS originates from the creation of charge separation state at HGN/CdS heterojunction, the considerably long‐lived hot electrons of plasmonic HGN, the magnified electric field, and the advantageous features of double‐hollow yolk@shell nanostructures. The findings can provide a guideline for the rational design of versatile double‐hollow yolk@shell nanostructures for widespread photocatalytic applications.

    DOI: 10.1002/adfm.202402392

    researchmap

  • Carbon Nanotubes as a Solid-State Electron Mediator for Visible-Light-Driven Z-Scheme Overall Water Splitting Reviewed

    Lihua Lin, Yiwen Ma, Nobuyuki Zettsu, Junie Jhon M. Vequizo, Chen Gu, Akira Yamakata, Takashi Hisatomi, Tsuyoshi Takata, Kazunari Domen

    Journal of the American Chemical Society   146 ( 21 )   14829 - 14834   2024.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jacs.4c03437

    researchmap

  • Trapping of Intermediates of a Photocatalytic Oxygen Evolution Reaction in Overall Water Splitting Reviewed

    Fumiaki Amano, Satoshi Nakayama, Souta Suzuki, Akira Yamakata, Kosuke Beppu

    ACS Applied Energy Materials   2024.2

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsaem.3c03172

    researchmap

  • Double Hydrogen Atom Transfer Strategy for Catalytic Acceptorless Dehydrogenation of Cycloalkanes Reviewed

    Rahul Jagtap, Yuki Nishioka, Stephen Geddis, Yu Irie, Fuki Masaaki, Yasuhiro Kobori, Rintaro Adachi, Akira Yamakata, Harunobu Mitsunuma, Motomu Kanai

    2024.2

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    The advancement of an effective hydrogen liberation tech-nology from liquid organic hydrogen carriers (LOHCs), such as cyclohexane and methylcyclohexane (MCH), holds significance in realizing a hydrogen-centric society. However, the attainment of homogeneous catalytic acceptorless dehydrogenation (CAD) characterized by elevated selectivity for thorough aromatization under mild conditions remains unrealized. In this study, a catalyst system, facilitated by a double hydrogen atom transfer (HAT) processes, has been devised for the CAD of inert cycloalkanes at ambient temperature under visible light irradiation. Through the synergistic utilization of tetrabutylammonium chloride (TBACl) and thiophosphoric acid (TPA) HAT catalysts, successful CAD with comprehensive aromatization has been accomplished with high functional group tolerance.

    DOI: 10.26434/chemrxiv-2024-s5n5v

    researchmap

  • Suppression of Charge Recombination by Vertical Arrangement of A Donor Moiety on Flat Planar Dyes for Efficient Dye‐Sensitized Solar Cells Reviewed

    Qi Guo, Tomohiro Higashino, Rintaro Adachi, Chayanit Wechwithayakhlung, Daniel Packwood, Akira Yamakata, Hiroshi Imahori

    ChemSusChem   17 ( 9 )   2024.1

     More details

    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    Abstract

    In dye‐sensitized solar cells (DSSCs), flat planar dyes (e. g., highly light‐harvesting porphyrins and corroles) with multiple anchoring groups are known to adopt a horizontal orientation on TiO2 through the multiple binding to TiO2. Due to the strong electronic coupling between the dye and TiO2, fast charge recombination between the oxidized dye and an electron in TiO2 occurs, lowering the power conversion efficiency (η). To overcome this situation, an additional donor moiety can be placed on top of the planar dye on TiO2 to slow down the undesirable charge recombination. Here we report the synthesis and photovoltaic properties of a triarylamine (TAA)‐tethered gold(III) corrole (TAA‐AuCor). The DSSC with TAA‐AuCor using iodine redox shuttle exhibited the highest η‐value among corrole‐based DSSCs, which is much higher than that with the reference AuCor. The transient absorption spectroscopies clearly demonstrated that fast electron transfer from the TAA moiety to the corrole radical cation in TAA‐AuCor competes with the undesirable charge recombination to generate long‐lived charge separated state TAA⋅+‐Cor/TiO2 efficiently. Consequently, the introduction of the TAA moiety enhanced the η‐value remarkably, demonstrating the usefulness of our new concept to manipulate charge‐separated states toward highly efficient DSSCs.

    DOI: 10.1002/cssc.202301661

    researchmap

  • Efficient and stable visible-light-driven Z-scheme overall water splitting using an oxysulfide H2 evolution photocatalyst Reviewed

    Lihua Lin, Yiwen Ma, Junie Jhon M. Vequizo, Mamiko Nakabayashi, Chen Gu, Xiaoping Tao, Hiroaki Yoshida, Yuriy Pihosh, Yuta Nishina, Akira Yamakata, Naoya Shibata, Takashi Hisatomi, Tsuyoshi Takata, Kazunari Domen

    Nature Communications   15 ( 1 )   2024.1

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Springer Science and Business Media LLC  

    Abstract

    So-called Z-scheme systems permit overall water splitting using narrow-bandgap photocatalysts. To boost the performance of such systems, it is necessary to enhance the intrinsic activities of the hydrogen evolution photocatalyst and oxygen evolution photocatalyst, promote electron transfer from the oxygen evolution photocatalyst to the hydrogen evolution photocatalyst, and suppress back reactions. The present work develop a high-performance oxysulfide photocatalyst, Sm2Ti2O5S2, as an hydrogen evolution photocatalyst for use in a Z-scheme overall water splitting system in combination with BiVO4 as the oxygen evolution photocatalyst and reduced graphene oxide as the solid-state electron mediator. After surface modifications of the photocatalysts to promote charge separation and redox reactions, this system is able to split water into hydrogen and oxygen for more than 100 hours with a solar-to-hydrogen energy conversion efficiency of 0.22%. In contrast to many existing photocatalytic systems, the water splitting activity of the present system is only minimally reduced by increasing the background pressure to 90 kPa. These results suggest characteristics suitable for applications under practical operating conditions.

    DOI: 10.1038/s41467-024-44706-4

    researchmap

    Other Link: https://www.nature.com/articles/s41467-024-44706-4

  • An efficient particulate photocatalyst for overall water splitting based on scandium and magnesium co-doped strontium titanate Reviewed

    Shigeru Ikeda, Riku Okamoto, Akira Kimura, Yuhi Nakayasu, Akira Yamakata, Ryota Tomizawa, Taizo Masuda, Koichiro Nakatani

    Sustainable Energy &amp; Fuels   8 ( 2 )   202 - 209   2024

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    A high photocatalytic performance for overall water splitting was demonstrated over a photocatalyst based on a magnesium and scandium co-doped strontium titanate particle composed of a cubic shape having a nanosized step structure on the edge of the particle.

    DOI: 10.1039/d3se01408h

    researchmap

  • Activation of Nonoxide Photocatalyst Sheet Operable under Visible Light Irradiation up to 600 nm by Conductive Bilayer Reviewed

    Swarnava Nandy, Hiroka Sandaiji, Shuji Sekimori, Junie Jhon M. Vequizo, Rhauane Almeida Galvão, Natsutogi Iwasa, Swapnil S. Karade, Mamiko Nakabayashi, Tsuyoshi Takata, Takashi Hisatomi, Akira Yamakata, Kazunari Domen

    ACS Energy Letters   4708 - 4714   2024

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsenergylett.4c01795

    Scopus

    researchmap

  • Boosting charge separation in organic photovoltaics: unveiling dipole moment variations in excited non-fullerene acceptor layers Reviewed

    Akira Yamakata, Kosaku Kato, Takumi Urakami, Sota Tsujimura, Kasumi Murayama, Masahiro Higashi, Hirofumi Sato, Yasuhiro Kobori, Tomokazu Umeyama, Hiroshi Imahori

    Chemical Science   15 ( 32 )   12686 - 12694   2024

     More details

    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    Neat ITIC films are found to facilitate charge transfer, dissociation, and free carrier formation without the need for donor layers. This process, driven by V-type molecular stacking, significantly boosts organic photovoltaic efficiency.

    DOI: 10.1039/d4sc00917g

    researchmap

  • Sub-50 nm perovskite-type tantalum-based oxynitride single crystals with enhanced photoactivity for water splitting Reviewed

    Jiadong Xiao, Mamiko Nakabayashi, Takashi Hisatomi, Junie Jhon M. Vequizo, Wenpeng Li, Kaihong Chen, Xiaoping Tao, Akira Yamakata, Naoya Shibata, Tsuyoshi Takata, Yasunobu Inoue, Kazunari Domen

    Nature Communications   14 ( 1 )   2023.12

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Springer Science and Business Media LLC  

    Abstract

    A long-standing trade-off exists between improving crystallinity and minimizing particle size in the synthesis of perovskite-type transition-metal oxynitride photocatalysts via the thermal nitridation of commonly used metal oxide and carbonate precursors. Here, we overcome this limitation to fabricate ATaO2N (A = Sr, Ca, Ba) single nanocrystals with particle sizes of several tens of nanometers, excellent crystallinity and tunable long-wavelength response via thermal nitridation of mixtures of tantalum disulfide, metal hydroxides (A(OH)2), and molten-salt fluxes (e.g., SrCl2) as precursors. The SrTaO2N nanocrystals modified with a tailored Ir–Pt alloy@Cr2O3 cocatalyst evolved H2 around two orders of magnitude more efficiently than the previously reported SrTaO2N photocatalysts, with a record solar-to-hydrogen energy conversion efficiency of 0.15% for SrTaO2N in Z-scheme water splitting. Our findings enable the synthesis of perovskite-type transition-metal oxynitride nanocrystals by thermal nitridation and pave the way for manufacturing advanced long-wavelength-responsive particulate photocatalysts for efficient solar energy conversion.

    DOI: 10.1038/s41467-023-43838-3

    researchmap

    Other Link: https://www.nature.com/articles/s41467-023-43838-3

  • A Quantitative Study on the Relationship of Specific Surface Area and Carrier Lifetime to Photocatalytic Activity of Anatase TiO2 Nanoparticles Reviewed

    Shimpei Naniwa, Kosaku Kato, Akira Yamakata, Akira Yamamoto, Hisao Yoshida

    ACS Catalysis   13 ( 22 )   15212 - 15218   2023.11

     More details

    Authorship:Corresponding author   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acscatal.3c04209

    researchmap

  • Photocatalytic Hydrogen Evolution Activity of Nitrogen/Fluorine-Codoped Rutile TiO2 Reviewed

    Akinobu Miyoshi, Megumi Okazaki, Kosaku Kato, Tomoki Kanazawa, Toshiyuki Yokoi, Shunta Nishioka, Shunsuke Nozawa, Akira Yamakata, Kazuhiko Maeda

    ACS Omega   8 ( 44 )   41809 - 41815   2023.10

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acsomega.3c06492

    researchmap

  • In situ surface-enhanced infrared absorption analysis of the excited carrier transfer from n-type Si photoelectrode to Pt oxygen evolution cocatalyst by probing adsorbed CO molecules Reviewed

    Shu Ashimura, Reiya Konaka, Taki Suginaga, Kazuki Harada, Akira Yamakata, Chechia Hu, Hepsiba Niruba Catherine, Ke-Hsuan Wang, Takeshi Kawai, Masaaki Yoshida

    Journal of the Taiwan Institute of Chemical Engineers   105121 - 105121   2023.9

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.jtice.2023.105121

    researchmap

  • Unfolding the Impact of H<inf>2</inf>-Reduction Treatment in Enhancing the Photocatalytic Activity of Rutile TiO<inf>2</inf> Based on Photocarriers Dynamics Invited Reviewed

    Junie Jhon M. Vequizo, Kosaku Kato, Fumiaki Amano, Akira Yamakata

    Journal of Physical Chemistry C   127 ( 22 )   10411 - 10418   2023.6

     More details

    Authorship:Corresponding author   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpcc.3c00855

    Scopus

    researchmap

  • Metal Single‐Atom Cocatalyst on Carbon Nitride for the Photocatalytic Hydrogen Evolution Reaction: Effects of Metal Species Reviewed

    Yuki Akinaga, Tokuhisa Kawawaki, Hinano Kameko, Yuki Yamazaki, Kenji Yamazaki, Yuhi Nakayasu, Kosaku Kato, Yuto Tanaka, Adie Tri Hanindriyo, Makito Takagi, Tomomi Shimazaki, Masanori Tachikawa, Akira Yamakata, Yuichi Negishi

    Advanced Functional Materials   33 ( 33 )   2023.5

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    Abstract

    Single‐atom (SA) catalysts exhibit high activity in various reactions because there are no inactive internal atoms. Accordingly, SA cocatalysts are also an active research fields regarding photocatalytic hydrogen (H2) evolution which can be generated by abundant water and sunlight. Herein, it is investigated whether 10 transition metal elements can work as an SA on graphitic carbon nitride (g‐C3N4; i.e., gCN), a promising visible‐light‐driven photocatalyst. A method is established to prepare SA‐loaded gCN at high loadings (weight of ≈3 wt.% for Cu, Ni, Pd, Pt, Rh, and Ru) by modulating the photoreduction power. Regarding Au and Ag, SAs are formed with difficulty without aggregation because of the low binding energy between gCN and the SA. An evaluation of the photocatalytic H2‐evolution activity of the prepared metal SA‐loaded gCN reveals that Pd, Pt, and Rh SA‐loaded gCN exhibits relatively high H2‐evolution efficiency per SA. Transient absorption spectroscopy and electrochemical measurements reveal the following: i) Pd SA‐loaded gCN exhibits a particularly suitable electronic structure for proton adsorption and ii) therefore they exhibit the highest H2‐evolution efficiency per SA than other metal SA‐loaded gCN. Finally, the 8.6 times higher H2‐evolution rate per active site of Pd SA is achieved than that of Pd‐nanoparticles cocatalyst.

    DOI: 10.1002/adfm.202303321

    researchmap

  • Improved Photocatalytic O2 Evolution on a Sillén–Aurivillius Perovskite Oxychloride Bi6NbWO14Cl by Rh2O3 Additives and Surface Modifications Invited Reviewed

    Hajime Suzuki, Takanori Takashima, Osamu Tomita, Tomoki Kanazawa, Shunsuke Nozawa, Kosaku Kato, Akira Yamakata, Kouichi Nakashima, Akinori Saeki, Ryu Abe

    The Journal of Physical Chemistry C   127 ( 17 )   7965 - 7973   2023.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acs.jpcc.3c00846

    researchmap

  • Co-doping of a La5Ti2Cu0.9Ag0.1O7S5 photocatalyst (λ < 700 nm) with Ga and Al to enhance photocatalytic H2 evolution Reviewed International journal

    Xiaojun Wang, Zhenhua Pan, Junie Jhon, M. Vequizo, Takashi Hisatomi, Swarnava Nandy, Tomohiro Higashi, Lihua Lin, Jiadong Xiao, Tsuyoshi Takata, Akira Yamakata, Wei Yan, Kazunari Domen

    Chemical communications (Cambridge, England)   59 ( 45 )   6913 - 6916   2023.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    La5Ti2Cu0.9Ag0.1O7S5 (LTCA) (λ < 700 nm) can function as a photocatalyst for H2 evolution. Co-doping LTCA with Ga3+ and Al3+ at Ti4+ sites effectively enhanced the H2 evolution activity of LTCA, yielding an apparent quantum efficiency of 18% at 420 nm. The activity of this material was greater than that previously reported for Ga-doped LTCA by a factor of 1.6. Such activity enhancement is attributed to increasing the population of long-lived photogenerated electrons and facilitating the electron transfer to the cocatalyst. This work significantly improved the LTCA-based photocatalyst for H2 evolution, making it a promising material for future application in non-sacrificial Z-scheme water splitting.

    DOI: 10.1039/D3CC01863F

    PubMed

    researchmap

  • Carbon Nitride Loaded with an Ultrafine, Monodisperse, Metallic Platinum‐Cluster Cocatalyst for the Photocatalytic Hydrogen‐Evolution Reaction Reviewed

    Daichi Yazaki, Tokuhisa Kawawaki, Daisuke Hirayama, Masanobu Kawachi, Kosaku Kato, Sota Oguchi, Yuichi Yamaguchi, Soichi Kikkawa, Yoshiya Ueki, Sakiat Hossain, D. J. Osborn, Fumihiko Ozaki, Shunsuke Tanaka, Jun Yoshinobu, Gregory F. Metha, Seiji Yamazoe, Akihiko Kudo, Akira Yamakata, Yuichi Negishi

    Small   19 ( 34 )   2208287   2023.4

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/smll.202208287

    Scopus

    researchmap

  • Synthesis of crystal-phase and color tunable mixed anion co-doped titanium oxides and their controllable photocatalytic activity Reviewed

    Jingdi Cao, Takuya Hhasegawa, Yusuke Asakura, Akira Yamakata, Peng Sun, Wenbin Cao, Shu Yin

    International Journal of Minerals, Metallurgy and Materials   30 ( 10 )   2036 - 2043   2023.4

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Springer Science and Business Media LLC  

    DOI: 10.1007/s12613-022-2573-6

    researchmap

    Other Link: https://link.springer.com/article/10.1007/s12613-022-2573-6/fulltext.html

  • Asymmetrically coordinated cobalt single atom on carbon nitride for highly selective photocatalytic oxidation of CH4 to CH3OH Reviewed

    Jie Ding, Zhenyuan Teng, Xiaozhi Su, Kosaku Kato, Yuhang Liu, Ting Xiao, Wei Liu, Lingyue Liu, Qiao Zhang, Xinyi Ren, Jincheng Zhang, Zhaoyang Chen, Ohno Teruhisa, Akira Yamakata, Hongbin Yang, Yanqiang Huang, Bin Liu, Yueming Zhai

    Chem   9 ( 4 )   1017 - 1035   2023.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.chempr.2023.02.011

    researchmap

  • Surface-Specific Modification of Graphitic Carbon Nitride by Plasma for Enhanced Durability and Selectivity of Photocatalytic CO2 Reduction with a Supramolecular Photocatalyst Reviewed

    Noritaka Sakakibara, Mitsuhiko Shizuno, Tomoki Kanazawa, Kosaku Kato, Akira Yamakata, Shunsuke Nozawa, Tsuyohito Ito, Kazuo Terashima, Kazuhiko Maeda, Yusuke Tamaki, Osamu Ishitani

    ACS Applied Materials & Interfaces   15   13025 - 13218   2023.3

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsami.3c00955

    researchmap

  • Particle Size Dependent Trap States of Photoexcited Carriers in Anatase TiO2 Nanoparticles Invited Reviewed

    Shimpei Naniwa, Kosaku Kato, Akira Yamamoto, Hisao Yoshida, Akira Yamakata

    The Journal of Physical Chemistry C   127 ( 8 )   4295 - 4302   2023.3

     More details

    Authorship:Corresponding author   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpcc.2c08125

    researchmap

  • Promoted Utilization of Charge Carriers in La5Ti2Cu0.9Ag0.1O7S5-Based Photocatalyst Sheets for Efficient Z-Scheme Overall Water Splitting Reviewed

    Shanshan Chen, Swarnava Nandy, Junie Jhon M. Vequizo, Takashi Hisatomi, Mamiko Nakabayashi, Zhenhua Pan, Qi Xiao, Zheng Wang, Lihua Lin, Song Sun, Kosaku Kato, Akira Yamakata, Naoya Shibata, Tsuyoshi Takata, Fuxiang Zhang, Kazunari Domen

    ACS Catalysis   13 ( 5 )   3285 - 3294   2023.2

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acscatal.2c06249

    researchmap

  • Overall Water Splitting by a SrTaO2N-Based Photocatalyst Decorated with an Ir-Promoted Ru-Based Cocatalyst Reviewed

    Kaihong Chen, Jiadong Xiao, Junie Jhon M. Vequizo, Takashi Hisatomi, Yiwen Ma, Mamiko Nakabayashi, Tsuyoshi Takata, Akira Yamakata, Naoya Shibata, Kazunari Domen

    Journal of the American Chemical Society   145 ( 7 )   3839 - 3843   2023.1

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jacs.2c11025

    researchmap

  • Zr-doped BaTaO2N photocatalyst modified with Na–Pt cocatalyst for efficient hydrogen evolution and Z-scheme water splitting Reviewed

    Huihui Li, Junie Jhon M. Vequizo, Takashi Hisatomi, Mamiko Nakabayashi, Jiadong Xiao, Xiaoping Tao, Zhenhua Pan, Wenpeng Li, Shanshan Chen, Zheng Wang, Naoya Shibata, Akira Yamakata, Tsuyoshi Takata, Kazunari Domen

    EES Catalysis   1   26 - 35   2023.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    Detailed investigation of photocatalysts, cocatalysts and redox mediators provides a Z-scheme overall water splitting system operating under long-wavelength visible light.

    DOI: 10.1039/d2ey00031h

    researchmap

  • Active BaTaO2N Photocatalysts Prepared from Amorphous Ta2O5 Precursor for Overall Water Splitting under Visible Light Reviewed

    Shinji Nishimae, Junie Jhon M. Vequizo, Yasunobu Inoue, Akira Yamakata, Mamiko Nakabayashi, Tomohiro Higashi, Kazunari Domen

    Journal of Materials Chemistry A   11   6299 - 6310   2023

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    Barium tantalum oxynitride (BaTaO2N), a photocatalyst active during one-step-excitation overall water splitting under visible light, was synthesized by NH3-based nitridation of a mixture of BaCO3 and amorphous Ta2O53H2O. H2 and...

