Updated on 2024/11/06

写真a

 
Kato Riki
 
Organization
Research Institute for Interdisciplinary Science Special-Appointment Assistant Professor
Position
Special-Appointment Assistant Professor
External link

Degree

  • 博士(工学)

Research Interests

  • バイオミネラリゼーション

  • 有機無機複合材料

  • ゲル

  • 構造色

  • ナノシート

  • コロイド液晶

Research Areas

  • Nanotechnology/Materials / Functional solid state chemistry

  • Nanotechnology/Materials / Nanometer-scale chemistry

Education

  • Fukuoka Institute of Technology   工学研究科   物質生産システム工学専攻

    2018.4 - 2021.3

      More details

  • Fukuoka Institute of Technology   工学研究科   生命環境化学専攻

    2016.4 - 2018.3

      More details

  • Fukuoka Institute of Technology   工学部   生命環境科学科

    2012.4 - 2016.3

      More details

Research History

  • Okayama University   The Research Institute for Interdisciplinary Science

    2024.4

      More details

  • The University of Tokyo   The Graduate School of Engineering Department of Chemistry and Biotechnology   Postdoctoral Fellow

    2021.4 - 2024.3

      More details

 

Papers

  • 2D Photonic Colloidal Liquid Crystals Composed of Self‐Assembled Rod‐Shaped Particles

    Riki Kato, Takahiro Mikami, Takashi Kato

    Advanced Materials   2024.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/adma.202404396

    researchmap

  • Monodisperse nanosheet mesophases

    Nobuyoshi Miyamoto, Momoka Miyoshi, Riki Kato, Yuji Nakashima, Hiroyuki Iwano, Takashi Kato

    Science Advances   10 ( 23 )   2024.6

     More details

    Publishing type:Research paper (scientific journal)   Publisher:American Association for the Advancement of Science (AAAS)  

    Self-assemblies of anisotropic colloidal particles into colloidal liquid crystals and well-defined superlattices are of great interest for hierarchical nanofabrications that are applicable for various functional materials. Inorganic nanosheets obtained by exfoliation of layered crystals have been highlighted as the intriguing colloidal units; however, the size polydispersity of the nanosheets has been preventing precise design of the assembled structures and their functions. Here, we demonstrate that the anionic titanate nanosheets with monodisperse size reversibly form very unusual superstructured mesophases through finely tunable weak attractive interactions between the nanosheets. Transmission electron microscopy, polarizing optical microscopy, small-angle x-ray scattering, and confocal laser scanning microscopy clarified the reversible formation of the mesophases (columnar nanofibers, columnar nematic liquid crystals, and columnar nanofiber bundles) as controlled by counter cations, nanosheet concentration, solvent, and temperature.

    DOI: 10.1126/sciadv.adk6452

    researchmap

  • Nanostructure Control in Zinc Oxide Films and Microfibers through Bioinspired Synthesis of Liquid‐Crystalline Zinc Hydroxide Carbonate; Formation of Free‐Standing Materials in Centimeter‐Level Lengths

    Takahiro Mikami, Riki Kato, Yoshihiro Hosokawa, Nobuyoshi Miyamoto, Takashi Kato

    Small Methods   2024.4

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/smtd.202300353

    researchmap

  • Time evolution of the inner structure of antimony phosphate nanosheet suspension developing structural colouration

    Emiko Mouri, Takashi Fukumoto, Riki Kato, Nobuyoshi Miyamoto, Teruyuki Nakato

    Soft Matter   20 ( 32 )   6353 - 6360   2024

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    Structural colouration observed in antimony phosphate nanosheet suspensions has been known for two decades, but the stability of their inner structure has not been a topic in colloidal nanosheet systems.

    DOI: 10.1039/d4sm00647j

    researchmap

  • Thermotropic Colloidal Liquid‐Crystalline Hydroxyapatite Nanorod Hybrids Containing a Forklike Mesogen

    Junya Uchida, Ryuta Kiguchi, Riki Kato, Takashi Kato

    Helvetica Chimica Acta   2023.8

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/hlca.202300053

    researchmap

  • Development of liquid-crystalline smectic nanoporous membranes for the removal of SARS-CoV-2 and waterborne viruses

    Takeshi Sakamoto, Kazuhiro Asakura, Naru Kang, Riki Kato, Miaomiao Liu, Tsuyoshi Hayashi, Hiroyuki Katayama, Takashi Kato

    Journal of Materials Chemistry A   2023

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D3TA02705H

    researchmap

  • Degradable and Nanosegregated Elastomers with Multiblock Sequences of Biobased Aromatic Mesogens and Biofunctional Aliphatic Oligocarbonates

    Yuya Watanabe, Riki Kato, Kazuki Fukushima, Takashi Kato

    Macromolecules   2022.12

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.macromol.2c01747

    researchmap

  • Bioinspired macromolecular templates for crystallographic orientation control of ZnO thin films through zinc hydroxide carbonate

    Takahiro Mikami, Shunichi Matsumura, Rino Ichikawa, Riki Kato, Junya Uchida, Tatsuya Nishimura, Takashi Kato

    Polymer Journal   2022.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    <jats:title>Abstract</jats:title><jats:p>The biomineralization-inspired preparation of inorganic hybrid materials has attracted attention. Here, we report a new approach to the orientation control of zinc oxide (ZnO) thin-film crystals through the preparation of zinc hydroxide carbonate (ZHC) by the macromolecular templates of poly(2-hydroxyethyl methacrylate) (PHEMA) and poly(vinyl alcohol) (PVA). Using 100-nm-thick PHEMA templates, ZHC thin films with the<jats:italic>c</jats:italic>-axis oriented parallel to the substrate were obtained, while ZHC thin films prepared by 100-nm-thick PVA templates showed perpendicular orientation. After the thermal treatment of ZHC, the crystal orientations of the ZnO thin films were maintained. The effects of the thickness and annealing time for the polymer templates on the morphologies of the ZnO thin films were examined.</jats:p>

    DOI: 10.1038/s41428-022-00661-9

    researchmap

  • Perovskite Nanosheet Hydrogels with Mechanochromic Structural Color

    Wenqi Yang, Shinya Yamamoto, Keiichiro Sueyoshi, Takumi Inadomi, Riki Kato, Nobuyoshi Miyamoto

    Angewandte Chemie   2021.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    <jats:title>Abstract</jats:title><jats:p>Structural color colloidal sols of perovskite nanosheets were synthesized and were immobilized in a polymer hydrogel film by in situ photopolymerization, leading to a novel mechanochromic material. Visible absorption spectroscopy, polarized optical microscopy and small‐angle X‐ray scattering revealed that the nanosheets are aligned parallel to the film surface with the periodic distance of up to ca. 300 nm, giving the structural color tunable over full color range. The present structural color gel showed reversible mechanochromic response