    DOI: 10.1039/d2ta10010j

    researchmap

  • An unexplored role of the CrOx shell in an elaborated Rh/CrOx core–shell cocatalyst for photocatalytic water splitting: a selective electron transport pathway from semiconductors to core metals, boosting charge separation and H2 evolution Reviewed

    Tetsu Kotani, Kanta Ogawa, Hajime Suzuki, Kosaku Kato, Osamu Tomita, Akira Yamakata, Ryu Abe

    EES Catalysis   1 ( 3 )   255 - 262   2023

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    In a Rh/CrOx core–shell cocatalyst for water-splitting photocatalysts, CrOx serves as an electron pathway, transfers the photoexcited electrons from photocatalysts to Rh (reduction site), and improves the H2 evolution activity.

    DOI: 10.1039/d2ey00109h

    researchmap

  • An emissive charge-transfer excited-state at the well-defined hetero-nanostructure interface of an organic conjugated molecule and two-dimensional inorganic nanosheet Reviewed

    Tomokazu Umeyama, Daizu Mizutani, Yuki Ikeda, W. Ryan Osterloh, Futa Yamamoto, Kosaku Kato, Akira Yamakata, Masahiro Higashi, Takumi Urakami, Hirofumi Sato, Hiroshi Imahori

    Chemical Science   14 ( 42 )   11914 - 11923   2023

     More details

    Authorship:Corresponding author   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    An unusual emissive charge-transfer excited state was formed at the pyrene–MoS2 interface.

    DOI: 10.1039/d3sc03604a

    researchmap

  • A general interfacial-energetics-tuning strategy for enhanced artificial photosynthesis Reviewed

    Tian Liu, Zhenhua Pan, Kosaku Kato, Junie Jhon M. Vequizo, Rito Yanagi, Xiaoshan Zheng, Weilai Yu, Akira Yamakata, Baoliang Chen, Shu Hu, Kenji Katayama, Chiheng Chu

    Nature Communications   13 ( 1 )   7783   2022.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Springer Science and Business Media LLC  

    Abstract

    The demands for cost-effective solar fuels have triggered extensive research in artificial photosynthesis, yet the efforts in designing high-performance particulate photocatalysts are largely impeded by inefficient charge separation. Because charge separation in a particulate photocatalyst is driven by asymmetric interfacial energetics between its reduction and oxidation sites, enhancing this process demands nanoscale tuning of interfacial energetics on the prerequisite of not impairing the kinetics and selectivity for surface reactions. In this study, we realize this target with a general strategy involving the application of a core/shell type cocatalyst that is demonstrated on various photocatalytic systems. The promising H2O2 generation efficiency validate our perspective on tuning interfacial energetics for enhanced charge separation and photosynthesis performance. Particularly, this strategy is highlighted on a BiVO4 system for overall H2O2 photosynthesis with a solar-to-H2O2 conversion of 0.73%.

    DOI: 10.1038/s41467-022-35502-z

    researchmap

    Other Link: https://www.nature.com/articles/s41467-022-35502-z

  • Harnessing infrared solar energy with plasmonic energy upconversion (Oct, 10.1038/s41893-022-01015-2, 2022) Reviewed

    Zichao Lian, Yoichi Kobayashi, Junie Jhon M. Vequizo, Chandana Sampath Kumara Ranasinghe, Akira Yamakata, Takuro Nagai, Koji Kimoto, Katsuaki Kobayashi, Koji Tanaka, Toshiharu Teranishi, Masanori Sakamoto

    NATURE SUSTAINABILITY   5   1092 - 1099   2022.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s41893-022-01015-2

    Web of Science

    researchmap

  • Effects of Hydroxy Groups in Anthraquinone Dyes on Photocatalytic Activity of Visible-light-sensitized Pt-TiO2 for Hydrogen Evolution Reviewed

    Fumiaki Amano, Yasukazu Akaki, Akira Yamakata

    Catalysis Surveys from Asia   27 ( 1 )   75 - 83   2022.10

     More details

    Authorship:Last author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Springer Science and Business Media LLC  

    DOI: 10.1007/s10563-022-09370-y

    researchmap

    Other Link: https://link.springer.com/article/10.1007/s10563-022-09370-y/fulltext.html

  • 固体表面の動力学に追る時間分解中赤外分光 Invited Reviewed

    山方啓, 加藤康作

    光学   51   448 - 454   2022.10

     More details

    Authorship:Lead author, Corresponding author   Language:Japanese   Publishing type:Research paper (scientific journal)  

    researchmap

  • Effects of a Nanoparticulate TiO2 Modifier on the Visible-Light CO2 Reduction Performance of a Metal-Complex/Semiconductor Hybrid Photocatalyst Reviewed

    Mitsuhiko Shizuno, Kosaku Kato, Shunta Nishioka, Tomoki Kanazawa, Daiki Saito, Shunsuke Nozawa, Akira Yamakata, Osamu Ishitani, Kazuhiko Maeda

    ACS Applied Energy Materials   5 ( 8 )   9479 - 9486   2022.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsaem.2c01052

    Web of Science

    researchmap

  • One-Step Excitation Overall Water Splitting over a Modified Mg-Doped BaTaO2N Photocatalyst Reviewed

    Huihui Li, Jiadong Xiao, Junie Jhon M. Vequizo, Takashi Hisatomi, Mamiko Nakabayashi, Zhenhua Pan, Naoya Shibata, Akira Yamakata, Tsuyoshi Takata, Kazunari Domen

    ACS Catalysis   12 ( 16 )   10179 - 10185   2022.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acscatal.2c02394

    Web of Science

    researchmap

  • Effect of Surface Plasmon Resonance and the Heterojunction on Photoelectrochemical Activity of Metal-Loaded TiO2 Electrodes under Visible Light Irradiation Reviewed

    Chia-Yu Chang, Akira Yamakata, Wenjea J. Tseng

    The Journal of Physical Chemistry C   126   12450 - 12459   2022.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpcc.2c02649

    Web of Science

    researchmap

  • Eliciting the contribution of TiN to photoelectrochemical performance enhancement of Imma-LaTiO2N at neutral pH Invited Reviewed

    Mirabbos Hojamberdiev, Juan Manuel Mora-Hernandez, Ronald Vargas, Eva Maria Heppke, Kunio Yubuta, Akira Yamakata, Zukhra Kadirova, Leticia Torres-Martinez, Katsuya Teshima, Martin Lerch

    MATERIALS TODAY ENERGY   27   2022.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.mtener.2022.101053

    Web of Science

    researchmap

  • Role of Oxygen Vacancy in the Photocarrier Dynamics of WO3 Photocatalysts: The Case of Recombination Centers Reviewed

    Kosaku Kato, Yohei Uemura, Kiyotaka Asakura, Akira Yamakata

    The Journal of Physical Chemistry C   126 ( 22 )   9257 - 9263   2022.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpcc.2c01662

    Web of Science

    researchmap

  • Enhanced Overall Water Splitting by a Zirconium‐Doped TaON‐Based Photocatalyst Reviewed

    Jiadong Xiao, Shinji Nishimae, Junie Jhon M. Vequizo, Mamiko Nakabayashi, Takashi Hisatomi, Huihui Li, Lihua Lin, Naoya Shibata, Akira Yamakata, Yasunobu Inoue, Kazunari Domen

    Angewandte Chemie International Edition   61 ( 17 )   2022.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.202116573

    Web of Science

    researchmap

  • Identification of a Self-Photosensitizing Hydrogen Atom Transfer Organocatalyst System. Reviewed International journal

    Hiromu Fuse, Yu Irie, Masaaki Fuki, Yasuhiro Kobori, Kosaku Kato, Akira Yamakata, Masahiro Higashi, Harunobu Mitsunuma, Motomu Kanai

    Journal of the American Chemical Society   144 ( 14 )   6566 - 6574   2022.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    We developed organocatalyst systems to promote the cleavage of stable C-H bonds, such as formyl, α-hydroxy, and benzylic C-H bonds, through a hydrogen atom transfer (HAT) process without the use of exogenous photosensitizers. An electronically tuned thiophosphoric acid, 7,7'-OMe-TPA, was assembled with substrate or co-catalyst N-heteroaromatics through hydrogen bonding and π-π interactions to form electron donor-acceptor (EDA) complexes. Photoirradiation of the EDA complex induced stepwise, sequential single-electron transfer (SET) processes to generate a HAT-active thiyl radical. The first SET was from the electron-rich naphthyl group of 7,7'-OMe-TPA to the protonated N-heteroaromatics and the second proton-coupled SET (PCET) from the thiophosphoric acid moiety of 7,7'-OMe-TPA to the resulting naphthyl radical cation. Spectroscopic studies and theoretical calculations characterized the stepwise SET process mediated by short-lived intermediates. This organocatalytic HAT system was applied to four different carbon-hydrogen (C-H) functionalization reactions, hydroxyalkylation and alkylation of N-heteroaromatics, acceptorless dehydrogenation of alcohols, and benzylation of imines, with high functional group tolerance.

    DOI: 10.1021/jacs.2c01705

    PubMed

    researchmap

  • 時間分解分光計測を利用した光触媒反応機構の解明 Invited Reviewed

    山方啓

    分光研究   71   75 - 89   2022.4

     More details

    Authorship:Lead author, Corresponding author   Language:Japanese   Publishing type:Research paper (scientific journal)  

    researchmap

  • Donor-π-Acceptor Type Porphyrin-Fullerene Dyad with Acetylene Bridge for p-Type Dye-sensitized Solar Cell Reviewed

    Qi Guo, Tomohiro Higashino, Kosaku Kato, Akira Yamakata, Hiroshi Imahori

    Chemistry Letters   51 ( 3 )   260 - 263   2022.2

     More details

    Authorship:Corresponding author   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/cl.210717

    Web of Science

    researchmap

  • Manipulation of charge carrier flow in Bi4NbO8Cl nanoplate photocatalyst with metal loading Reviewed

    Kanta Ogawa, Ryota Sakamoto, Chengchao Zhong, Hajime Suzuki, Kosaku Kato, Osamu Tomita, Kouichi Nakashima, Akira Yamakata, Takashi Tachikawa, Akinori Saeki, Hiroshi Kageyama, Ryu Abe

    Chemical Science   13 ( 11 )   3118 - 3128   2022.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d1sc06054f

    Web of Science

    researchmap

  • Unfolding the Role of B Site-Selective Doping of Aliovalent Cations on Enhancing Sacrificial Visible Light-Induced Photocatalytic H2 and O2 Evolution over BaTaO2N Reviewed

    Mirabbos Hojamberdiev, Ronald Vargas, Zukhra C. Kadirova, Kosaku Kato, Hadi Sena, Aleksei G. Krasnov, Akira Yamakata, Katsuya Teshima, Martin Lerch

    ACS Catalysis   12 ( 2 )   1403 - 1414   2022.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acscatal.1c04547

    Web of Science

    researchmap

  • Overall photosynthesis of H2O2 by an inorganic semiconductor Reviewed

    Pan Zhenhua, Junie Jhon, M. Vequizo, Kosaku Kato, Akira Yamakata, Kenji Katayama, Chiheng Chu, Kazunari Domen

    Nature Communications   13 ( 1 )   2022.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s41467-022-28686-x

    Web of Science

    researchmap

  • Improvement of Visible‐Light H2 Evolution Activity of Pb2Ti2O5.4F1.2 Photocatalyst by Coloading of Rh and Pd Cocatalysts Reviewed

    Kenta Aihara, Kosaku Kato, Tomoki Uchiyama, Shuhei Yasuda, Toshiyuki Yokoi, Akira Yamakata, Yoshiharu Uchimoto, Kazuhiko Maeda

    Chemistry - A European Journal   28 ( 43 )   2022

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/CHEM.202200875

    Scopus

    PubMed

    researchmap

  • Influences of pulverization and annealing treatment on the photocatalytic activity of BiVO4 for oxygen evolution Reviewed

    Kazuya Okuno, Hiromu Kumagai, Junie Jhon M. Vequizo, Kosaku Kato, Makoto Kobayashi, Akira Yamakata, Masato Kakihana, Hideki Kato

    Sustainable Energy &amp; Fuels   6 ( 7 )   1698 - 1707   2022

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    Pulverization followed by annealing treatment improved the activity of BiVO4 although the annealing treatment had a negative impact on the non-milled sample.

    DOI: 10.1039/d2se00065b

    researchmap

  • Photoexcited charge manipulation in conjugated polymers bearing a Ru(ii) complex catalyst for visible-light CO2 reduction Invited Reviewed

    Akinobu Nakada, Ryuichi Miyakawa, Ren Itagaki, Kosaku Kato, Chinami Takashima, Akinori Saeki, Akira Yamakata, Ryu Abe, Hiromi Nakai, Ho-Chol Chang

    Journal of Materials Chemistry A   10 ( 37 )   19821 - 19828   2022

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D2TA02183H

    Web of Science

    researchmap

  • Effects of the rigid and sterically bulky structure of non-fused nonfullerene acceptors on transient photon-to-current dynamics Reviewed

    Seihou Jinnai, Kasumi Murayama, Keisuke Nagai, Megumi Mineshita, Kosaku Kato, Azusa Muraoka, Akira Yamakata, Akinori Saeki, Yasuhiro Kobori, Yutaka Ie

    Journal of Materials Chemistry A   10 ( 37 )   20035 - 20047   2022

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    Non-fused electron-accepting π-conjugated compounds have been investigated recently for application to nonfullerene acceptors (NFAs) in organic solar cells (OSCs).

    DOI: 10.1039/D2TA02604J

    researchmap

  • Unfolding the Role of B Site-Selective Doping of Aliovalent Cations on Enhancing Sacrificial Visible Light-Induced Photocatalytic H2 and O2 Evolution over BaTaO2N

    Akira Yamakata

    ACS Catalysis   2022

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ACSCATAL.LC04547

    Web of Science

    researchmap

  • One-Step Excitation Overall Water Splitting over a Modified Mg-Doped BaTaO2N Photocatalyst

    Akira Yamakata

    ACS Catalysis   2022

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ACSCATAL.2C02394

    Web of Science

    researchmap

  • Harnessing infrared solar energy with plasmonic energy upconversion

    Akira Yamakata

    Nature Sustainability   2022

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/S41893-022-00975-9

    Web of Science

    researchmap

  • Effect of Terminal-Group Halogenation of Naphthalene-Based Nonfullerene Acceptors on Their Film Structure and Photophysical and Photovoltaic Properties Reviewed

    Tomokazu Umeyama, Tatsuho Wada, Kensho Igarashi, Kosaku Kato, Akira Yamakata, Taiki Takeyama, Yuji Sakamoto, Yasunari Tamai, Hideo Ohkita, Keiichi Ishida, Tomoyuki Koganezawa, Shunsuke Ohtani, Kazuo Tanaka, Hiroshi Imahori

    ACS Applied Energy Materials   4 ( 12 )   14022 - 14033   2021.12

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acsaem.1c02816

    Scopus

    researchmap

  • Modified SILAR grown ZnO films on p ‐Si(100) with enhanced charge separation for UV light sensing application Reviewed

    Jose Presiphil B. Ontolan, Junie Jhon M. Vequizo, Akira Yamakata, Reynaldo M. Vequizo

    physica status solidi (a)   218 ( 22 )   2100363 - 2100363   2021.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/pssa.202100363

    Web of Science

    researchmap

  • Forward and backward electron transfer on Pt loaded TiO2 photocatalysts under visible-light illumination Reviewed

    Naohiro Inoue, Kyohei Shiraki, Kosaku Kato, Shu Ashimura, Masaaki Yoshida, Akira Yamakata

    Applied Physics Letters   119 ( 13 )   133905 - 133905   2021.9

     More details

    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1063/5.0065074

    Web of Science

    researchmap

  • Time-Retrenched Synthesis of BaTaO2N by Localizing an NH3 Delivery System for Visible-Light-Driven Photoelectrochemical Water Oxidation at Neutral pH: Solid-State Reaction or Flux Method? Reviewed

    Mirabbos Hojamberdiev, J. Manuel Mora-Hernandez, Ronald Vargas, Akira Yamakata, Kunio Yubuta, Eva Maria Heppke, Leticia M. Torres-Martínez, Katsuya Teshima, Martin Lerch

    ACS Applied Energy Materials   4 ( 9 )   9315 - 9327   2021.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsaem.1c01539

    Web of Science

    researchmap

  • Control of the Photocatalytic Activity of Metastable Layered Oxynitride K2LaTa2O6N through Topochemical Transformation of Tuned Oxide Precursors Reviewed

    Hiroto Mogi, Kosaku Kato, Shuhei Yasuda, Tomoki Kanazawa, Akinobu Miyoshi, Shunta Nishioka, Takayoshi Oshima, Ya Tang, Toshiyuki Yokoi, Shunsuke Nozawa, Akira Yamakata, Kazuhiko Maeda

    Chemistry of Materials   33 ( 16 )   6443 - 6452   2021.8

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.chemmater.1c01726

    Scopus

    researchmap

  • Surface Modifications of (ZnSe)0.5(CuGa2.5Se4.25)0.5 to Promote Photocatalytic Z-Scheme Overall Water Splitting Reviewed

    Shanshan Chen, Junie Jhon M. Vequizo, Zhenhua Pan, Takashi Hisatomi, Mamiko Nakabayashi, Lihua Lin, Zheng Wang, Kosaku Kato, Akira Yamakata, Naoya Shibata, Tsuyoshi Takata, Taro Yamada, Kazunari Domen

    Journal of the American Chemical Society   143 ( 28 )   10633 - 10641   2021.7

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jacs.1c03555

    researchmap

  • Simultaneously Tuning the Defects and Surface Properties of Ta3N5 Nanoparticles by Mg–Zr Codoping for Significantly Accelerated Photocatalytic H2 Evolution Reviewed

    Jiadong Xiao, Junie Jhon M. Vequizo, Takashi Hisatomi, Jabor Rabeah, Mamiko Nakabayashi, Zheng Wang, Qi Xiao, Huihui Li, Zhenhua Pan, Mary Krause, Nick Yin, Gordon Smith, Naoya Shibata, Angelika Brückner, Akira Yamakata, Tsuyoshi Takata, Kazunari Domen

    Journal of the American Chemical Society   143 ( 27 )   10059 - 10064   2021.7

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jacs.1c04861

    researchmap

  • Buckyball as an Electron Donor in a Dyad of C60 and Xanthene Dye Reviewed

    Haruka Kano, Kyohei Matsuo, Hironobu Hayashi, Kosaku Kato, Akira Yamakata, Hiroko Yamada, Naoki Aratani

    European Journal of Organic Chemistry   2021 ( 23 )   3377 - 3381   2021.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/ejoc.202100276

    Web of Science

    researchmap

    Other Link: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/ejoc.202100276

  • Titanium Dioxide/Polyvinyl Alcohol/Cork Nanocomposite: A Floating Photocatalyst for the Degradation of Methylene Blue under Irradiation of a Visible Light Source Reviewed

    Nurul Hidayah Mohamad Idris, Jayalakshmi Rajakumar, Kuan Yew Cheong, Brendan J. Kennedy, Teruhisa Ohno, Akira Yamakata, Hooi Ling Lee

    ACS Omega   6 ( 22 )   14493 - 14503   2021.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsomega.1c01458

    Web of Science

    researchmap

  • (Invited) Core-Shell Double Doping for the Remarkable Photocatalytic Water Splitting on Ga2O3

    Akira Yamakata, Junie Jhon M. Vequizo, Kosaku Kato, Yoshihisa Sakata

    ECS Meeting Abstracts   {MA}2021-01 ( 15 )   725 - 725   2021.5

     More details

    Publishing type:Research paper (scientific journal)   Publisher:The Electrochemical Society  

    DOI: 10.1149/MA2021-0115725mtgabs

    researchmap

  • Atomically dispersed antimony on carbon nitride for the artificial photosynthesis of hydrogen peroxide Reviewed

    Zhenyuan Teng, Qitao Zhang, Hongbin Yang, Kosaku Kato, Wenjuan Yang, Ying-Rui Lu, Sixiao Liu, Chengyin Wang, Akira Yamakata, Chenliang Su, Bin Liu, Teruhisa Ohno

    Nature Catalysis   4 ( 5 )   374 - 384   2021.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s41929-021-00605-1

    Web of Science

    researchmap

    Other Link: http://www.nature.com/articles/s41929-021-00605-1

  • A Na-containing Pt cocatalyst for efficient visible-light-induced hydrogen evolution on BaTaO2N Reviewed

    Huihui Li, Daling Lu, Shanshan Chen, Takashi Hisatomi, Junie Jhon M. Vequizo, Jiadong Xiao, Zheng Wang, Lihua Lin, Qi Xiao, Yuliang Sun, Yugo Miseki, Kazuhiro Sayama, Akira Yamakata, Tsuyoshi Takata, Kazunari Domen

    Journal of Materials Chemistry A   9 ( 24 )   13851 - 13854   2021.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d1ta01162f

    Web of Science

    researchmap

  • Utilization of Perovskite-Type Oxynitride La0.5Sr0.5Ta0.5Ti0.5O2N as an O2-Evolving Photocatalyst in Z-Scheme Water Splitting Reviewed

    Hiromu Kumagai, Ryosuke Aoyagi, Kosaku Kato, Akira Yamakata, Masato Kakihana, Hideki Kato

    ACS Applied Energy Materials   2021.3

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acsaem.0c03055

    researchmap

  • Core–Shell Double Doping of Zn and Ca on β-Ga2O3 Photocatalysts for Remarkable Water Splitting Reviewed

    Akira Yamakata, Junie Jhon M. Vequizo, Takafumi Ogawa, Kosaku Kato, Shoya Tsuboi, Naohiro Furutani, Masahiro Ohtsuka, Shunsuke Muto, Akihide Kuwabara, Yoshihisa Sakata

    ACS Catalysis   11 ( 4 )   1911 - 1919   2021.2

     More details

    Authorship:Lead author   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acscatal.0c05104

    researchmap

  • Sequential cocatalyst decoration on BaTaO2N towards highly-active Z-scheme water splitting Reviewed

    Zheng Wang, Ying Luo, Takashi Hisatomi, Junie Jhon M. Vequizo, Sayaka Suzuki, Shanshan Chen, Mamiko Nakabayashi, Lihua Lin, Zhenhua Pan, Nobuko Kariya, Akira Yamakata, Naoya Shibata, Tsuyoshi Takata, Katsuya Teshima, Kazunari Domen

    Nature Communications   12 ( 1 )   1005   2021.2

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s41467-021-21284-3

    Web of Science

    researchmap

    Other Link: http://www.nature.com/articles/s41467-021-21284-3

  • 半導体光触媒粒子中の欠陥が及ぼす光励起キャリアの再結合促進と抑制効果 Invited

    山方啓, 加藤康作

    会報光触媒   64   27 - 36   2021.1

     More details

    Authorship:Lead author, Corresponding author  

    researchmap

  • Earth-abundant iron(iii) species serves as a cocatalyst boosting the multielectron reduction of IO3−/I− redox shuttle in Z-scheme photocatalytic water splitting Reviewed

    Katsuya Murofushi, Kanta Ogawa, Hajime Suzuki, Ryota Sakamoto, Osamu Tomita, Kosaku Kato, Akira Yamakata, Akinori Saeki, Ryu Abe

    Journal of Materials Chemistry A   9 ( 19 )   11718 - 11725   2021

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    <p>The FeIII/FeII redox couple in the amorphous FeOx cocatalyst on the Bi4TaO8Cl photocatalyst captures photoexcited electrons and facilitates the multielectron (6-electrons) reduction of IO3, thus boosting O2 evolution under visible light.</p>

    DOI: 10.1039/D1TA01703A

    researchmap

  • Cocatalyst engineering of a narrow bandgap Ga-La5Ti2Cu0.9Ag0.1O7S5 photocatalyst towards effectively enhanced water splitting Reviewed

    Qi Xiao, Jiadong Xiao, Junie Jhon M. Vequizo, Takashi Hisatomi, Mamiko Nakabayashi, Shanshan Chen, Zhenhua Pan, Lihua Lin, Naoya Shibata, Akira Yamakata, Tsuyoshi Takata, Kazunari Domen

    Journal of Materials Chemistry A   9 ( 48 )   27485 - 27492   2021

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    The hydrogen evolution activity of Ga-doped La5Ti2Cu0.9Ag0.1O7S5 (Ga-LTCA) was boosted by loading a Rh cocatalyst having uniform dispersion and intimate contact.

    DOI: 10.1039/d1ta08770c

    researchmap

  • Atomically dispersed antimony on carbon nitride for the artificial photosynthesis of hydrogen peroxide (vol 4, pg 374, 2021)

    Akira Yamakata

    Nature Catalysis   2021

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/S41929-021-00644-8

    Web of Science

    researchmap

  • Heavy Metal Effects on the Photovoltaic Properties of Metallocorroles in Dye-Sensitized Solar Cells Reviewed

    Tomohiro Higashino, Yuma Kurumisawa, Abraham B. Alemayehu, Rune F. Einrem, Debashis Sahu, Daniel Packwood, Kosaku Kato, Akira Yamakata, Abhik Ghosh, Hiroshi Imahori

    ACS Applied Energy Materials   3 ( 12 )   12460 - 12467   2020.12

     More details

    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsaem.0c02427

    Web of Science

    researchmap

  • Time-Resolved Spectroscopy of Defect-Induced Effects on Photocarrier Dynamics in SrTiO3 Powder

    Akira Yamakata, Kosaku Kato

    ECS Meeting Abstracts   {MA}2020-02 ( 56 )   3873 - 3873   2020.11

     More details

    Publishing type:Research paper (scientific journal)   Publisher:The Electrochemical Society  

    DOI: 10.1149/MA2020-02563873mtgabs

    researchmap

  • Optically Transparent Colloidal Dispersion of Titania Nanoparticles Storable for Longer than One Year Prepared by Sol/Gel Progressive Hydrolysis/Condensation Reviewed

    Keito Sano, Fazalurahman Kuttassery, Tetsuya Shimada, Tamao Ishida, Shinsuke Takagi, Bunsho Ohtani, Akira Yamakata, Tetsuo Honma, Hiroshi Tachibana, Haruo Inoue

    ACS Applied Materials & Interfaces   12 ( 40 )   44743 - 44753   2020.10

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acsami.0c12951

    Scopus

    PubMed

    researchmap

  • Investigation on the highly active SrTiO3 photocatalyst toward overall H2O splitting by doping Na ion Reviewed

    Junzhe Jiang, Kosaku Kato, Hirotaka Fujimori, Akira Yamakata, Yoshihisa Sakata

    Journal of Catalysis   390   81 - 89   2020.8

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.jcat.2020.07.025

    researchmap

  • Synthesis of Three-Layer Perovskite Oxynitride K2Ca2Ta3O9N·2H2O and Photocatalytic Activity for H2 Evolution under Visible Light Reviewed

    Ya Tang, Kosaku Kato, Takayoshi Oshima, Hiroto Mogi, Akinobu Miyoshi, Kotaro Fujii, Kei-ichi Yanagisawa, Koji Kimoto, Akira Yamakata, Masatomo Yashima, Kazuhiko Maeda

    Inorganic Chemistry   59 ( 15 )   11122 - 11128   2020.8

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acs.inorgchem.0c01607

    researchmap

  • Heteroatom Dopants Promote Two‐Electron O 2 Reduction for Photocatalytic Production of H 2 O 2 on Polymeric Carbon Nitride Reviewed

    Peng Zhang, Yawen Tong, Yong Liu, Junie Jhon M. Vequizo, Hongwei Sun, Can Yang, Akira Yamakata, Fengtao Fan, Wei Lin, Xinchen Wang, Wonyong Choi

    Angewandte Chemie International Edition   59   16209 - 16217   2020.6

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/anie.202006747

    researchmap

    Other Link: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.202006747

  • Efficient photocatalytic hydrogen evolution on single-crystalline metal selenide particles with suitable cocatalysts Reviewed

    Shanshan Chen, Junie Jhon, M. Vequizo, Takashi Hisatomi, Mamiko Nakabayashi, Lihua Lin, Zheng Wang, Akira Yamakata, Naoya Shibata, Tsuyoshi Takata, Taro Yamada, Kazunari Domen

    Chemical Science   11 ( 25 )   6436 - 6441   2020.4

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    <p>Coloading of a Ni–Ru composite cocatalyst on a 700 nm-class single-crystalline particulate selenide photocatalyst improves its hydrogen evolution activity.</p>

    DOI: 10.1039/D0SC01167C

    researchmap

  • Activation of a Pt-loaded Pb<inf>2</inf>Ti<inf>2</inf>O<inf>5.4</inf>F<inf>1.2</inf> photocatalyst by alkaline chloride treatment for improved H<inf>2</inf> evolution under visible light Reviewed

    Wakayama, H., Kato, K., Kashihara, K., Uchiyama, T., Miyoshi, A., Nakata, H., Lu, D., Oka, K., Yamakata, A., Uchimoto, Y., Maeda, K.

    Journal of Materials Chemistry A   8 ( 18 )   9099 - 9108   2020.4

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/d0ta02883e

    Scopus

    researchmap

  • How g-C3N4 Works and Is Different from TiO2 as an Environmental Photocatalyst: Mechanistic View

    Jonghun Lim, Hyejin Kim, Jihee Park, Gun-Hee Moon, Junie Jhon M Vequizo, Akira Yamakata, Jinwoo Lee, Wonyong Choi

    Environmental science &amp; technology   54 ( 1 )   497 - 506   2020.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:NLM (Medline)  

    DOI: 10.1021/acs.est.9b05044

    Scopus

    PubMed

    researchmap

  • Identification of Individual Electron- and Hole-Transfer Kinetics at CoOx/BiVO4/SnO2 Double Heterojunctions Reviewed

    Akira Yamakata, Chandana Sampath, Kumara Ranasinghe, Naruki Hayashi, Kosaku Kato, Junie Jhon, M. Vequizo

    ACS Applied Energy Materials   3 ( 1 )   1207 - 1214   2020.1

     More details

    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsaem.9b02262

    Web of Science

    researchmap

  • 時間分解分光測定による粉末欠陥への光励起キャリアー捕捉過程と光触媒活性に及ぼす影響 Reviewed

    山方啓* and Junie Jhon M. Vequizo,

    触媒 【特集号: 触媒設計を拓く欠陥構造のキャラクタリゼーション】   62 ( 1 )   22 - 28   2020.1

     More details

    Authorship:Lead author, Corresponding author  

    researchmap

  • Synthesis of Copolymerized Carbon Nitride Nanosheets from Urea and 2-Aminobenzonitrile for Enhanced Visible-Light CO2 Reduction with a Ruthenium(II) Complex Catalyst Reviewed

    Kengo Shibata, Kosaku Kato, Constantine Tsounis, Tomoki Kanazawa, Daling Lu, Shunsuke Nozawa, Akira Yamakata, Osamu Ishitani, Kazuhiko Maeda

    Solar RRL   4 ( 8 )   1900461   2020.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/solr.201900461

    Web of Science

    researchmap

  • How g-C3N4 Works and Is Different from TiO2 as Environmental Photocatalyst: Mechanistic View Reviewed International journal

    Jonghun Lim, Hyejin Kim, Jihee Park, Gun-hee Moon, Junie Jhon, M. Vequizo, Akira Yamakata, Jinwoo Lee, Wonyong Choi

    Environmental Science & Technology   54 ( 1 )   497 - 506   2020.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.est.9b05044

    Web of Science

    PubMed

    researchmap

  • Enhancement of UV-responsive photocatalysts aided by visible-light responsive photocatalysts: Role of WO<inf>3</inf> for H<inf>2</inf> evolution on CuCl Reviewed

    Takagi, M., Kawaguchi, M., Yamakata, A.

    Applied Catalysis B: Environmental   263   118333 - 118333   2020

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.apcatb.2019.118333

    Web of Science

    Scopus

    researchmap

  • Cobalt Aluminate Spinel as a Cocatalyst for Photocatalytic Oxidation of Water: Significant Hole-Trapping Effect Reviewed

    Kanazawa, T., Kato, K., Yamaguchi, R., Uchiyama, T., Lu, D., Nozawa, S., Yamakata, A., Uchimoto, Y., Maeda, K.

    ACS Catalysis   10 ( 9 )   4960 - 4966   2020

     More details

    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acscatal.0c00944

    Web of Science

    Scopus

    researchmap

  • Defect-Induced Acceleration and Deceleration of Photocarrier Recombination in SrTiO<inf>3</inf>Powders Reviewed

    Kato, K., Yamakata, A., Yamakata, A.

    Journal of Physical Chemistry C   124 ( 20 )   11057 - 11063   2020

     More details

    Authorship:Corresponding author   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acs.jpcc.0c03369

    Scopus

    researchmap

  • Synthesis of three-component C<inf>3</inf>N<inf>4</inf>/rGO/C-TiO<inf>2</inf> photocatalyst with enhanced visible-light responsive photocatalytic deNO<inf>x</inf> activity Reviewed

    Noda, C., Asakura, Y., Shiraki, K., Yamakata, A., Yin, S.

    Chemical Engineering Journal   390   124616 - 124616   2020

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.cej.2020.124616

    Web of Science

    Scopus

    researchmap

  • Nano vs. bulk rutile TiO2:N,F in Z-scheme overall water splitting under visible light Reviewed

    Akinobu Miyoshi, Kosaku Kato, Toshiyuki Yokoi, Jan J. Wiesfeld, Kiyotaka Nakajima, Akira Yamakata, Kazuhiko Maeda

    Journal of Materials Chemistry A   8 ( 24 )   11996 - 12002   2020

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    <p>Nitrogen/fluorine-codoped rutile TiO2 nanoparticles worked more efficiently as a water oxidation photocatalyst in visible-light Z-scheme water splitting than a bulk analogue.</p>

    DOI: 10.1039/d0ta04450d

    researchmap

  • Enhancement of photoelectrochemical activity of TiO<inf>2</inf> electrode by particulate/dense double-layer formation Invited Reviewed

    Hayashi, N., Kato, K., Yamakata, A.

    The Journal of chemical physics   152 ( 24 )   241101 - 241101   2020

     More details

    Authorship:Corresponding author   Publishing type:Research paper (scientific journal)   Publisher:AIP Publishing  

    DOI: 10.1063/5.0010121

    Scopus

    researchmap

  • Fe/Ru Oxide as Versatile and Effective Cocatalyst for Boosting Z-Scheme Water Splitting: Suppressing Undesirable Backward Electron Transfer Reviewed

    Akinobu Nakada, Hajime Suzuki, Junie Jhon, M. Vequizo, Kanta Ogawa, Masanobu Higashi, Akinori Saeki, Akira Yamakata, Hiroshi Kageyama, Ryu Abe

    ACS Applied Materials & Interfaces   11 ( 49 )   45606 - 45611   2019.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsami.9b14802

    Web of Science

    researchmap

  • Crucial impact of reduction on the photocarriers dynamics on SrTiO3 powders studied by transient absorption spectroscopy Reviewed

    Junie Jhon, M. Vequizo, Shunta Nishioka, Junji Hyodo, Yoshihiro Yamazaki, Kazuhiko Maeda, Akira Yamakata

    J. Mater. Chem. A   7 ( 45 )   26139 - 26146   2019.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C9TA08216F

    Web of Science

    researchmap

  • Achievement of High Photocatalytic Performance to BaTi4O9 toward Overall H2O Splitting Reviewed

    Yuichi Hiramachi, Hirotaka Fujimori, Akira Yamakata, Yoshihisa Sakata

    ChemCatChem   11 ( 24 )   6213 - 6217   2019.10

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/cctc.201901564

    Scopus

    researchmap

  • Solar-Driven Photoelectrochemical Water Oxidation over an n-Type Lead-Titanium Oxyfluoride Anode Reviewed

    Naoki Hirayama, Hiroko Nakata, Haruki Wakayama, Shunta Nishioka, Tomoki Kanazawa, Ryutaro Kamata, Yosuke Ebato, Kosaku Kato, Hiromu Kumagai, Akira Yamakata, Kengo Oka, Kazuhiko Maeda

    J. Am. Chem. Soc.   141 ( 43 )   17158 - 17165   2019.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jacs.9b06570

    Web of Science

    researchmap

  • Effect of Na-doping on Electron Decay kinetics in SrTiO3 Photocatalyst Reviewed

    Kosaku Kato, Junzhe Jiang, Yoshihisa Sakata, Akira Yamakata

    ChemCatChem   11 ( 24 )   6349 - 6354   2019.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/cctc.201901669

    Web of Science

    researchmap

  • Enhanced water splitting through two-step photoexcitation by sunlight using tantalum/nitrogen-codoped rutile titania as a water oxidation photocatalyst Reviewed

    Shunta Nishioka, Kei-ichi Yanagisawa, Daling Lu, Junie Jhon, M. Vequizo, Akira Yamakata, Koji Kimoto, Miki Inada, Kazuhiko Maeda

    Sustainable Energy & Fuels   3 ( 9 )   2337 - 2346   2019.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C9SE00289H

    Web of Science

    researchmap

  • Enhanced Visible Light Response of TiO<inf>2</inf> Codoped with Cr and Ta Photocatalysts by Electron Doping Reviewed

    Fumiaki Amano, Masashi Nakata, Junie Jhon M. Vequizo, Akira Yamakata

    ACS Applied Energy Materials   2 ( 5 )   3274 - 3282   2019.5

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsaem.9b00126

    Scopus

    researchmap

  • Construction of Spatial Charge Separation Facets on BaTaO2N Crystals by Flux Growth Approach for Visible-Light-Driven H2 Production Reviewed

    Ying Luo, Sayaka Suzuki, Zheng Wang, Kunio Yubuta, Junie Jhon, M. Vequizo, Akira Yamakata, Hiromasa Shiiba, Takashi Hisatomi, Kazunari Domen, Katsuya Teshima

    ACS Applied Materials & Interfaces   11 ( 25 )   22264 - 22271   2019.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsami.9b03747

    Web of Science

    researchmap

  • Effect of CuFe2O4 ferrite on photocatalysis and carrier dynamics of electrospun α-Fe2O3 nanofibers by time-resolved transient absorption spectroscopy Reviewed

    Pei-Hsuan Hung, Junie Jhon, M. Vequizo, Ren-An Wu, Akira Yamakata, Wenjea J. Tseng

    Ceram. Int.   45 ( 12 )   15676 - 15680   2019.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.ceramint.2019.05.080

    Web of Science

    researchmap

  • Oxygen-Doped Ta3N5 Nanoparticles for Enhanced Z-Scheme Carbon Dioxide Reduction with a Binuclear Ruthenium(II) Complex under Visible Light Reviewed

    Kanemichi Muraoka, Junie Jhon, M. Vequizo, Ryo Kuriki, Akira Yamakata, Tomoki Uchiyama, Daling Lu, Yoshiharu Uchimoto, Osamu Ishitani, Kazuhiko Maeda

    ChemPhotoChem   3 ( 10 )   1027 - 1033   2019.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/cptc.201900120

    Web of Science

    researchmap

  • Improvement of photocatalytic activity under visible-light irradiation by heterojunction of Cu ion loaded WO3 and Cu ion loaded N-TiO2 Reviewed

    Tomoya Iihoshi, Takeshi Ohwaki, Junie Jhon, M. Vequizo, Akira Yamakata

    Applied Catalysis B: Environmental   248   249 - 254   2019.2

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.apcatb.2019.01.046

    researchmap

  • Sodium titanium oxide bronze nanoparticles synthesized via concurrent reduction and Na+-doping into TiO2(B) Reviewed

    Hasegawa, George, Tanaka, Moeko, Vequizo, Junie Jhon M., Yamakata, Akira, Hojo, Hajime, Kobayashi, Makoto, Kakihana, Masato, Inada, Miki, Akamatsu, Hirofumi, Hayashi, Katsuro

    NANOSCALE   11 ( 3 )   1442 - 1450   2019.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c8nr08372j

    Web of Science

    researchmap

  • Clear and transparent nanocrystals for infrared-responsive carrier transfer Reviewed

    Sakamoto, M., Kawawaki, T., Kimura, M., Vequizo, J.J.M., Matsunaga, H., Ranasinghe, C.S.K., Yamakata, A., Matsuzaki, H., Furube, A., Teranishi, T.

    Nature communications   10 ( 1 )   406 - 406   2019

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s41467-018-08226-2

    Scopus

    researchmap

  • Near infrared light induced plasmonic hot hole transfer at a nano-heterointerface Reviewed

    Zichao Lian, Masanori Sakamoto, Hironori Matsunaga, Junie Jhon M. Vequizo, Akira Yamakata, Mitsutaka Haruta, Hiroki Kurata, Wataru Ota, Tohru Sato, Toshiharu Teranishi

    Nature Communications   9 ( 1 )   2314 - 2314   2018.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Nature Publishing Group  

    DOI: 10.1038/s41467-018-04630-w

    Scopus

    researchmap

  • Curious Behaviors of Photogenerated Electrons and Holes at the Defects on Anatase, Rutile, and Brookite TiO2 Powders: A Review Invited Reviewed

    Akira Yamakata, Junie Jhon, M. Vequizo

    J. Photochem. Photobiol. C-Photochem. Rev.   40   234 - 243   2018.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.jphotochemrev.2018.12.001

    Web of Science

    researchmap

  • Plasmonic p–n Junction for Infrared Light to Chemical Energy Conversion Reviewed

    Zichao Lian, Masanori Sakamoto, Junie Jhon, M. Vequizo, Chandana Sampath, Kumara Ranasinghe, Akira Yamakata, Takuro Nagai, Koji Kimoto, Yoichi Kobayashi, Naoto Tamai, Toshiharu Teranishi

    J. Am. Chem. Soc.   141 ( 6 )   2446 - 2450   2018.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jacs.8b11544

    Web of Science

    researchmap

  • Expansion of the photoresponse window of a BiVO4 photocatalyst by doping with chromium(VI) Reviewed

    Kazuya Okuno, Hideki Kato, Junie Jhon, M. Vequizo, Akira Yamakata, Hisayoshi Kobayashi, Makoto Kobayashi, Masato Kakihana

    RSC Advances   8 ( 67 )   38140 - 38145   2018.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C8RA07830K

    Web of Science

    researchmap

  • A Copolymerization Approach to Improving Ru(II)-Complex/C3N4 Hybrid Photocatalysts for Visible-Light CO2 Reduction Reviewed

    Constantine Tsounis, Ryo Kuriki, Kengo Shibata, Junie Jhon, M. Vequizo, Daling Lu, Akira Yamakata, Osamu Ishitani, Rose Amal, Kazuhiko Maeda

    ACS Sustainable Chemistry & Engineering   6 ( 11 )   15333 - 15340   2018.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acssuschemeng.8b03782

    Web of Science

    researchmap

  • Effects of Interfacial Electron Transfer in Metal Complex−Semiconductor Hybrid Photocatalysts on Z‑Scheme CO2 Reduction under Visible Light Reviewed

    Akinobu Nakada, Ryo Kuriki, Keita Sekizawa, Shunta Nishioka, Junie Jhon, M. Vequizo, Tomoki Uchiyama, Nozomi Kawakami, Daling Lu, Akira Yamakata, Yoshiharu Uchimoto, Osamu Ishitani, Kazuhiko Maeda

    ACS Catalysis   8 ( 10 )   9744 - 9754   2018.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acscatal.8b03062

    Web of Science

    researchmap

  • Undoped Layered Perovskite Oxynitride Li2 LaTa2 O6 N for Photocatalytic CO2 Reduction with Visible Light. Reviewed International journal

    Takayoshi Oshima, Tom Ichibha, Ken Sinkou Qin, Kanemichi Muraoka, Junie Jhon M Vequizo, Keisuke Hibino, Ryo Kuriki, Shunsuke Yamashita, Kenta Hongo, Tomoki Uchiyama, Kotaro Fujii, Daling Lu, Ryo Maezono, Akira Yamakata, Hideki Kato, Koji Kimoto, Masatomo Yashima, Yoshiharu Uchimoto, Masato Kakihana, Osamu Ishitani, Hiroshi Kageyama, Kazuhiko Maeda

    Angewandte Chemie (International ed. in English)   57 ( 27 )   8154 - 8158   2018.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    Oxynitrides are promising visible-light-responsive photocatalysts, but their structures are almost confined with three-dimensional (3D) structures such as perovskites. A phase-pure Li2 LaTa2 O6 N with a layered perovskite structure was successfully prepared by thermal ammonolysis of a lithium-rich oxide precursor. Li2 LaTa2 O6 N exhibited high crystallinity and visible-light absorption up to 500 nm. As opposed to well-known 3D oxynitride perovskites, Li2 LaTa2 O6 N supported by a binuclear RuII complex was capable of stably and selectively converting CO2 into formate under visible light (λ>400 nm). Transient absorption spectroscopy indicated that, as compared to 3D oxynitrides, Li2 LaTa2 O6 N possesses a lower density of mid-gap states that work as recombination centers of photogenerated electron/hole pairs, but a higher density of reactive electrons, which is responsible for the higher photocatalytic performance of this layered oxynitride.

    DOI: 10.1002/anie.201803931

    PubMed

    researchmap

  • Binary flux-promoted formation of trigonal ZnIn2S4 layered crystals using ZnS-containing industrial waste and their photocatalytic performance for H2 production Reviewed

    Mirabbos Hojamberdiev, Yanfei Cai, Junie Jhon, M. Vequizo, Mohammad Mansoob Khan, Ronald Vargas, Kunio Yubuta, Akira Yamakata, Katsuya Teshima, Masashi Hasegawa

    Green Chemistry   20 ( 16 )   3845 - 3856   2018.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C8GC01746H

    Web of Science

    researchmap

  • Enhanced photocatalytic NOx decomposition of visible-light responsive F-TiO2/(N,C)-TiO2 by charge transfer between F-TiO2 and (N,C)-TiO2through their doping levels Reviewed

    Shio Komatsuda, Yusuke Asakura, Junie Jhon, M. Vequizo, Akira Yamakata, Shu Yin

    Appl. Catal. B-Environ.   238   358 - 364   2018.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.apcatb.2018.07.038

    Web of Science

    researchmap

  • Excited-State Dynamics of Graphitic Carbon Nitride Photocatalyst and Ultrafast Electron Injection to a Ru(II) Mononuclear Complex for Carbon Dioxide Reduction Reviewed

    Ryo Kuriki, Chandana Sampath, Kumara Ranasinghe, Yasuomi Yamazaki, Akira Yamakata, Osamu Ishitani, Kazuhiko Maeda

    J. Phys. Chem. C.   122 ( 29 )   16795 - 16802   2018.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpcc.8b03996

    Web of Science

    researchmap

  • Homogeneous Electron Doping into Non-Stoichiometric Strontium Titanate Improves Its Photocatalytic Activity for Hydrogen and Oxygen Evolution Reviewed

    Shunta Nishioka, Junji Hyodo, Junie Jhon, M. Vequizo, Shunsuke Yamashita, Hiromu Kumagai, Koji Kimoto, Akira Yamakata, Yoshihiro Yamazaki, Kazuhiko Maeda

    ACS Catal.   8 ( 8 )   7190 - 7200   2018.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acscatal.8b01379

    Web of Science

    researchmap

  • Fabrication of robust TiO2 thin films by atomized spray pyrolysis deposition for photoelectrochemical water oxidation Reviewed

    Chandana Sampath Kumara Ranasinghe, Junie Jhon M. Vequizo, Akira Yamakata

    Journal of Photochemistry and Photobiology A: Chemistry   358   320 - 326   2018.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier B.V.  

    DOI: 10.1016/j.jphotochem.2017.09.006

    Scopus

    researchmap

  • Role of CoOx cocatalyst on Ta3N5 photocatalysts studied by transient visible to mid-infrared absorption spectroscopy Reviewed

    Junie Jhon M. Vequizo, Mirabbos Hojamberdiev, Katsuya Teshima, Akira Yamakata

    Journal of Photochemistry and Photobiology A: Chemistry   358   315 - 319   2018.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier B.V.  

    DOI: 10.1016/j.jphotochem.2017.09.005

    Scopus

    researchmap

  • Structural changes of water molecules during photoelectrochemical water oxidation on TiO2 thin film electrodes Reviewed

    Chandana Sampath Kumara Ranasinghe, Akira Yamakata

    Physical Chemistry Chemical Physics   20 ( 5 )   3388 - 3394   2018.2

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry  

    DOI: 10.1039/c7cp06646e

    Scopus

    researchmap

  • Oxygen induced enhancement of NIR emission in brookite TiO2 powders: Comparison with rutile and anatase TiO2 powders Reviewed

    Junie Jhon M. Vequizo, Sunao Kamimura, Teruhisa Ohno, Akira Yamakata

    Physical Chemistry Chemical Physics   20 ( 5 )   3241 - 3248   2018.2

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry  

    DOI: 10.1039/c7cp06975h

    Scopus

    researchmap

  • Visible-light CO2 reduction over a ruthenium(ii)-complex/C3N4 hybrid photocatalyst: The promotional effect of silver species Reviewed

    Kazuhiko Maeda, Daehyeon An, Chandana Sampath Kumara Ranasinghe, Tomoki Uchiyama, Ryo Kuriki, Tomoki Kanazawa, Daling Lu, Shunsuke Nozawa, Akira Yamakata, Yoshiharu Uchimoto, Osamu Ishitani

    Journal of Materials Chemistry A   6 ( 20 )   9708 - 9715   2018

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry  

    DOI: 10.1039/c8ta03245a

    Scopus

    researchmap

  • Nitrogen/fluorine-codoped rutile titania as a stable oxygen-evolution photocatalyst for solar-driven Z-scheme water splitting Reviewed

    Akinobu Miyoshi, Junie Jhon M. Vequizo, Shunta Nishioka, Yuma Kato, Muneaki Yamamoto, Shunsuke Yamashita, Toshiyuki Yokoi, Akihide Iwase, Shunsuke Nozawa, Akira Yamakata, Tomoko Yoshida, Koji Kimoto, Akihiko Kudo, Kazuhiko Maeda

    Sustainable Energy & Fuels   2   2025 - 2035   2018

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/C8SE00191J

    researchmap

  • Engaging the flux-grown La1-xSrxFe1-yTiyO3 crystals in visible-light-driven photocatalytic hydrogen generation Reviewed

    Mirabbos Hojamberdiev, Kenta Kawashima, Mahesh Kumar, Akira Yamakata, Kunio Yubuta, Aleksander Gurlo, Masashi Hasegawa, Kazunari Domen, Katsuya Teshima

    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY   42 ( 44 )   27024 - 27033   2017.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.ijhydene.2017.09.036

    Web of Science

    researchmap

  • Cation-dependent restructure of the electric double layer on CO-covered Pt electrodes: Difference between hydrophilic and hydrophobic cations Reviewed

    Akira Yamakata, Masatoshi Osawa

    JOURNAL OF ELECTROANALYTICAL CHEMISTRY   800   19 - 24   2017.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.jelechem.2016.12.034

    Web of Science

    researchmap

  • Elucidating the impact of A-site cation change on photocatalytic H-2 and O-2 evolution activities of perovskite-type LnTaON(2) (Ln = La and Pr) Reviewed

    Mirabbos Hojamberdiev, Maged F. Bekheet, Judy N. Hart, Junie Jhon M. Vequizo, Akira Yamakata, Kunio Yubuta, Aleksander Gurlo, Masashi Hasegawa, Kazunari Domen, Katsuya Teshima

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   19 ( 33 )   22210 - 22220   2017.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c7cp03714g

    Web of Science

    researchmap

  • Interfacial Manipulation by Rutile TiO2 Nanoparticles to Boost CO2 Reduction into CO on a Metal-Complex/Semiconductor Hybrid Photocatalyst Reviewed

    Keisuke Wada, Chandana Sampath Kumara Ranasinghe, Ryo Kuriki, Akira Yamakata, Osamu Ishitani, Kazuhiko Maeda

    ACS APPLIED MATERIALS & INTERFACES   9 ( 28 )   23869 - 23877   2017.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsami.7b07484

    Web of Science

    researchmap

  • Solar-driven Z-scheme water splitting using tantalum/nitrogen co-doped rutile titania nanorod as an oxygen evolution photocatalyst Reviewed

    Akinobu Nakada, Shunta Nishioka, Junie Jhon M. Vequizo, Kanemichi Muraoka, Tomoki Kanazawa, Akira Yamakata, Shunsuke Nozawa, Hiromu Kumagai, Shin-ichi Adachi, Osamu Ishitani, Kazuhiko Maeda

    JOURNAL OF MATERIALS CHEMISTRY A   5 ( 23 )   11710 - 11719   2017.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c6ta10541f

    Web of Science

    researchmap

  • Trapping-Induced Enhancement of Photocatalytic Activity on Brookite TiO2 Powders: Comparison with Anatase and Rutile TiO2 Powders Reviewed

    Junie Jhon M. Vequizo, Hironori Matsunaga, Tatsuya Ishiku, Sunao Karnimura, Teruhisa Ohno, Akira Yamakata

    ACS CATALYSIS   7 ( 4 )   2644 - 2651   2017.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acscatal.7b00131

    Web of Science

    researchmap

  • The contrasting effect of the Ta/Nb ratio in (111)-layered B-site deficient hexagonal perovskite Ba5Nb4-xTaxO15 crystals on visible-light-induced photocatalytic water oxidation activity of their oxynitride derivatives Reviewed

    Mirabbos Hojamberdiev, Maged F. Bekheet, Ehsan Zahedi, Hajime Wagata, Junie Jhon M. Vequizo, Akira Yamakata, Kunio Yubuta, Aleksander Gurlo, Kazunari Domen, Katsuya Teshima

    DALTON TRANSACTIONS   45 ( 31 )   12559 - 12568   2016.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c6dt02095j

    Web of Science

    researchmap

  • Photocatalytic property of metal ion added SrTiO3 to Overall H2O splitting Reviewed

    Yoshihisa Sakata, Yoshiko Miyoshi, Tatsuya Maeda, Kohki Ishikiriyama, Yuki Yamazaki, Hayao Imamura, Yeilin Ham, Takashi Hisatomi, Jun Kubota, Akira Yamakata, Kazunari Domen

    APPLIED CATALYSIS A-GENERAL   521   227 - 232   2016.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.apcata.2015.12.013

    Web of Science

    researchmap

  • Enhancement of photoelectrochemical activity of SnS thin-film photoelectrodes using TiO2, Nb2O5, and Ta2O5 metal oxide layers Reviewed

    Junie Jhon M. Vequizo, Masanori Yokoyama, Masaya Ichimura, Akira Yamakata

    APPLIED PHYSICS EXPRESS   9 ( 6 )   067101   2016.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.7567/APEX.9.067101

    Web of Science

    researchmap

  • 酸化チタン光触媒のキャリアーダイナミクス-粉末におけるアナターゼとルチルの特異的な挙動- Reviewed

    山方啓

    光化学   47 ( 1 )   25 - 32   2016.4

     More details

  • Dynamics of Photogenerated Charge Carriers on Ni- and Ta-Doped SrTiO3 Photocatalysts Studied by Time-Resolved Absorption and Emission Spectroscopy Reviewed

    Akira Yamakata, Masayuki Kawaguchi, Ryosuke Murachi, Masahiro Okawa, Itaru Kamiya

    JOURNAL OF PHYSICAL CHEMISTRY C   120 ( 15 )   7997 - 8004   2016.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpcc.6b01494

    Web of Science

    researchmap

  • Nature-Inspired, Highly Durable CO2 Reduction System Consisting of a Binuclear Ruthenium(II) Complex and an Organic Semiconductor Using Visible Light Reviewed

    Ryo Kuriki, Hironori Matsunaga, Takuya Nakashima, Keisuke Wada, Akira Yamakata, Osamu Ishitani, Kazuhiko Maeda

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   138 ( 15 )   5159 - 5170   2016.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jacs.6b01997

    Web of Science

    researchmap

  • KCl flux-induced growth of isometric crystals of cadmium-containing early transition-metal (Ti4+, Nb5+, and Ta5+) oxides and nitridability to form their (oxy)nitride derivatives under an NH3 atmosphere for water splitting application Reviewed

    Mirabbos Hojamberdiev, Hajime Wagata, Kunio Yubuta, Kenta Kawashima, Junie Jhon M. Vequizo, Akira Yamakata, Shuji Oishi, Kazunari Domen, Katsuya Teshima

    APPLIED CATALYSIS B-ENVIRONMENTAL   182   626 - 635   2016.3

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/bj.apcatb.2015.10.002

    Web of Science

    researchmap

  • Transient Absorption and FT-IR Analysis of the Carrier Dynamics of TiO2 Photocatalysts

    Vequizo Junie Jhon, Matsunaga Hironori, Okamura Shou, Ohno Teruhisa, Yamakata Akira

    表面科学学術講演会要旨集   36 ( 0 )   217 - 217   2016.1

     More details

    Language:English   Publisher:The Surface Science Society of Japan  

    The behavior of photocarriers in anatase, rutile, and brookite TiO&lt;sub&gt;2&lt;/sub&gt; was studied by using transient absorption and FT-IR spectroscopy. In anatase, free electrons survive &gt; 1 ms. In contrast, most of the electrons in rutile are deeply trapped at the defects. In brookite, some of the electrons are deeply trapped, but some also survive in the conduction band. FT-IR results revealed that the rate of charge accumulation is faster in anatase but slower in rutile and brookite.

    DOI: 10.14886/sssj2008.36.0_217

    CiNii Article

    researchmap

  • Flux-mediated doping of SrTiO3 photocatalysts for efficient overall water splitting Reviewed

    Yeilin Ham, Takashi Hisatomi, Yosuke Goto, Yosuke Moriya, Yoshihisa Sakata, Akira Yamakata, Jun Kubota, Kazunari Domen

    JOURNAL OF MATERIALS CHEMISTRY A   4 ( 8 )   3027 - 3033   2016

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c5ta04843e

    Web of Science

    researchmap

  • Femto-second time-resolved absorption study on photocatalysts

    Matsunaga Hironori, Vequizo Junie Jhon, Yamakata Akira

    Abstract of annual meeting of the Surface Science of Japan   36   218 - 218   2016

     More details

    Language:Japanese   Publisher:The Surface Science Society of Japan  

    DOI: 10.14886/sssj2008.36.0_218

    CiNii Article

    researchmap

  • Behavior of photogenerated charge carriers on metal-particle loaded photocatalysts studied by time-resolved absorption spectroscopy

    Yamakata Akira

    Abstract of annual meeting of the Surface Science of Japan   36   216 - 216   2016

     More details

    Language:Japanese   Publisher:The Surface Science Society of Japan  

    DOI: 10.14886/sssj2008.36.0_216

    CiNii Article

    researchmap

  • Morphology-sensitive trapping states of photogenerated charge carriers on SrTiO3 particles studied by time-resolved visible to Mid-IR absorption spectroscopy: The effects of molten salt flux treatments Reviewed

    Akira Yamakata, Ham Yeilin, Masayuki Kawaguchi, Takashi Hisatomi, Jun Kubota, Yoshihisa Sakata, Kazunari Domen

    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY   313   168 - 175   2015.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.jphotochem.2015.05.016

    Web of Science

    J-GLOBAL

    researchmap

  • Distinctive Behavior of Photogenerated Electrons and Holes in Anatase and Rutile TiO2 Powders Reviewed

    Akira Yamakata, Junie Jhon M. Vequizo, Hironori Matsunaga

    JOURNAL OF PHYSICAL CHEMISTRY C   119 ( 43 )   24538 - 24545   2015.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpcc.5b09236

    Web of Science

    J-GLOBAL

    researchmap

  • NH3-Assisted Flux Growth of Cube-like BaTaO2N Submicron Crystals in a Completely Ionized Nonaqueous High-Temperature Solution and Their Water Splitting Activity Reviewed

    Mirabbos Hojamberdiev, Kunio Yubuta, Junie Jhon M. Vequizo, Akira Yamakata, Shuji Oishi, Kazunari Domen, Katsuya Teshima

    CRYSTAL GROWTH & DESIGN   15 ( 9 )   4663 - 4671   2015.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.cgd.5b00927

    Web of Science

    J-GLOBAL

    researchmap

  • NH3-Assisted Flux-Mediated Direct Growth of LaTiO2N Crystallites for Visible-Light-Induced Water Splitting Reviewed

    Kenta Kawashirna, Mirabbos Hojamberdiev, Hajirne Wagata, Kunio Yubuta, Junie Jhon M. Vequizo, Akira Yamakata, Shuji Oishi, Kazunari Domen, Katsuya Teshima

    JOURNAL OF PHYSICAL CHEMISTRY C   119 ( 28 )   15896 - 15904   2015.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpcc.5b03718

    Web of Science

    J-GLOBAL

    researchmap

  • 時間分解可視中赤外分光法を用いた光励起キャリアーの反応活性評価

    山方啓, 久保田純, 堂免一成

    触媒   115   52 - 54   2015.3

     More details

    Language:Japanese  

    J-GLOBAL

    researchmap

  • Behavior and Energy State of Photogenerated Charge Carriers in Single-Crystalline and Polycrystalline Powder SrTiO3 Studied by Time-Resolved Absorption Spectroscopy in the Visible to Mid-Infrared Region Reviewed

    Akira Yamakata, Junie Jhon M. Vequizo, Masayuki Kawaguchi

    JOURNAL OF PHYSICAL CHEMISTRY C   119 ( 4 )   1880 - 1885   2015.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp510647b

    Web of Science

    J-GLOBAL

    researchmap

  • Surface-enhanced IR absorption spectroscopy of the KcsA potassium channel upon application of an electric field Reviewed

    Akira Yamakata, Hirofumi Shimizu, Shigetoshi Oiki

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   17 ( 33 )   21104 - 21111   2015

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c5cp02681d

    Web of Science

    J-GLOBAL

    researchmap

  • Behavior and Energy States of Photogenerated Charge Carriers on Pt- or CoOx-Loaded LaTiO2N Photocatalysts: Time-Resolved Visible to Mid-Infrared Absorption Study Reviewed

    Akira Yamakata, Masayuki Kawaguchi, Naoyuki Nishimura, Tsutomu Minegishi, Jun Kubota, Kazunari Domen

    JOURNAL OF PHYSICAL CHEMISTRY C   118 ( 41 )   23897 - 23906   2014.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp508233z

    Web of Science

    J-GLOBAL

    researchmap

  • 電極界面におけるイオンの水和殻崩壊過程の時間分解赤外分光観察 Reviewed

    山方啓, 大澤雅俊, 森田明弘

    Electrochemistry 電気化学および工業物理化学   82 ( 9 )   771 - 776   2014.9

     More details

  • Behavior of Photogenerated Charge Carriers on Several Photocatalysts Studied by Time-resolved IR Absorption Spectroscopy. Reviewed

    天野史章, 山方啓

    触媒   56 ( 2 )   88 - 94   2014.4

     More details

  • Properties of N-H Local Vibration Modes in GaAsN Grown by Chemical Beam Epitaxy

    Kazuma Ikeda, Akira Yamakata, Koushiro Demizu, Nobuaki Kojima, Oshio Ohshita, Masafumi Yamaguchi

    2014 IEEE 40TH PHOTOVOLTAIC SPECIALIST CONFERENCE (PVSC)   1821 - 1824   2014

     More details

    Language:English   Publishing type:Research paper (international conference proceedings)  

    DOI: 10.1109/PVSC.2014.6925276

    Web of Science

    researchmap

  • Effect of Particle Size on the Photocatalytic Activity of WO3 Particles for Water Oxidation Reviewed

    Fumiaki Amano, Eri Ishinaga, Akira Yamakata

    JOURNAL OF PHYSICAL CHEMISTRY C   117 ( 44 )   22584 - 22590   2013.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp408446u

    Web of Science

    J-GLOBAL

    researchmap

  • Real-Time Observation of the Destruction of Hydration Shells Reviewed

    Akira Yamakata, Eiji Soeta, Tatsuya Ishiyama, Masatoshi Osawa, Akihiro Morita

    J. Am. Chem. Soc.   135 ( 40 )   977 - 988   2013.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp4078882

    researchmap

  • Real-Time Observation of the Destruction of Hydration Shells under Electrochemical Force Reviewed

    Akira Yamakata, Eiji Soeta, Tatsuya Ishiyama, Masatoshi Osawa, Akihiro Morita

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   135 ( 40 )   15033 - 15039   2013.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja408326d

    Web of Science

    J-GLOBAL

    researchmap

  • Photocatalytic activity of titania particles calcined at high temperature: Investigating deactivation Reviewed

    Fumiaki Amano, Masashi Nakata, Kenji Asami, Akira Yamakata

    Chemical Physics Letters   579   111 - 113   2013.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.cplett.2013.06.038

    Scopus

    J-GLOBAL

    researchmap

  • Structural changes of the KcsA potassium channel upon application of the electrode potential studied by surface-enhanced IR absorption spectroscopy Reviewed

    Akira Yamakata, Hirofumi Shimizu, Masatoshi Osawa, Shigetoshi Oiki

    CHEMICAL PHYSICS   419   224 - 228   2013.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.chemphys.2013.02.035

    Web of Science

    J-GLOBAL

    researchmap

  • Electronically cross-linked PbS quantum dot networks using polymers as surface ligands Reviewed

    Wei Lü, Yue Yang, Akira Yamakata, Itaru Kamiya

    Nano   8 ( 2 )   1350013.1-1350013.7   2013.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1142/S1793292013500136

    Scopus

    J-GLOBAL

    researchmap

  • Cobalt-Modified Porous Single-Crystalline LaTiO2N for Highly Efficient Water Oxidation under Visible Light Reviewed

    Fuxiang Zhang, Akira Yamakata, Kazuhiko Maeda, Yosuke Moriya, Tsuyoshi Takata, Jun Kubota, Katsuya Teshima, Shuji Oishi, Kazunari Domen

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   134 ( 20 )   8348 - 8351   2012.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja301726c

    Web of Science

    J-GLOBAL

    researchmap

  • Infrared Spectroscopic Study of the Potential Change at Cocatalyst Particles on Oxynitride Photocatalysts for Water Splitting by Visible Light Irradiation Reviewed

    Xuwang Lu, Athula Bandara, Masao Katayama, Akira Yamakata, Jun Kubota, Kazunari Domen

    JOURNAL OF PHYSICAL CHEMISTRY C   115 ( 48 )   23902 - 23907   2011.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp207484q

    Web of Science

    J-GLOBAL

    researchmap

  • Effect of Photoexcited Electron Dynamics on Photocatalytic Efficiency of Bismuth Tungstate Reviewed

    Fumiaki Amano, Akira Yamakata, Kohei Nogami, Masatoshi Osawa, Bunsho Ohtani

    JOURNAL OF PHYSICAL CHEMISTRY C   115 ( 33 )   16598 - 16605   2011.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp2051257

    Web of Science

    J-GLOBAL

    researchmap

  • Potential-Dependent Recombination Kinetics of Photogenerated Electrons in n- and p-Type GaN Photoelectrodes Studied by Time-Resolved IR Absorption Spectroscopy Reviewed

    Akira Yamakata, Masaaki Yoshida, Jun Kubota, Masatoshi Osawa, Kazunari Domen

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   133 ( 29 )   11351 - 11357   2011.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja203639q

    Web of Science

    J-GLOBAL

    researchmap

  • Quantum Dots and Wells for Novel Light-Energy Conversions

    YAMAKATA Akira

    触媒   53 ( 3 )   201 - 201   2011.4

     More details

  • Structure and Behavior of Water at the Electrochemical Interface Studied by Surface-Enhanced Infrared Absorption Spectroscopy Reviewed

    Masatshi Osawa, Akira Yamakata

    BUNSEKI KAGAKU   60 ( 1 )   1 - 9   2011.1

     More details

    Language:Japanese   Publishing type:Research paper (scientific journal)  

    DOI: 10.2116/bunsekikagaku.60.1

    Web of Science

    CiNii Article

    researchmap

  • Destruction of the Water Layer on a Hydrophobic Surface Induced by the Forced Approach of Hydrophilic and Hydrophobic Cations Reviewed

    Akira Yamakata, Masatoshi Osawa

    JOURNAL OF PHYSICAL CHEMISTRY LETTERS   1 ( 9 )   1487 - 1491   2010.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jz100424e

    Web of Science

    researchmap

  • Correlation between Photoexcited Electron Lifetimes and Photocatalytic Activities of Bismuth Tungstate Particles Reviewed

    AMANO Fumiaki, YAMAKATA Akira, NOGAMI Kohei, OSAWA Masatoshi, OHTANI Bunsho

    触媒   52 ( 2 )   128 - 130   2010.3

     More details

    Language:Japanese   Publisher:触媒学会  

    CiNii Article

    CiNii Books

    researchmap

  • Dynamics of photogenerated charge carriers on photocatalysts for the water splitting reaction : relation between the carrier dynamics and the steady state reactions Reviewed

    YAMAKATA Akira

    分光研究 = Journal of the spectroscopical research of Japan   59 ( 1 )   12 - 19   2010.2

     More details

    Language:Japanese   Publisher:日本分光学会  

    CiNii Article

    researchmap

  • ATR-SEIRAS Investigation of the Fermi Level of Pt Cocatalyst on a GaN Photocatalyst for Hydrogen Evolution under Irradiation Reviewed

    Masaaki Yoshida, Akira Yamakata, Kazuhiro Takanabe, Jun Kubota, Masatoshi Osawa, Kazunari Domen

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   131 ( 37 )   13218 - 13219   2009.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja904991p

    Web of Science

    J-GLOBAL

    researchmap

  • Photoexcited processes on metal surfaces : from gas/solid toward liquid/solid interfaces Reviewed

    YAMAKATA Akira, OSAWA Masatoshi

    Photochemistry   40 ( 2 )   78 - 84   2009.8

     More details

    Language:Japanese   Publisher:光化学協会  

    CiNii Article

    CiNii Books

    researchmap

  • Destruction of the hydration shell around tetraaolkylammonium ions at the electrochemical interface Reviewed

    Akira Yamakata, Masatoshi Osawa

    Journal of the American Chemical Society   131 ( 20 )   6892 - 6893   2009.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja8100374

    Scopus

    J-GLOBAL

    researchmap

  • Acceleration of electrolysis of water by the adsorption of 4, 4'-bipyridine on Ag electrode : creation of reaction center by organic molecules Reviewed

    UCHIDA Taro, YAMAKATA Akira, SASAKI Youichi, OSAWA Masatoshi

    觸媒 = Catalyst   51 ( 2 )   129 - 131   2009.3

     More details

    Language:Japanese   Publisher:触媒学会  

    CiNii Article

    J-GLOBAL

    researchmap

  • Electrocatalytic Reactions Studied by Time-resolved Surface-enhanced Infrared Spectroscopy Reviewed

    SAMJESKE Gabor, YAMAKATA Akira, UCHIDA Taro, OSAWA Masatoshi

    Journal of the Surface Science Society of Japan   30 ( 2 )   68 - 74   2009.2

     More details

    Language:Japanese   Publisher:日本表面科学会  

    DOI: 10.1380/jsssj.30.68

    CiNii Article

    J-GLOBAL

    researchmap

  • Visible Light Responsive Pristine Metal Oxide Photocatalyst: Enhancement of Activity by Crystallization under Hydrothermal Treatment Reviewed

    Fumiaki Amano, Akira Yamakata, Kohei Nogami, Masatoshi Osawa, Bunsho Ohtani

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   130 ( 52 )   17650 - +   2008.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja807438z

    Web of Science

    PubMed

    CiNii Article

    J-GLOBAL

    researchmap

  • Dynamics of the Electric Double Layer of CO-covered Pt Electrode Reviewed

    YAMAKATA Akira, OSAWA Masatoshi

    J. Surf. Sci. Soc. Jpn.   29 ( 9 )   526 - 531   2008.9

     More details

    Language:Japanese   Publisher:The Surface Science Society of Japan  

    The dynamics of the water molecules on a CO-covered Pt electrode has been studied by laser-induced potential transient measurements. This is a model system to elucidate the behavior of water molecules in the electric double layer during electrochemical reactions. At the potentials where CO is stably adsorbed, the Pt surface is negatively charged and water molecules are oriented pointing the hydrogen atoms toward the surface. The laser irradiation heats the interface and disturbs the orientation of water, which induces a potential jump toward the negative direction. We found that the amplitude of the potential jump on the CO-covered surface is much larger than on the CO-free surface. The finding suggests that the water molecules are more flexible on the CO-covered surface due to the weaker water-CO interaction than water-Pt interaction. Stronger laser pulse irradiation additionally induces the desorption of CO, which result in the adsorption of water with the hydrogen atom pointing toward the surface and induces a positive potential shift. The potential shift takes ∼70 microseconds to reach the maximum, which becomes slower as the electric field becomes intense. The intense field and hydrogen-bonded cations affect water structure in a long range and the collective motion of the water layers.

    DOI: 10.1380/jsssj.29.526

    CiNii Article

    CiNii Books

    researchmap

  • Hydrogen evolution reaction catalyzed by proton-coupled redox cycle of 4,4 &apos;-bipyridine monolayer adsorbed on silver electrodes Reviewed

    Taro Uchida, Hirokazu Mogami, Akira Yamakata, Yoichi Sasaki, Masatoshi Osawa

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   130 ( 33 )   10862 - +   2008.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja803446s

    Web of Science

    PubMed

    CiNii Article

    J-GLOBAL

    researchmap

  • Dynamics of double-layer restructuring on a platinum electrode covered by CO: Laser-induced potential transient measurement Reviewed

    Akira Yamakata, Masatoshi Osawa

    JOURNAL OF PHYSICAL CHEMISTRY C   112 ( 30 )   11427 - 11432   2008.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp8018149

    Web of Science

    CiNii Article

    J-GLOBAL

    researchmap

  • Surface-enhanced infrared absorption spectroscopic studies of adsorbed nitrate, nitric oxide, and related compounds 1: Reduction of adsorbed NO on a platinum electrode Reviewed

    Kou Nakata, Akinori Okubo, Katsuaki Shimazu, Akira Yamakata, Shen Ye, Masatoshl Osawa

    LANGMUIR   24 ( 8 )   4352 - 4357   2008.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/la703394z

    Web of Science

    PubMed

    CiNii Article

    J-GLOBAL

    researchmap

  • Surface-enhanced infrared absorption spectroscopic studies of adsorbed nitrate, nitric oxide, and related compounds 2: Nitrate ion adsorption at a platinum electrode Reviewed

    Kou Nakata, Yota Kayama, Katsuaki Shimazu, Akira Yamakata, Shen Ye, Masatoshi Osawa

    LANGMUIR   24 ( 8 )   4358 - 4363   2008.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/la703476m

    Web of Science

    PubMed

    CiNii Article

    J-GLOBAL

    researchmap

  • Structure of water at the electrified platinum-water interface: A study by surface-enhanced infrared absorption spectroscopy Reviewed

    Masatoshi Osawa, Minoru Tsushima, Hirokazu Mogami, Gabor Samjeske, Akira Yamakata

    JOURNAL OF PHYSICAL CHEMISTRY C   112 ( 11 )   4248 - 4256   2008.3

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp710386g

    Web of Science

    CiNii Article

    J-GLOBAL

    researchmap

  • 表面増強赤外吸収分光法による電極界面の超高速ダイナミクスの追跡 Reviewed

    山方 啓, 大澤 雅俊

    Electrochemistry 電気化学および工業物理化学 : denki kagaku   76 ( 3 )   208 - 213   2008.3

  • 固液界面の水分子の構造とエネルギー移動ダイナミクス Reviewed

    山方 啓

    分光研究   57 ( 1 )   23 - 24   2008

     More details

  • Time-resolved infrared absorption study of nine TiO2 photocatalysts Reviewed

    Akira Yamakata, Taka-aki Ishibashi, Hiroshi Onishi

    CHEMICAL PHYSICS   339 ( 1-3 )   133 - 137   2007.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.chemphys.2007.05.010

    Web of Science

    CiNii Article

    J-GLOBAL

    researchmap

  • How the Molecules Reach the Reaction Center? Reviewed

    YAMAKATA AKIRA

    触媒 = Catalysts & Catalysis   48 ( 8 )   611 - 611   2006.12

     More details

  • Laser-induced potential jump at the electrochemical interface probed by picosecond time-resolved surface-enhanced infrared absorption spectroscopy Reviewed

    A Yamakata, T Uchida, J Kubota, M Osawa

    JOURNAL OF PHYSICAL CHEMISTRY B   110 ( 13 )   6423 - 6427   2006.4

  • Study on photogenerated charge carriers dynamics in sulfur-doped titanium dioxide by transient IR absorption Reviewed

    Kan Takeshita, Akira Yamakata, Taka-aki Ishibashi, Hiroshi Onishi, Kazumoto Nishijima, Teruhisa Ohno

    J. photochem. Photobiol. B. Chemistry   117   269 - 275   2006.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    researchmap

  • Adsorbed structures of 4,4 '-bipyridine on Cu(111) in acid studied by STM and IR Reviewed

    YX Diao, MJ Han, LJ Wan, K Itaya, T Uchida, H Miyake, A Yamakata, M Osawa

    LANGMUIR   22 ( 8 )   3640 - 3646   2006.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/la052765w

    Web of Science

    PubMed

    CiNii Article

    J-GLOBAL

    researchmap

  • Transient IR absorption study of charge carriers photogenerated in sulfur-doped TiO2 Reviewed

    K Takeshita, A Yamakata, T Ishibashi, H Onishi, K Nishijima, T Ohno

    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY   177 ( 2-3 )   269 - 275   2006.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.jphotochem.2005.06.006

    Web of Science

    CiNii Article

    J-GLOBAL

    researchmap

  • Potential oscillations in galvanostatic electrooxidation of formic acid on platinum: A time-resolved surface-enhanced infrared study Reviewed

    G Samjeske, A Miki, S Ye, A Yamakata, Y Mukouyama, H Okamoto, M Osawa

    JOURNAL OF PHYSICAL CHEMISTRY B   109 ( 49 )   23509 - 23516   2005.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp055220j

    Web of Science

    J-GLOBAL

    researchmap

  • Time-Resolved IR Absorption Study on Solid Surfaces Reviewed

    YAMAKATA AKIRA, OSAWA MASATOSHI

    触媒 = Catalysts & Catalysis   47 ( 5 )   334 - 340   2005.8

     More details

    Language:Japanese   Publisher:触媒学会  

    CiNii Article

    CiNii Books

    researchmap

  • Time-resolved infrared absorption study of photochemical reactions over metal oxides Reviewed

    A Yamakata, T Ishibashi, K Takeshita, H Onishi

    TOPICS IN CATALYSIS   35 ( 3-4 )   211 - 216   2005.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1007/s11244-005-3826-0

    Web of Science

    J-GLOBAL

    researchmap

  • Carrier dynamics in TiO2 and Pt/TiO2 powders observed by femtosecond time-resolved near-infrared spectroscopy at a spectral region of 0.9-1.5 mu m with the direct absorption method Reviewed

    K Iwata, T Takaya, H Hamaguchi, A Yamakata, TA Ishibashi, H Onishi, H Kuroda

    JOURNAL OF PHYSICAL CHEMISTRY B   108 ( 52 )   20233 - 20239   2004.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp047531k

    Web of Science

    researchmap

  • In situ surface-enhanced infrared study of hydrogen bond pairing of complementary nucleic acid bases at the electrochemical interface Reviewed

    Y Sato, H Noda, F Mizutani, A Yamakata, M Osawa

    ANALYTICAL CHEMISTRY   76 ( 18 )   5564 - 5569   2004.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ac049303s

    Web of Science

    researchmap

  • Effect of annealing temperature on back electron transfer and distribution of deep trap sites in dye-sensitized TiO2, studied by time-resolved infrared spectroscopy Reviewed

    K Takeshita, Y Sasaki, M Kobashi, Y Tanaka, S Maeda, A Yamakata, TA Ishibashi, H Onishi

    JOURNAL OF PHYSICAL CHEMISTRY B   108 ( 9 )   2963 - 2969   2004.3

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp035416o

    Web of Science

    researchmap

  • Photodynamics of NaTaO3 catalysts for efficient water splitting Reviewed

    A Yamakata, T Ishibashi, H Kato, A Kudo, H Onishi

    JOURNAL OF PHYSICAL CHEMISTRY B   107 ( 51 )   14383 - 14387   2003.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp036473k

    Web of Science

    researchmap

  • Effects of water addition on the methanol oxidation on Pt/TiO2 photocatalyst studied by time-resolved infrared absorption spectroscopy Reviewed

    A Yamakata, TA Ishibashi, J Onishi

    JOURNAL OF PHYSICAL CHEMISTRY B   107 ( 36 )   9820 - 9823   2003.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp034997e

    Web of Science

    researchmap

  • Time-Resolved Infrared Absorption Study of Reaction Intermediate on Pt/TiO_2 Photocatalyst Reviewed

    YAMAKATA Akira, ISHIBASHI Taka-aki, ONISHI Hiroshi

    J. Surf. Sci. Soc. Jpn.   24 ( 9 )   563 - 567   2003.9

     More details

    Language:Japanese   Publisher:The Surface Science Society of Japan  

    Oxidation of 2-propanol to acetone on a Pt/TiO&lt;Sub&gt;2&lt;/Sub&gt; photocatalyst by UV pulse irradiation was observed by time-resolved IR spectroscopy (TR-IR). The hole transfer to the 2-propanol, which triggers the oxidation, was completed within 0.5 μs. Transient vibrational spectra showed a new band at 1640 cm&lt;Sup&gt;−1&lt;/Sup&gt;, which appeared immediately after the irradiation. This band gradually transformed to a band at 1700 cm&lt;Sup&gt;−1&lt;/Sup&gt;, which was assigned to the C=O stretching mode of acetone, the product of 2-propanol oxidation. Thus, the band at 1640 cm&lt;Sup&gt;−1&lt;/Sup&gt; was suggested to be the reaction intermediate that transforms to acetone. We discussed the origin of this band using density functional calculation, and an acceptable agreement was obtained with the anion radical of acetone adsorbed on the catalyst.

    DOI: 10.1380/jsssj.24.563

    CiNii Article

    CiNii Books

    researchmap

  • Effects of accumulated electrons on the decay kinetics of photogenerated electrons in Pt/TiO2 photocatalyst studied by time-resolved infrared absorption spectroscopy Reviewed

    A Yamakata, TA Ishibashi, H Onishi

    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY   160 ( 1-2 )   33 - 36   2003.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/S1010-6030(03)00217-X

    Web of Science

    researchmap

  • Microsecond kinetics of photocatalytic oxidation on Pt/TiO2 traced by vibrational spectroscopy Reviewed

    A Yamakata, T Ishibashi, H Onishi

    CHEMICAL PHYSICS LETTERS   376 ( 5-6 )   576 - 580   2003.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/S0009-2614(03)01034-0

    Web of Science

    researchmap

  • Photophysics and electron dynamics in dye-sensitized semiconductor film studied by time-resolved mid-IR spectroscopy Reviewed

    Kan Takeshita, Yutaka Sasaki, Masahiro Kobashi, Yuki Tanaka, Shuichi Maeda, Akira Yamakata, Taka-Aki Ishibashi, Hiroshi Onishi

    Journal of Physical Chemistry B   107 ( 17 )   4156 - 4161   2003.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp0275645

    Scopus

    researchmap

  • Kinetics of the photocatalytic water-splitting reaction on TiO2 and Pt/TiO2 studied by time-resolved infrared absorption spectroscopy Reviewed

    A Yamakata, T Ishibashi, H Onishi

    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL   199 ( 1-2 )   85 - 94   2003.5

     More details

  • Photophysics and electron dynamics in dye-sensitized semiconductor film studied by time-resolved mid-IR spectroscopy Reviewed

    K Takeshita, Y Sasaki, M Kobashi, Y Tanaka, S Maeda, A Yamakata, T Ishibashi, H Onishi

    JOURNAL OF PHYSICAL CHEMISTRY B   107 ( 17 )   4156 - 4161   2003.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp0275645

    Web of Science

    researchmap

  • Studies on the electron transfer reaction between TiO_2 and adsorbed dyes by time-resolved infrared spectroscopy

    TAKESHITA Kan, SASAKI Yutaka, KOBASHI Masahiro, TANAKA Yuki, MAEDA Shuichi, YAMAKATA Akira, ISHIBASHI Taka-aki, ONISHI Hiroshi

    触媒   45 ( 2 )   181 - 183   2003.3

     More details

    Language:Japanese   Publisher:触媒学会  

    CiNii Article

    CiNii Books

    researchmap

  • Electron-and Hole-transfer from TiO_2 Particles to Adsorbates Studied by Time-Resolved Infrared Absorption Spectroscopy Reviewed

    YAMAKATA Akira, ISHIBASHI Takaki, ONISHI Hiroshi

    J. Surf. Sci. Soc. Jpn.   24 ( 1 )   46 - 52   2003.1

     More details

    Language:Japanese   Publisher:The Surface Science Society of Japan  

    Behavior of the electrons and holes photogenerated in TiO&lt;Sub&gt;2&lt;/Sub&gt; particles was observed by time-resolved infrared absorption spectroscopy in the presence of oxygen, water, and methanol vapor. The electrons photogenerated by a band-gap excitation displayed a structureless, broad absorption of IR light from 3000 to 900 cm&lt;Sup&gt;−1&lt;/Sup&gt;, which was assigned to the intra-conduction-band transition and/or excitation from mid-gap traps to the conduction band. This electron-induced absorption was probed as a function of time delay after the photoexcitation. Electron decay caused by the recombination with holes and by the charge-transfer reactions with adsorbates were kinetically analyzed. The electron decay was accelerated in the presence of oxygen gas due to an electron-capture reaction at the interface, whereas was decelerated in methanol vapor due to an effective hole-capture by methoxy groups. On platinized TiO&lt;Sub&gt;2&lt;/Sub&gt; particles exposed to water vapor, a hole-capture reaction completed within 2 μs after band-gap excitation, whereas the electron-capture reaction occurred in 10 μs or later. These results demonstrate the effectiveness of this method to identify individual steps of photo-induced reactions at interfaces.

    DOI: 10.1380/jsssj.24.46

    CiNii Article

    CiNii Books

    researchmap

  • Pressure dependence of electron- and hole-consuming reactions in photocatalytic water splitting on Pt/TiO2 studied by time-resolved IR absorption spectroscopy Reviewed

    A Yamakata, T Ishibashi, H Onishi

    INTERNATIONAL JOURNAL OF PHOTOENERGY   5 ( 1 )   7 - 9   2003

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1155/s1110662x03000047

    Web of Science

    researchmap

  • Time-resolved infrared absorption study of electron- and hole-capture reactions on photoexcited Pt/TiO2 in the presence of methanol-water vapor mixture Reviewed

    A Yamakata, TA Ishibashi, H Onishi

    SCIENCE AND TECHNOLOGY IN CATALYSIS 2002   145   157 - 160   2003

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/s0167-2991(03)80184-2

    Web of Science

    researchmap

  • Microscopic identification of a bimolecular reaction intermediate Reviewed

    Hiroshi Uetsuka, Akira Sasahara, Akira Yamakata, Hiroshi Onishi

    Journal of Physical Chemistry B   106 ( 44 )   11549 - 11552   2002.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp026253r

    Scopus

    researchmap

  • Microscopic identification of a bimolecular reaction intermediate Reviewed

    H Uetsuka, A Sasahara, A Yamakata, H Onishi

    JOURNAL OF PHYSICAL CHEMISTRY B   106 ( 44 )   11549 - 11552   2002.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp026253r

    Web of Science

    researchmap

  • Electron- and hole-capture reactions on Pt/TiO2 photocatalyst exposed to methanol vapor studied with time-resolved infrared absorption spectroscopy Reviewed

    Akira Yamakata, Taka-Aki Ishibashi, Hiroshi Onishi

    Journal of Physical Chemistry B   106 ( 35 )   9122 - 9125   2002.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp025993x

    Scopus

    researchmap

  • Electron- and hole-capture reactions on Pt/TiO2 photocatalyst exposed to methanol vapor studied with time-resolved infrared absorption spectroscopy Reviewed

    A Yamakata, T Ishibashi, H Onishi

    JOURNAL OF PHYSICAL CHEMISTRY B   106 ( 35 )   9122 - 9125   2002.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp025993x

    Web of Science

    researchmap

  • Time-resolved infrared absorption studies of surface OH groups on TiO2 particles irradiated by UV pulses Reviewed

    A Yamakata, T Ishibashi, H Onishi

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   75 ( 5 )   1019 - 1022   2002.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/bcsj.75.1019

    Web of Science

    researchmap

  • 時間分解赤外分光法を用いた二酸化チタン上の光励起電子と吸着分子への電荷移動反応の観察 Reviewed

    山方 啓, 石橋 孝章, 大西 洋

    触媒   43 ( 6 )   396 - 398   2001.9

     More details

  • Water- and oxygen-induced decay kinetics of photogenerated electrons in TiO2 and Pt/TiO2: A time-resolved infrared absorption study Reviewed

    A Yamakata, T Ishibashi, H Onishi

    JOURNAL OF PHYSICAL CHEMISTRY B   105 ( 30 )   7258 - 7262   2001.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp010802w

    Web of Science

    researchmap

  • Time-resolved infrared absorption spectroscopy of photogenerated electrons in platinized TiO2 particles Reviewed

    A Yamakata, T Ishibashi, H Onishi

    CHEMICAL PHYSICS LETTERS   333 ( 3-4 )   271 - 277   2001.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/S0009-2614(00)01374-9

    Web of Science

    researchmap

  • Transport channels of X-ray beamlines at SPring-8

    Goto, S, Ohashi, H, Takeshita, K, Yabashi, M, Yamakata, A, Asano, Y, Ishikawa, T

    Nuclear Instruments &amp; Methods in Physics Research Section a-Accelerators Spectrometers Detectors and Associated Equipment   467   2001

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/S0168-9002(01)00460-0

    Web of Science

    researchmap

  • Transport channels of X-ray beamlines at SPring-8

    Akira Yamakata

    Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment   2001

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/S0168-9002(01)00460-0

    Web of Science

    researchmap

  • Exchange reaction of formate with gas-phase acetic acid on Ni(110) Reviewed

    A Yamakata, J Kubota, JN Kondo, C Hirose, K Domen, F Wakabayashi, K Tamaru

    SURFACE SCIENCE   433   210 - 214   1999.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/S0039-6028(99)00468-9

    Web of Science

    researchmap

  • In situ observation of the exchange reaction of formate with molecular formic acid on Ni(110) Reviewed

    A Yamakata, J Kubota, JN Kondo, C Hirose, K Domen, F Wakabayashi, K Tamaru

    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL   141 ( 1-3 )   73 - 82   1999.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/S1381-1169(98)00251-9

    Web of Science

    researchmap

  • Exchange reaction of adsorbed formate with gaseous formic acid on Ni(110) studied by time-resolved Fourier transform infrared reflection absorption spectroscopy Reviewed

    A Yamakata, J Kubota, JN Kondo, C Hirose, K Domen, F Wakabayashi, K Tamaru

    JOURNAL OF PHYSICAL CHEMISTRY B   102 ( 22 )   4401 - 4403   1998.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp981192b

    Web of Science

    researchmap

  • The IRAS Study of the Exchange Reaction of Formate with Gaseous Formic Acid on Ni(110) Reviewed

    YAMAKATA Akira, KUBOTA Jun, NOMURA Junko, HIROSE Chiaki, DOMEN Kazunari, WAKABAYASHI Fumitaka

    J. Surf. Sci. Soc. Jpn.   19 ( 7 )   441 - 445   1998

     More details

    Publisher:The Surface Science Society of Japan  

    The exchange reaction of formate (DCOO(a)) with gaseous formic acid (HCOOD) on Ni(110) was investigated below the decomposition temperature of formate (340 K) by means of time-resolved infrared reflection absorption spectroscopy (TR-IRAS). When HCOOD gas was admitted on DCOO(a)-covered Ni(110) at 300 K, the pre-adsorbed DCOO(a) was replaced by HCOO(a). Similar replacement was also observed by introducing H&lt;SUP&gt;12&lt;/SUP&gt; COOH gas onto H-&lt;SUP&gt;13&lt;/SUP&gt;COO(a)-covered Ni(110). In such a temperature region from 240 to 300 K, no decomposition of formate was observed. Thus it was confirmed that those pre-adsorbed formate desorbed as formic acid accompanied by the transfer of hydrogen (deuterium) atom from post-introduced formic acid. The kinetics of the exchange reaction is investigated and the mechanism of that is also discussed.

    DOI: 10.1380/jsssj.19.441

    CiNii Article

    researchmap

  • An IRAS Study of the Decomposition of Formate Adsorbed on Ni(110) Reviewed

    YAMAKATA Akira, KUBOTA Jun, NOMURA Junko, HIROSE Chiaki, DOMEN Kazunari, WAKABAYASHI Fumitaka

    Journal of the Surface Science Society of Japan   18 ( 7 )   417 - 423   1997.7

     More details

    Language:Japanese   Publisher:日本表面科学会  

    The decomposition of the surface formate on Ni(110) was studied by temperature programmed desorption (TPD) and timeresolved infrared reflection absorption spectroscopy (TR-IRAS). It was observed that dehydration proceeded simultaneously with dehydrogenation. The rate-determining step of dehydration was found to be the C-H bond cleavage of formate as is the case of dehydrogenation by analysis of the kinetic isotope effect using HCOO(a) and DCOO(a). These results suggest that the rate-determining steps of dehydration and dehydrogenation are common. We propose a mechanism in which the CO2(a) species formed via the C-H bond cleavage of formate acts as the intermediate not only for dehydrogenation but also for dehydration; dehydration takes place by dissociation of the C-O bond of CO2(a).

    DOI: 10.1380/jsssj.18.417

    CiNii Article

    researchmap

  • In situ observation of the dehydration of formate on Ni(110) Reviewed

    A Yamakata, J Kubota, JN Kondo, C Hirose, K Domen, F Wakabayashi

    JOURNAL OF PHYSICAL CHEMISTRY B   101 ( 26 )   5177 - 5181   1997.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp9703418

    Web of Science

    researchmap

  • Isotope exchange reaction of formate with molecular hydrogen on Ni(110) by IRAS Reviewed

    A Yamakata, J Kubota, JN Kondo, K Domen, C Hirose

    JOURNAL OF PHYSICAL CHEMISTRY   100 ( 46 )   18177 - 18182   1996.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jp9611986

    Web of Science

    researchmap

  • SFG study of formic acid on a Pt(110)-(1x2) surface Reviewed

    N Watanabe, K Iwatsu, A Yamakata, T Ohtani, J Kubota, JN Kondo, A Wada, K Domen, C Hirose

    SURFACE SCIENCE   357 ( 1-3 )   651 - 655   1996.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/0039-6028(96)00239-7

    Web of Science

    researchmap

▼display all

Books

  • 固体表面キャラクタリゼーション 機能性材料・ナノマテリアルのためのスペクトロスコピー (KS化学専門書)

    山下 弘巳, 吉田 寿雄, 田中 庸裕( Role: Contributor)

    講談社  2022.3  ( ISBN:4065261260

     More details

    Total pages:304   Language:Japanese

    CiNii Books

    ASIN

    researchmap

  • エネルギー変換型光触媒

    Takafumi Hisatomi, Jun Kubota, Kazunari Domen, Akira Yamakata( Role: Contributor ,  コラム9 「時間分解過渡吸収分光法によるキャリアダイナミクスの解明」)

    共立出版㈱  2017.6 

     More details

    Responsible for pages:P106-107  

    researchmap

  • 光触媒/光半導体を利用した人工光合成-最先端科学から実装技術への発展を目指して-

    Akira Yamakata( Role: Joint author ,  第3編第5章 光半導体による水分解の反応機構 時間分解分光測定を用いた光触媒のキャリアーダイナミクス)

    ㈱NTS  2017.1 

     More details

    Responsible for pages:p158-167  

    researchmap

  • 触媒の設計・反応制御 事例集-高活性、長寿命、低コスト化の実現-

    Akira Yamakata( Role: Joint author ,  第8節 赤外分光法を用いた光触媒・光電極反応の解析)

    ㈱技術情報協会  2013.4 

     More details

    Responsible for pages:P761-769  

    researchmap

  • 人工光合成 実用化に向けた最新技術~水素利用・有機物合成・エネルギー・CO2還元~

    Akira Yamakata( Role: Joint author ,  第6章第3節 光励起キャリアーの動きから見る水分解光触媒と水素貯蔵)

    ㈱情報機構  2013.3 

     More details

    Responsible for pages:p235-247  

    researchmap

  • 触媒技術の動向と展望2010

    Akira Yamakata( Role: Joint author ,  第3-8章 時間分解赤外分光法を用いた触媒反応ダイナミクス -光触媒の光励起ダイナミクス-)

    触媒学会  2010.4 

     More details

    Responsible for pages:p78-88  

    researchmap

  • 太陽電池と部材の開発・製造技術~構造・プロセスから見る、耐久性向上・高効率化を目指した各種事例~

    Akira Yamakata( Role: Joint author ,  第4-3項 太陽電池用TiO2透明導電膜の製造技術)

    ㈱情報機構  2010.3 

     More details

    Responsible for pages:p227-236  

    researchmap

  • 色材・顔料・色素の設計と開発ー発色・着色メカニズムから各種応用製品まで

    Akira Yamakata( Role: Joint author ,  第2-4章 酸化チタン)

    ㈱情報機構  2008.2 

     More details

    Responsible for pages:p267-280  

    researchmap

▼display all

MISC

  • Inorganic assembly catalysts for artificial photosynthesis: general discussion Reviewed

    Hiromu Kumagai, Leif Hammarstrom, Dong Ryeol Whang, Yuki Shinohara, Jose Martinez, Joshua Karlsson, Peter Summers, Christopher D. Windle, Masanori Kodera, Richard Cogdell, Kristine Rodulfo Tolod, Dogukan Hazar Apaydin, Etsuko Fujita, Alexander Kibler, Fengtao Fan, Elizabeth A. Gibson, Hisanao Usami, Akihide Iwase, Haruo Inoue, Akihiko Kudo, Devens Gust, Kazunari Domen, Flavia Cassiola, Katsuhiko Takagi, Sang Ook Kang, Akira Yamakata, Can Li, Licheng Sun, Hyunwoong Park, Young Soo Kang, Rengui Li, Fabio Di Fonzo, Tohru Setoyama, Osamu Ishitani

    FARADAY DISCUSSIONS   198   481 - 507   2017.6

     More details

  • 「研究現場発」【光触媒を使って水素を製造する】山方 啓

    中部経済新聞   2014.9

     More details

    Publishing type:Article, review, commentary, editorial, etc. (trade magazine, newspaper, online media)  

    researchmap

  • 「拓く研究人」【光触媒で水素安く合成】山方 啓

    日刊工業新聞   2014.5

     More details

    Publishing type:Article, review, commentary, editorial, etc. (trade magazine, newspaper, online media)  

    researchmap

  • 可視光で励起したAu/TiO2光触媒のキャリアーダイナミクス

    山方啓, VEQUIZO Junie Jhon M., 松永大典, 田中淳皓, 古南博

    触媒討論会討論会A予稿集   114th   2014

  • Research highlights International journal

    Šeila Selimović, Mark W. Tibbitt, Mehmet R. Dokmeci, Ali Khademhosseini

    Nature Chemistry   13 ( 8 )   1453 - 1456   2013

     More details

    Language:English   Publisher:Royal Society of Chemistry  

    DOI: 10.1039/c3lc90018e

    Scopus

    researchmap

  • Naイオンを添加したSrTiO3の水の完全分解反応に対する光触媒特性

    酒多喜久, 三好喜子, 田中修平, 前田竜也, 田中英之, 今村速夫, YEILIN Ham, 久富隆史, 久保田純, 堂免一成, 山方啓

    触媒討論会討論会A予稿集   112th   2013

  • 光励起キャリアーの動きとエネルギー制御

    山方啓

    化学経済   58 ( 14 )   75   2011.12

     More details

  • Hydrogen Evolution Reaction Catalyzed by 4,4'-Bipyridine Adsorbed on Metal Electrodes: A Combined Infrared and DFT Study Reviewed

    Taro Uchida, Akira Yamakata, Yoichi Sasaki, Masatoshi Osawa

    ECS Meeting Abstracts   2011.5

     More details

    Publisher:The Electrochemical Society  

    DOI: 10.1149/ma2011-01/38/1837

    researchmap

  • News Letter International journal

    Photonics Spectra Magazine   2010.7

  • 電極表面に吸着した4,4’ビピリジンが触媒する水素発生促進反応機構

    内田太郎, 山方啓, 佐々木陽一, 大澤雅俊

    電気化学秋季大会講演要旨集   2009   2009

  • Hydrogen Evolution Reaction Catalyzed by The Redox Cycle of 4,4’-Bipyridine Adsorbed on Ag electrode

    内田太郎, 山方啓, 佐々木陽一, 大澤雅俊

    日本化学会講演予稿集   89th ( 1 )   2009

  • Enhanced Hydrogen Evolution Reaction on an Ag Electrode Catalyzed by Proton-coupled Redox of 4,4'-Bipyridine Adsorbed on the Surface Reviewed

    Uchida, T, Mogami, H, Yamakata, A, Sasaki, Y, Osawa, M

    ECS Meeting Abstracts   2008

     More details

    Publisher:The Electrochemical Society  

    DOI: 10.1149/ma2008-02/47/2874

    researchmap

  • 電極表面への4,4′-ビピリジンの吸着に伴なう水素発生の促進:表面増強赤外吸収分光による検討

    内田太郎, 山方啓, 大澤雅俊

    電気化学会大会講演要旨集   74th   2007

  • ビピリジン電極修飾による電解水素発生の促進効果

    内田太郎, 山方啓, 大澤雅俊

    触媒討論会討論会A予稿集   100th   2007

  • 表面増強赤外吸収分光による吸着水素が関与した4,4′-ビピリジンの酸化還元反応の追跡

    内田太郎, 山方啓, 大澤雅俊

    日本化学会北海道支部研究発表会講演要旨集   2007   2007

▼display all

Presentations

  • 高速赤外分光を用いる光励起キャリアの挙動および光触媒反応機構の解明 Invited

    山方 啓

    日本化学会第103春季年会  2023.3.22 

     More details

    Event date: 2023.3.25

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • The role of oxygen vacancies for the enhancement of photocatalytic activity Invited

    Akira Yamakata, Kosaku Kato

    International Congress on Pure & Applied Chemistry Kota Kinabalu (ICPAC Kota Kinabalu 2022) 

     More details

    Event date: 2022.11.22 - 2022.11.27

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解分光計測による光触媒の高活性化因子の解明 Invited

    山方 啓

    2022年電気化学秋季大会 

     More details

    Event date: 2022.9.8 - 2022.9.9

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • The role of vacancies for the enhancement of photocatalytic activity Invited

    Akira Yamakata

    5th International Conference on Emerging Advanced Nanomaterials ICEAN 2024  2024.11.8 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Behaviors of Photogenerated Charge Carriers at the Defects on Photocatalysts Invited

    Akira Yamakata

    PRiME 2024  2024.10.8 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 光触媒反応の活性向上を目指した欠陥制御 Invited

    山方 啓

    公益社団法人日本セラミックス協会 第 37 回秋季シンポジウム  2024.9.10 

     More details

    Language:Japanese  

    researchmap

  • Minimizing Voltage Loss of Organic Photovoltaics by Local Dipole Moment Change of Non-Fullerene Acceptors Invited

    Akira Yamakata

    ICPAC MONGOLIA 2024  2024.8.29 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Defects Engineering for the Enhancement of Photocatalytic Reactions

    Akira Yamakata

    Taiwan International Conference on Catalysis 2024 (TICC 2024)  2024.6.20 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Curious Behaviors of Photogenerated Charge Carriers on Particulate Photocatalysts Invited

    Akira Yamakata

    AI-Mat International Workshop: Sustainable Energy Materials  2024.6.19 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Charge Separation Processes in Non-Fullerene Acceptors Studied By Time-Resolved IR Invited

    Akira Yamakata

    245th Meeting of the Electrochemical Society  2024.5.26 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解赤外分光法を用いた光触媒と有機太陽電池の動作機構解明 Invited

    山方啓

    日本分光学会・赤外ラマン分光部会シンポジウム「機能性分子・材料の赤外ラマン分光による解析」  2024.3.8 

     More details

    Language:Japanese  

    researchmap

  • Femtosecond time-resolved IR absorption study of the charge carrier dynamics in NFAs Invited

    Akira Yamakata

    International Symposium on Dynamic Exciton (ISDyEx) and International Symposium on Chiral Nanostructures for Photonique Applications  2023.12 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Binding States of Photogenerated Charge Carriers in Non-Fullerene Acceptors Studied by Broadband Transient Absorption Spectroscopy Invited

    Akira Yamakata

    International Symposium on Dynamic Exciton (ISDyEx)  2023.11 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Defects for the Enhancement of Photocatalytic Activity Invited

    Akira Yamakata

    The 28th North American Catalysis Society Meeting  2023.6 

     More details

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • Wideband Transient Absorption Spectroscopy of Dynamics Exciton Invited

    Akira Yamakata

    International Summer Course of National Yang Ming Chiao Tung Univeristy (NYCY) 2023  2023.6 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Observation of Free Carriers in Non-Fullerene Acceptors with Broadband Mid-Infrared Transient Absorption Spectroscopy Invited

    Akira Yamakata, Kosaku Kato, T. Urakami, M. Higashi, H. Sato, T. Umeyama, H. Imahori

    243rd Meeting of the Electrochemical Society  2023.5 

     More details

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解分光計測を利用した高性能光触媒の開発 Invited

    山方 啓

    界面科学コロキウム「光物質変換をささえる分光計測」  2022.12.14 

     More details

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • Properties of Defects That Determine the Charge Carrier Dynamics in Photocatalysts Invited

    Akira Yamakata, Kosaku Kato, U. Uemura, K. Asakura

    241st Meeting of the Electrochemical Society  2022.5 

     More details

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • 高性能光触媒の実現を目指した反応機構の解明 Invited

    山方啓

    光化学協会応用講座2021-社会実装が進む光触媒:基礎から人工光合成、新型コロナ対応まで-  2022.1.24 

     More details

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • 太陽光を使って水から水素を製造できる光触媒の研究 Invited

    山方啓

    2021年度南山大学・豊田工業大学連携講演会  2021.11.28 

     More details

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解分光計測を利用した光触媒の高活性化因子の解明 Invited

    山方啓

    2021年度日本表面真空学会中部支部研究会「金属酸化物表面の成長・反応・計測」  2021.11.13 

     More details

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • Behavior of Photocarriers for the Remarkable Water Splitting Photocatalysts Invited

    Akira Yamakata, Kosaku Kato

    The 11th Asian Photochemistry Conference (APC 2021)  2021.11.3 

     More details

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • Charge Carrier Dynamics at the Heterojunctions Studied by Transient Absorption Spectroscopy Invited

    Akira Yamakata, Kosaku Kato

    The 11th International Conference on Flexible and Printed Electronics (ICFPE) 2021  2021.10.1 

     More details

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • (JPA Award 2020 Award Lecture) Development of novel transient absorption spectroscopy and reaction dynamics for highly efficient photocatalysis Invited

    Akira Yamakata

    2021.9.16 

     More details

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • Core-shell Double Doping for the Remarkable Photocatalytic Water Splitting on Ga2O3” Invited

    Akira Yamakata, Junie Jhon, M. Vequizo, Kosaku Kato, Yoshihisa Sakata

    Light Energy Conversion with Metal Halide Perovskites, Semiconductor Nanostructures, and Inorganic/Organic Hybrid Materials symposium at 239th Meeting of the Electrochemical Society  2021.6.4 

     More details

  • 半導体光触媒粒子中の欠陥が及ぼす光励起キャリアの再結合促進と抑制効果 Invited

    山方啓

    光機能材料研究会 第81回講演会 「光触媒材料の設計開発と光触媒反応解析の最新動向」  2021.3.1 

     More details

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • 広帯域時間分解分光による動的エキシトン時間発展の追跡 Invited

    山方啓

    科研費・学術変⾰領域研究(A) 「動的エキシトン」 公募説明会・Kick‐off領域会議  2021.1.12 

     More details

    Presentation type:Oral presentation (invited, special)  

    researchmap

  • Behavior of Photogenerated Charge Carriers on Powder Photocatalysts Invited International conference

    Akira Yamakata

    Materials Research Meeting 2019  2019.12.11 

     More details

    Language:English  

    researchmap

  • Defects-induced enhancement of photocatalytic activity of Ga2O3 studied by time-resolved visible to mid-IR absorption spectroscopy Invited International conference

    Akira Yamakata

    The 36th International Japan-Korea Seminar on Ceramics (JK-Ceramics 36)  2019.11.22 

     More details

    Language:English  

    researchmap

  • レーザー分光を用いた光触媒反応機構の解明 Invited

    Akira Yamakata

    第29回キャラクタリゼーション講習会「触媒および表面の解析に役立つキャラクタリゼーションの基礎と実際」  2019.11.21 

     More details

    Language:Japanese  

    researchmap

  • Enhancement of photocatalytic activity of Ga2O3 by impurity doping Invited International conference

    Akira Yamakata, Junie Jhon, M. Vequizo, Shouta Ishiyama, Taishi Hiramine, Yoshihisa Sakata

    The 13th Pacific Rim Conference of Ceramic Societies (PACRIM13)  2019.10.29 

     More details

    Language:English  

    researchmap

  • Charge Carrier Dynamics on Powder Photocatalysts Studied by Time-resolved Visible to Mid-IR absorption Invited International conference

    Akira Yamakata, Junie Jhon, M. Vequizo

    International Conference on Photochemistry and Sustainable Energy (ICPSE 2019)  2019.10.19 

     More details

    Language:English  

    researchmap

  • Enhancement of photocatalytic activity of Ga2O3 based photocatalysts studied by time-resolved absorption spectroscopy Invited International conference

    Akira Yamakata

    The 24th International Conference on Semiconductor Photocatalysis and Solar Energy Conversion (SPASEC-24)  2019.10.14 

     More details

    Language:English  

    researchmap

  • Impurity Induced Enhancement of Photocatalytic Activity on Ga2O3 Invited International conference

    Akira Yamakata

    International Congress on Pure & Applied Chemistry (ICPAC) Yangon 2019  2019.8.7 

     More details

  • Behaviour of Photogenerated Charge Carriers at the Defects on Photocatalysts Invited International conference

    Akira Yamakata

    The First Symposium on Photo (electro) catalysis (SOP-1)  2019.6.23 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Defects for the Enhancement of Photocatalytic Activity Invited International conference

    Akira Yamakata, Junie Jhon, M. Vequizo, Shouta Ishiyama, Taishi Hiramine, Yoshihisa Sakata

    International Conference on Photocatalysis and Photoenergy 2019 (ICoPP2019)  2019.5.24 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 高性能光触媒の設計を目指した反応機構の解明 Invited

    Akira Yamakata

    中央大学理工学部・研究セミナー  2019.1.22 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Curious Behaviors of Photogenerated Charge Carriers at the Defects on Powder Photocatalysts Invited International conference

    Akira Yamakata

    (Keynote) International Workshop on Crystalline Materials and Applications (IWCMA-2019)  2019.1.3 

     More details

    Language:English   Presentation type:Oral presentation (keynote)  

    researchmap

  • 時間分解分光測定による高活性光触媒反応のメカニズム解明 Invited

    Akira Yamakata

    熊本大学工学部研究セミナー  2018.12.5 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Time-Resolved Visible to mid-IR Absorption Study of Photodynamics on Powder Photocatalysts Invited International conference

    Akira Yamakata

    Research Seminar at National Chiao Tung University  2018.11.20 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Curious Behavior of Photogenerated Electrons and Holes in Single-crystalline and Powder Photocatalysts Invited International conference

    Akira Yamakata

    Research Seminar at National Chung Hsing University  2018.11.19 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Time-resolved Absorption Study on the Behavior of Photogenerated Electrons and Holes in Highly Active Photocatalysts Invited International conference

    Akira Yamakata, Junie Jhon, M. Vequizo

    Functional Ceramics forum for the upcoming Annual Materials Science Conference  2018.11.17 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 高活性光触媒の実現を目指した新しい分光測定技術の開発 Invited

    Akira Yamakata

    第11回ワークショップ 固体材料合成および評価技術の新展開  2018.11.12 

     More details

    Language:Japanese   Presentation type:Oral presentation (keynote)  

    researchmap

  • ポンププローブ法による界面ダイナミクス Invited

    Akira Yamakata

    2018年電気化学会関東支部セミナー 先端計測技術による電極界面分析の新展開  2018.11.9 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 過渡吸収分光測定を用いた光触媒粒子の光励起ダイナミクス Invited

    Akira Yamakata

    第49回中部化学関係学協会支部連合秋季大会  2018.11.4 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解分光測定を利用した高活性光触媒の反応機構解明 Invited

    Akira Yamakata

    第31回 日本セラミックス協会 秋季シンポジウム 特定セッション「先進的な構造科学と分析技術」  2018.9.5 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Behavior of Photogenerated Charge Carriers on Highly Efficient Photocatalysts Invited International conference

    Akira Yamakata, Junie Jhon, M. Vequizo

    The 8th Advanced Functional Materials and Devices (AFMD 2018)  2018.8.18 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Effects of Surface Defects on Powder Photocatalysts Studied by Time-resolved Visible to Mid-IR Absorption Spectroscopy Invited International conference

    Akira Yamakata, Junie Jhon, M. Vequizo

    International Workshop on Water Splitting: Challenges and Opportunity  2018.8.4 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • The Role of Powder Defects for Efficient Photocatalytic Reactions Invited International conference

    Akira Yamakata

    (Keynote) The 22nd International Conference on Photochemical Conversion and Storage of Solar Energy (IPS-22)  2018.8.1 

     More details

    Language:English   Presentation type:Oral presentation (keynote)  

    researchmap

  • Defects Induced Enhancement of Ga2O3 Based Photocatalysts Studied by Time-Resolved Absorption Spectroscopy Invited International conference

    Akira Yamakata, Junie Jhon, M. Vequizo, Yoshihisa Sakata

    2018 International Symposium on Advancement and Prospect of Catalysis Science & Technology  2018.7.26 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • How the Defects Affects the Photocatalytic Activity on Powder and Single crystalline TiO2 Invited International conference

    Akira Yamakata

    International Conference on Ceramic Materials and Components for Energy and Environmental Applications (CMCEE-12)  2018.7.23 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Trapping-Induced Enhancement of Photocatalytic Activity on TiO2 Powders Invited International conference

    Akira Yamakata, Junie Jhon, M. Vequizo

    International Congress on Pure & Applied Chemistry (ICPAC) 2018  2018.3.7 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Behaviors of Photogenerated Electrons and Holes on TiO2 Powder Photocatalysts Invited International conference

    Akira Yamakata

    The 22nd International Conference on Semiconductor Photocatalysis & Solar Energy Conversion (SPASEC-22)  2017.11.14 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Behaviors of Electrons and Holes in Photocatalysts Studied by Time-resolved Visible to Mid-IR Absorption Spectroscopy Invited International conference

    Akira Yamakata

    International Conference on Photochemistry and Its Applications (ICPA 2017)  2017.11.11 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Mechanism of Photocatalytic Reactions on TiO2 Powders Invited International conference

    Akira Yamakata

    (Plenary) 19th SPVM National Physics Conference, 2017 ASEAN Conference on Advanced Functional Materials and Nanotechnology (ASEAN-AFMN), and 5th International Meeting on Complex Systems (IMCS)  2017.10.21 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Impact of Metal Ion Doping on Ga2O3 Photocatalysts Studied by Transient Absorption Spectroscopy Invited International conference

    Junie Jhon, M. Vequizo, Akira Yamakata

    2017 ASEAN Conference on Advanced Functional Materials and Nanotechnology (ASEAN-AFMN)  2017.10.19 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 金属酸窒化物複合アニオン型光触媒のキャリアーダイナミクス Invited

    Akira Yamakata

    新学術領域研究 (平成28〜32年度) 複合アニオン化合物の創製と新機能 第2回トピカル会議 (機能)  2017.8.7 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Reaction dynamics at the liquid/solid soft-interfaces Invited International conference

    Akira Yamakata

    KAKENHI International Symposium on “Studying the Function of Soft Molecular Systems”  2017.6.27 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Behaviors of Photogenerated Electrons and Holes in Photoelectrochemical Interfaces Invited International conference

    Akira Yamakata

    International Symposium on Pure & Applied Chemistry (ISPAC) 2017  2017.6.8 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Dynamics of Photocarriers of Brookite TiO2 Studied by Spectroscopic Techniques: A Comparison with Anatase and Rutile TiO2 Photocatalysts Invited

    Junie Jhon, M. Vequizo, Hironori Matsunaga, Teruhisa Ohno, ○Akira Yamakata

    2016.12.20 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 新しい分光技術を利用した光触媒反応の機構解明 Invited

    Akira Yamakata

    山口大学 光・エネルギー研究センターシンポジウム 光科学が生み出す新しい世界-光制御と分光技術の最前線-  2016.12.14 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解分光測定を利用した金属微粒子を担持した光触媒のキャリアーダイナミクス Invited

    Akira Yamakata

    第36回表面科学学術講演会  2016.11.30 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Dynamics of Photocarriers of Metal Nitrides/Oxynitrides Studied by Transient Absorption Spectroscopy: Controlling the Effects of Defects Invited International conference

    Junie Jhon, M. Vequizo, Akira Yamakata, Mirabbos Hojamberdiev, Kenta Kawashima, Hajime Wagata, Kunio Yubuta, Shuji Oishi, Kazunari Domen, Katsuya Teshima

    2016 International Conference on Materials Science and Nanotechnology (ICMSN)  2016.10.21 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 半導体光触媒の光励起ダイナミクス Invited

    Akira Yamakata

    第2回 半導体による太陽光-水素エネルギー変換技術研究会  2016.10.13 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Curious Behaviors of Photogenerated e- and h+ in Anatase and Rutile TiO2 Powders Invited International conference

    Akira Yamakata

    IKM International Symposium on Pure & Applied Chemistry (ISPAC) 2016  2016.8.17 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Behavior of Photogenerated Electrons and Holes on Anatase and Rutile TiO2 Powders Invited International conference

    Akira Yamakata

    Collaborative Conference on 3D and Materials Research (CC3DMR) 2016  2016.6.22 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Behaviors of Photogenerated Charge Carriers in Single-Crystalline and Polycrystalline Powder SrTiO3 Invited International conference

    Akira Yamakata

    2015 EMN Meeting on Photocatalysis (Energy Materials Nanotechnology)  2015.11.23 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Control of behavior and energy state of photogenerated charge carriers on photocatalysts Invited International conference

    Akira Yamakata

    JSTさきがけ 光エネルギーと物質変換 領域研究成果報告会  2015.3.26 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解分光測定を利用した光触媒の開発 Invited

    Akira Yamakata

    第32回無機材料に関する最近の研究成果発表会  2015.1.26 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解赤外分光法を用いた光触媒反応ダイナミクス Invited

    Akira Yamakata

    平成26年度日本分光学会中部支部講演会 (愛知地区)  2014.12.24 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Behavior of Photogenerated Charge Carriers on Transition Metal Doped Visible-light Responsive SrTiO3 Photocatalysts Invited International conference

    Akira Yamakata

    Vietnam Malaysia International Chemical Congress (VMICC)  2014.11.7 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 光励起キャリアーの動きを制御した光触媒の開発 Invited

    Akira Yamakata

    日本表面科学会中部支部研究会  2014.10.31 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Charge Carrier Dynamics on Visible-Light Responsive Water-Splitting Photocatalysts Invited International conference

    Akira Yamakata

    (Plenary) 16th Samahang Pisika ng Visayas at Mindanao (SPVM) National Physics Conference, 2014 International Conference on Applied Physics and Materials Science (ICAMS2014)  2014.10.24 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Behavior of Photogenerated Charge Carriers in the Visible Light Responsive Water Splitting LaTiO2N Photocatalysts Studied by Time-Resolved Visible to mid-IR Absorption Spectroscopy Invited International conference

    Akira Yamakata

    UK-Japan Solar Driven Fuel Synthesis Workshop: Materials, Understanding and Reactor Design  2014.9.18 

     More details

    Language:English   Presentation type:Poster presentation  

    researchmap

  • Electron and Hole Transfer from Photocatalyst to Cocatalysts Studied by Time-resolved Absorption Spectroscopy Invited International conference

    Akira Yamakata, Masayuki Kawaguchi, Jun Kubota, Kazunari Domen

    International Peradeniya University Research Sessions (iPURSE)  2014.7.4 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Behavior of Photogeneraged Charge Carriers in Water Splitting Photocatalysts Studied by Timeresolved Absorption Spectroscopy Invited International conference

    Akira Yamakata, Masayuki Kawaguchi, Jun Kubota, Kazunari Domen

    EMN Spring Meeting (Energy Materials Nanotechnology) 2014  2014.3.1 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 可視から赤外域の過渡吸収測定による光触媒反応の機構解明 Invited

    Akira Yamakata

    学術講演会 (神戸大学)  2014.1.30 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Real-time observation of destruction of hydration shells around several cations at electrochemical interface Invited International conference

    Akira Yamakata

    Seventh International Conference on Advanced Vibrational Spectroscopy (ICAVS-7)  2013.8.29 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Real-time observation of destruction processes of hydrophobic hydration shells at the electrified hydrophobic interface Invited International conference

    Akira Yamakata

    The 15th Asian Chemical Congress (15ACC)  2013.8.22 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 光触媒を利用した化学反応 Invited

    Akira Yamakata

    名工大オープンキャンパス4大学合同アフタヌーンセミナー  2013.6.15 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 光触媒反応の時間分解赤外分光観察 Invited

    Akira Yamakata

    第43回中部化学関係学協会支部連合秋季大会  2012.11.10 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Time-resolved IR absorption study on water-splitting photoelectrodes Invited International conference

    Akira Yamakata, Masaaki Yoshida, Jun Kubota, Masatoshi Osawa, Kazunari Domen

    Cambodian Malaysian Chemical Conference (CMCC) 2012  2012.10.19 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Dynamics of photogenerated electrons in GaN photoelectrochemical systems Invited International conference

    Akira Yamakata, Masaaki Yoshida, Jun Kubota, Masatoshi Osawa, Kazunari Domen

    17th Malaysian Chemical Congress (17MCC)  2012.10.15 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 赤外分光法を用いた光触媒反応の解析 Invited

    Akira Yamakata

    第22回キャラクタリゼーション講習会 -触媒および表面のキャラクタリゼーションの原理と実例ー  2012.10.12 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • FD講習を受けた二年目の常微分方程式 Invited

    Akira Yamakata

    FD推進ワークショップ  2012.8.8 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解赤外分光法でみた光触媒のキャリアーダイナミクス Invited

    Akira Yamakata

    ISSP ワークショップ 「表面・界面における輸送と変換」  2012.7.13 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Development and Mechanism of Water Splitting Photocatalysts Invited International conference

    Akira Yamakata

    Seminar at Department of Electrical Engineering, National Chung Hsing University  2012.6.25 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Real-time Observation of Destruction of Hydration Shells at Electrified Interfaces Invited International conference

    Akira Yamakata

    Workshop on Exploring the Structures and Dynamics of Water at Interfaces  2012.6.22 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 電極表面に固定したKcsAの構造変化 Invited

    山方 啓, 清水 啓史, 大澤 雅俊, 老木 成稔

    第15回 ミニ公開シンポジウム イオンチャネル研究の現状とこれからについて考える  2012.1.24 

     More details

    Language:Japanese  

    researchmap

  • Surface-enhanced IR study on the dynamics of hydration shells around several cations at the electrochemical interface Invited International conference

    Akira Yamakata, Masatoshi Osawa

    The 14th Asian Chemical Congress 2011  2011.9.7 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Time-resolved IR absorption study on the destruction processes of hydration shells at electrode surfaces Invited International conference

    Akira Yamakata, Masatoshi Osawa

    The 14th Asian Chemical Congress 2011 –Cambodia Satellite Meeting  2011.9.4 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Time-resolved surface-enhanced infrared absorption study on destruction of hydration shells at the electrochemical interface Invited International conference

    Akira Yamakata

    Symposium on Advanced Spectroscopy  2010.10.8 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 固液界面における溶質の水和殻崩壊過程の赤外分光観察 Invited

    Akira Yamakata, Masatoshi Osawa

    第106回触媒討論会  2010.9.17 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解赤外分光法を用いた触媒反応機構の解明 Invited

    Akira Yamakata

    第50回オーロラセミナー  2010.8.1 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 赤外分光法を用いた表面反応機構の解明 Invited

    Akira Yamakata

    2010年日本化学会北海道支部冬季研究発表会(北海道支部奨励賞受賞講演)  2010.1.27 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Structural changes of water layers between ions and a hydrophobic solid surface by their close contact Invited International conference

    Akira Yamakata, Masatoshi Osawa

    The second Asian Spectroscopy Conference  2009.11.30 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Reaction dynamics on catalysis studied by time-resolved IR absorption spectroscopy Invited

    Akira Yamakata, Masatoshi Osawa

    日本分光学会年次講演会 (日本分光学会奨励賞受賞講演)  2009.11.16 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 固液界面における準束縛溶媒分子の配向緩和ダイナミクス Invited

    Akira Yamakata

    特定領域研究高次系分子科学公開シンポジウム  2009.11 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Orientation Dynamics of Solvent Molecules on Liquid/Solid Interfaces Invited

    Akira Yamakata

    特定領域研究高次系分子科学公開シンポジウム  2009.6 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 赤外分光・和周波発生分光法を用いた電極界面分子のダイナミクス Invited

    Akira Yamakata

    科研費特定領域研究 高次系分子科学 第6回ミニ公開シンポジウム 表面・界面を観る非線形分光の新しい展開  2009.3.24 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 電極界面における水分子の反応とダイナミクス Invited

    Akira Yamakata

    触媒学会北海道地区札幌講演会 「触媒研究の近未来を語る」  2008.12.10 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解赤外分光法を用いた電極表面に固定したタンパク質の構造とダイナミクス Invited

    Akira Yamakata

    ミニ公開シンポジウム イオンチャネルの構造ダイナミクス  2008.7.8 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解赤外分光法を用いた電極・触媒表面ダイナミクスの追跡 Invited

    Akira Yamakata

    神戸大学セミナー  2007.11 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Probing Ultrafast Electrode Dynamics by Picosecond Time-Resolved Surface-Enhanced Infrared Spectroscopy Invited International conference

    Akira Yamakata, Jun Kubota, Masatoshi Osawa

    Workshop on Electrocatalysis: Surface science approaches  2006.10 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Picosecond Time-resolved Surface Enhanced IR Absorption Study on Electrochemical Interface Invited International conference

    Akira Yamakata, Jun Kubota, Masatoshi Osawa

    Seminar at Department of Chemical Physics of Fritz-Haber-Institut der Max-Planck-Gesellschaft  2006.7 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解赤外分光法を用いた二酸化チタン光触媒反応の観察 Invited

    Akira Yamakata

    第4回東京工業大学資源化学研究所フォーラム  2005.3 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解赤外分光法でみた光触媒反応ダイナミクス Invited

    Akira Yamakata

    上智大学物理学科談話会  2005.3 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解赤外分光法を用いた二酸化チタン光触媒反応中間体の観察 Invited

    Akira Yamakata

    第24回表面科学講演大会  2004.11 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 赤外分光法を用いた酸化チタン参照触媒の光励起ダイナミクス Invited

    Akira Yamakata, Taka-aki Ishibashi, Hiroshi Onishi

    第25回参照触媒討論会  2004.9.26 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 時間分解赤外分光法を用いた二酸化チタン光触媒反応中間体の観察 Invited

    Akira Yamakata

    第21回ライラックセミナー・第10回若手研究者交流会  2004.6 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 二酸化チタン新規参照触媒の時間分解赤外分光測定 Invited

    Akira Yamakata, Taka-aki Ishibashi, Hiroshi Onishi

    第24回参照触媒討論会  2003.9.17 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • Time-resolved Infrared Study of Photocatalytic Reactions on TiO2 Particles Invited International conference

    Akira Yamakata, Taka-aki Ishibashi, Hiroshi Onishi

    Seminar at Department of Physical Chemistry of Fritz-Haber-Institut der Max-Planck-Gesellschaft  2003.6 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

  • 酸化チタン参照触媒の時間分解赤外分光測定 Invited

    Akira Yamakata, Taka-aki Ishibashi, Hiroshi Onishi

    第23回参照触媒討論会  2002.9.17 

     More details

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    researchmap

  • The Reactions of Photogenerated Carriers on Photocatalysts Studied by Time-resolved IR Spectroscopy Invited International conference

    Akira Yamakata, Taka-aki Ishibashi, Hiroshi Onishi

    CRC International Symposium on photochemistry @interfaces  2002.8 

     More details

    Language:English   Presentation type:Oral presentation (invited, special)  

    researchmap

▼display all

Industrial property rights

  • 構造物及びその製造方法

    山方啓, Junie Jhon, M. Vequizo, Chandana Sampath, Kumara Ranasinghe

     More details

    Application no:PCT国際特許 K04002US  Date applied:2018.1.26

    researchmap

  • 構造物及びその製造方法

    山方啓, Junie Jhon, M. Vequizo, Chandana Sampath, Kumara Ranasinghe

     More details

    Application no:特願2017-013478  Date applied:2017.1.27

    researchmap

  • 拡散反射配置による時間分解分光装置

    大西 洋, 山方 啓, 石橋 孝章

     More details

    Applicant:財団法人神奈川科学技術アカデミー, 独立行政法人科学技術振興機構

    Application no:特願2003-392026  Date applied:2003.11.21

    Announcement no:特開2005-156229  Date announced:2005.6.16

    J-GLOBAL

    researchmap

  • 時間分解赤外分光法による光触媒の迅速評価法

    大西 洋, 山方 啓, 石橋 孝章

     More details

    Applicant:財団法人神奈川科学技術アカデミー

    Application no:特願2002-371956  Date applied:2002.12.24

    Announcement no:特開2004-205256  Date announced:2004.7.22

    J-GLOBAL

    researchmap

Awards

  • The Japanese Photochemistry Association Award

    2020.9   The Japanese Photochemistry Association   Development of novel transient absorption spectroscopy and reaction dynamics for highly efficient photocatalysis

    Akira Yamakata

     More details

  • 豊田奨学基金研究進歩賞

    2020.3   豊田工業大学   時間分解分光測定を利用した光触媒反応機構の解明

    山方 啓

     More details

  • 2018年度前期教育優秀賞 (受講者30人以上の部)

    2018.11   豊田工業大学  

    山方 啓

     More details

  • Symposium Award

    2018.3   International Congress on Pure & Applied Chemistry (ICPAC) 2018   "Trapping-Induced Enhancement of Photocatalytic Activity on TiO2 Powders"

    Akira Yamakata

     More details

  • 2017年度前期教育優秀賞 (受講者30人以上の部)

    2017.10   豊田工業大学  

    山方 啓

     More details

  • H26年度永井科学技術財団学術賞

    2015.3   永井科学技術財団  

    山方 啓

     More details

  • 豊田奨学基金研究奨励賞

    2014.3   豊田工業大学   時間分解赤外分光法を用いた触媒表面反応の解析

    山方 啓

     More details

  • 2013年度前期教育優秀賞 (受講者30人以上の部)

    2013.10   豊田工業大学  

    山方 啓

     More details

  • 2012年度前期教育優秀賞 (受講者30人以上の部)

    2012.10   豊田工業大学  

    山方 啓

     More details

  • 日本化学会北海道支部奨励賞

    2010.1   “赤外分光法を用いた表面反応機構の解明”

    山方 啓

     More details

    Country:Japan

    researchmap

  • 日本分光学会奨励賞

    2009.11   “時間分解赤外分光法を用いた触媒表面反応ダイナミクス”

    山方 啓

     More details

    Country:Japan

    researchmap

  • 日本表面科学会奨励賞

    2004.11   “時間分解赤外分光法を用いた二酸化チタン光触媒反応中間体の観察”

    山方 啓

     More details

    Country:Japan

    researchmap

▼display all

Research Projects

  • 粉末系光触媒材料における欠陥の理解と制御

    2022.10 - 2024.09

    泉科学技術振興財団  研究助成 

      More details

    Authorship:Principal investigator 

    researchmap

  • 反応機構に立脚した高活性可視光応答型光触媒の開発

    2022.06 - 2023.03

    八雲環境科学振興財団  環境研究助成 

      More details

    Authorship:Principal investigator 

    researchmap

  • 励起キャリア移動の指向性制御による高効率光触媒表面の構築

    Grant number:21H02050  2021.04 - 2024.03

    日本学術振興会  科学研究費助成事業  基盤研究(B)

    吉田 真明, 酒多 喜久, 山方 啓, 長坂 将成

      More details

    Grant amount:\17550000 ( Direct expense: \13500000 、 Indirect expense:\4050000 )

    researchmap

  • Dynamic Exciton: Emerging Science and Innovation

    Grant number:20H05831  2020.11 - 2025.03

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Transformative Research Areas (A)

    今堀 博, 小堀 康博, 佐伯 昭紀, 山田 容子, 東 雅大, 三ツ沼 治信, 梶 弘典, 山方 啓, 家 裕隆, 作田 絵里, 村上 達也, 鈴木 克明

      More details

    Grant amount:\66170000 ( Direct expense: \50900000 、 Indirect expense:\15270000 )

    本学術変革領域では、従来の光化学における「静的エキシトン」の概念を打ち破る学術領域「動的エキシトン学」の構築にむけ、分野融合・統合的研究を推進する。そのために総括班では、本領域全体での「学問分野の枠を超えた有機的連携の堅持」を最重要課題と位置づけ、期間内に全ての計画班員12名が役割分担して領域の推進に貢献する。特に、班長及び研究課題代表者による共同研究支援に加えて、若手研究者育成支援、女性研究者育成支援、国際活動支援、産学連携支援の五つの支援を柱に、様々な具体的施策により、領域の目標と方針を計画班員に周知徹底し、目標の達成に向け先導的な役割を達成を目指す。
    研究領域全体の研究方針の作成は領域代表者の今堀と各班長、研究課題代表1-4を中心に行った。拡大運営委員会、領域会議等で計画班、公募班員全員が集まる機会を複数回設け、領域目標の周知・確認を繰り返し行った。また、広報活動の一環として、また領域目標の共有に向けて、領域ホームページ、プレスリリース、学会発表、アウトリーチ等も積極的に活用した。これらの機会を利用して、計画班員全員が互いの動的エキシトン研究の進捗を密に共有した。計画、公募班員は二ヶ月に一回程度、メールやZoomなどのインターネット会議で研究の進捗を各班長、研究課題代表に報告し 、各班長、研究課題代表は班長会議、研究課題会議、サイトビジットにより、計画、公募班全体の研究の進捗を把握した。これにより、必要に応じて適切なタイミングで、機動的な共同研究の提案、開始、とりまとめを行えた。

    researchmap

  • Wideband transient absorption spectroscopy for the analysis of dynamic exciton

    Grant number:20H05838  2020.11 - 2025.03

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Transformative Research Areas (A)

    山方 啓

      More details

    Grant amount:\72930000 ( Direct expense: \56100000 、 Indirect expense:\16830000 )

    近年、新しい非フラーレン型アクセプター(NFA)の開発に伴い、有機太陽電池の発電効率が飛躍的に向上している。したがって、さらなる発電効率の向上には、これらのNFAにおける光励起電子と正孔の動きを詳しく理解することが重要である。そこで、本研究では、分子振動数が局所的な電荷密度変化に敏感に応答することを利用して振動数変化からNFAの分子内における電子と正孔の分布を解析することを目的とした。
    まず、NFAとして最も良く用いられるITIC薄膜にポンプパルスを照射してC≡N基の振動数変化を時間分解赤外分光計測を用いて調べた。その結果、暗状態で観察された2220 cm-1のピークは、光照射によって強度が減少し、2205 cm-1と2175 cm-1に新しいピークが出現した。これらのピーク強度はいずれも同じ速度で変化し、1000 ps以内に始状態に回復した。
    次に電子ドナーであるPBDB-T分子とバルクヘテロ接合薄膜を調製し、ITICを光励起すると、ITIC単膜と同様に2220 cm-1の強度が減少し、2205 cm-1と2175 cm-1に新しいピークが出現した。しかし、2205 cm-1のピーク強度は光照射10 ps以内に減少し、2175 cm-1は1000 ps経っても減衰しなくなった。C≡Nの振動数は電子密度の増加と減少に対し、いずれも結合が弱くなり、振動数低下をもたらす。したがって、これらの新しいピークはそれぞれC≡N近傍に正孔と電子が局在化した状態に帰属される。そして、これらのピーク強度の時間変化から、ITIC単膜の場合には分子内あるいは分子間で電子と正孔が分離した状態が出現し、複合膜の場合にはITICからPBDB-Tへの正孔移動は10 ps以内に進行することが分かった。すなわち、時間分解赤外分光測定により、NFA分子内における電子と正孔の分布の変化を追跡できることを示した。

    researchmap

  • 表面欠陥準位を制御した新しい光触媒の開発

    2020.11 - 2021.10

    ENEOS水素基金 

      More details

  • 人工光合成を実現する異種接合界面の光励起ダイナミクス

    Grant number:20H05117  2020.04 - 2022.03

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

    山方 啓

      More details

    Grant amount:\6500000 ( Direct expense: \5000000 、 Indirect expense:\1500000 )

    researchmap

  • 異種接合光触媒界面の光励起ダイナミクス

    2020.01 - 2020.12

    豊田工業大学・学内競争的資金 研究促進費 

      More details

  • 欠陥準位を制御した高活性光触媒の開発

    2019.04 - 2022.03

    文科省  科研費・基盤研究B 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 複合アニオン化合物の光励起ダイナミクス

    2019.04 - 2021.03

    文科省  科研費・新学術領域研究 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 金属酸窒化物光触媒の光励起ダイナミクス

    2017.04 - 2019.03

    文科省  科研費・新学術領域研究 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 光触媒粒子のキャリアダイナミクス

    2017.04 - 2018.03

    北海道大学触媒科学研究所  共同利用・共同研究公募(戦略型) 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 原子層堆積装置を用いた光触媒の活性向上

    2016.10 - 2017.09

    豊田工業大学・学内競争的資金  研究促進費 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 表面欠陥の構造とエネルギーを制御した可視光応答型光触媒の高性能化

    2016.04 - 2019.03

    文科省  科研費・基盤研究B 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 柔らかな固液界面における化学反応ダイナミクス

    2016.04 - 2018.03

    文科省  科研費・新学術領域研究 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 粉末系光触媒の光励起ダイナミクス

    2016.04 - 2017.03

    北海道大学触媒科学研究所  共同利用・共同研究公募(課題設定型) 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 赤外分光を用いた酸化物光触媒の表面欠陥サイトの同定

    2015.04 - 2016.03

    東京工業大学資源化学研究所  物質・デバイス領域共同研究拠点共同研究 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 可視光応答型光触媒の開発

    2011.10 - 2013.03

    豊田工業大学・学内競争的資金  研究促進費 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 光励起キャリアーの動きとエネルギー制御

    2011.04 - 2017.03

    科学技術振興機構  さきがけ研究 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 固液界面での光励起キャリアダイナミクスに基づいた革新的水分解光触媒の開発

    2011.04 - 2016.03

    文科省  科研費・特別推進研究 

    堂免 一成

      More details

    Grant type:Competitive

    researchmap

  • 可視光応答型光触媒のキャリア制御

    2011.04 - 2015.03

    文科省  科研費・基盤研究B 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 次代を担う超高効率集光型太陽光発電の日欧共同研究開発 (NGCPV)

    2011.04 - 2014.10

    NEDO  革新的太陽光発電技術研究開発プロジェクト 

    山口 真史

      More details

    Grant type:Competitive

    researchmap

  • ピコ秒時間分解赤外分光法を用いた可視光型光触媒の光励起キャリアーダイナミクス

    2011.04 - 2012.03

    豊田理研スカラー  研究助成 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 酸化物半導体のバンドギャップ制御と光励起キャリアーの長寿命化

    2011.04 - 2012.03

    日本板硝子材料工学助成会  研究助成 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • Development of intensity modulated infrared spectroscopy for analysis of photocatalytic reactions

    Grant number:23655187  2011 - 2012

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Challenging Exploratory Research

    AMANO Fumiaki, YAMAKATA Akira

      More details

    Grant amount:\4030000 ( Direct expense: \3100000 、 Indirect expense:\930000 )

    Solar water splitting using photocatalysts is a promising technology for energy conversion and storage. However, design concepts for highly efficient photocatalyst have not been clarified even in the case of a widely used TiO2 photocatalyst. Elucidating correlations between structure, physical properties, and photoexcited electron lifetime will provide the design concepts of highly efficient photocatalysts. In this study, we investigated the decisive factors deciding the photocatalytic activities of TiO2 and WO3 using time-resolved infrared absorption spectroscopy evaluating photoexcited electron lifetime.

    researchmap

  • 電極界面におけるイオンの水和構造ダイナミクス

    2010.04 - 2012.03

    文科省  科研費・特定領域研究 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 固液界面における準束縛溶媒分子の配向緩和ダイナミクス

    2008.04 - 2010.03

    文科省  科研費・特定領域研究 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 高活性水素発生電極触媒の開発と機構解明

    2007.10 - 2008.03

    北海道大学GCOEプログラム  若手教員イノベーション事業 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 超高速電位ジャンプ法を用いた電子移動・電極反応ダイナミクスの赤外分光解析

    2007.04 - 2010.03

    文科省  科研費・若手研究A 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 会議名【210th Electrochemical Society (ECS) Meeting】・メキシコ

    2006.10

    電気化学会  海外渡航費用 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 固液界面反応の赤外分光イメージング

    2006.04 - 2008.03

    文科省  科研費・基盤研究B 

    大澤 雅俊

      More details

    Grant type:Competitive

    researchmap

  • ピコ秒時間分解表面増強振動分光法を用いた電極表面キャリアーダイナミクス

    2006.04 - 2008.03

    文科省  科研費・特定領域研究 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 赤外表面増強場を用いた振動誘起表面反応の制御

    2005.04 - 2007.03

    文科省  科研費・若手研究B 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 触媒学会参照触媒酸化チタンを利用する光触媒の標準化

    2004.04 - 2005.03

    文科省  科研費・基盤研究C 

    岡本康昭

      More details

    Grant type:Competitive

    researchmap

  • 会議名【11th International conference on Time-resolved Vibrational Spectroscopy】・ イタリア

    2003.06

    吉田科学振興財団  海外渡航費用 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 光励起キャリアーの動的過程を観測した光触媒活性評価法の確立と触媒探索への応用

    2003.04 - 2005.03

    文科省  科研費・萌芽研究 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 微小電極界面における高速反応ダイナミクスの振動分光解析

    2002.04 - 2005.03

    文科省  科研費・基盤研究A 

    大澤 雅俊

      More details

    Grant type:Competitive

    researchmap

  • 和周波分光法と赤外吸収分光法を用いたイオン液体(常温溶融塩)の界面分子構造の研究

    2002.04 - 2004.03

    文科省  科研費・基盤研究B 

    大西 洋

      More details

    Grant type:Competitive

    researchmap

  • アナターゼ型およびルチル型二酸化チタン単結晶薄膜の合成と原子スケール評価

    2002.04 - 2003.03

    文科省  科研費・特定領域研究 公募 

    大西 洋

      More details

    Grant type:Competitive

    researchmap

  • 会議名【International Conference of Vibrations at Surfaces 10】・フランス

    2001.06

    新世代研究所  海外渡航費用 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 時間分解マルチプレックス表面和周波分光装置の開発

    2001.04 - 2004.03

    文科省  科研費・基盤研究B 

    石橋 孝章

      More details

    Grant type:Competitive

    researchmap

  • 時間分解赤外分光法による光触媒上の励起キャリアーによる吸着分子の反応過程観察

    2000.04 - 2002.03

    文科省  科研費・奨励研究A 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

  • 赤外反射吸収分光法による反応条件下の表面反応の研究

    1998.04 - 1999.03

    文科省  科研費・特別研究員奨励費 

    山方 啓

      More details

    Authorship:Principal investigator  Grant type:Competitive

    researchmap

▼display all

 

Class subject in charge

  • Seminar in Molecular Science (Surface Physical Chemistry) (2024academic year) Other  - その他

  • Seminar in Molecular Science (Surface Physical Chemistry) (2024academic year) Year-round  - その他

  • Basic Modern Chemistry A1 (2024academic year) 1st semester  - 火1~2

  • Physical Chemistry 3 (2024academic year) Third semester  - 月3~4

  • Physical Chemistry 4 (2024academic year) Fourth semester  - 月3~4

  • Physical Chemistry Ⅱ (2024academic year) 3rd and 4th semester  - 月3~4

  • Introduction to Natural Science 1(Chemistry) (2024academic year) 1st semester  - 火3~4

  • Introduction to Natural Science 2(Chemistry) (2024academic year) Second semester  - 火3~4

  • Surface Photochemistry (2024academic year) Late  - その他

  • Seminar in Surface Physical Chemistry (2024academic year) Year-round  - その他

  • Advanced Surface Physical Chemistry (2024academic year) Late  - 火3~4

  • Quantum Chemistry 5 (2024academic year) 1st semester  - 月1~2

  • Quantum Chemistry 6 (2024academic year) Second semester  - 月1~2

  • Quantum Chemistry III (2024academic year) 1st and 2nd semester  - 月1~2

  • Advanced Surface Physical Chemistry (2023academic year) Late  - その他

  • Topics in Molecular Chemistry 2 (2023academic year) Concentration  - その他

  • Seminar in Molecular Science (Surface Physical Chemistry) (2023academic year) Year-round  - その他

  • Basic Modern Chemistry A1 (2023academic year) 1st semester  - 火1~2

  • Physical Chemistry 3 (2023academic year) Third semester  - 月3~4

  • Physical Chemistry 4 (2023academic year) Fourth semester  - 月3~4

  • Physical Chemistry Ⅱ (2023academic year) 3rd and 4th semester  - 月3~4

  • Surface Photochemistry (2023academic year) Late  - その他

  • Seminar in Surface Physical Chemistry (2023academic year) Year-round  - その他

  • Seminar in Surface Physical Chemistry (2023academic year) Year-round  - その他

  • Advanced Surface Physical Chemistry (2023academic year) Late  - 火3~4

  • Advanced Surface Physical Chemistry (2023academic year) Late  - 火3~4

  • Quantum Chemistry 5 (2023academic year) 1st semester  - 月1~2

  • Quantum Chemistry 6 (2023academic year) Second semester  - 月1~2

  • Quantum Chemistry III (2023academic year) 1st and 2nd semester  - 月1~2

  • Advanced Course of Innovation (2022academic year) Summer concentration

  • General Chemistry 1 (2022academic year) Third semester  - 金1~2

  • General Chemistry 1 (2022academic year) Third semester  - 金1~2

  • Advanced Surface Physical Chemistry (2022academic year) Late  - その他

  • 化学実験法3 (2022academic year) 第3学期

  • 教養化学実験 (2022academic year) 第4学期  - 木5〜8

  • Basic Modern Chemistry A1 (2022academic year) 1st semester  - 火1~2

  • Seminar in Surface Physical Chemistry (2022academic year) Year-round  - その他

  • Advanced Surface Physical Chemistry (2022academic year) Late  - 火3~4

▼display all

 

Media Coverage

  • プラズモンを用いたエネルギーアップコンバージョン -未使用エネルギー赤外光の活用方法に道- Internet

    京都大学化学研究所広報  2022.10.18

     More details

    Author:Myself 

    researchmap

  • 再生可能エネルギー実現の社会に向けて研究 Newspaper, magazine

    タウンニュースてんぱくNo.823  2021.7.29

     More details

    Author:Other 

    researchmap

  • 水・酸素から過酸化水素生成 九州工大と豊田工大、光触媒を開発 Newspaper, magazine

    日刊工業新聞  日刊工業新聞  ニュースリリース  2021.6.11

     More details

    Author:Other 

    researchmap

  • 水と酸素から過酸化水素を生成する高性能光触媒の開発に成功 ― 次世代燃料の製造プロセス開発に向けて ― Internet

    九州工業大学・豊田工業大学  2021.5.25

     More details

    Author:Myself 

    researchmap

  • 赤外光を電気エネルギーや信号に変換する無色透明な材料の開発 ―見えない電子デバイスの開発へ道― Internet

    京都大学化学研究所広報  2019.1.24

     More details

    Author:Myself 

    researchmap

  • 新しい赤外光誘起キャリア移動機構の発見 -赤外光のエネルギー利用に期待- Internet

    京都大学化学研究所広報  2018.6.13

     More details

    Author:Myself 

    researchmap

  • 拓く研究人【光触媒で水素安く合成】 Newspaper, magazine

    日刊工業新聞  2014.5.28

     More details

    Author:Myself 

    researchmap

  • 「研究現場発」【光触媒を使って水素を製造する】 Newspaper, magazine

    中部経済新聞朝刊  2014.5.28

     More details

    Author:Myself 

    researchmap

  • “光励起キャリアーの動きとエネルギー制御” Newspaper, magazine

    化学経済  2011.12

     More details

    Author:Myself 

    researchmap

▼display all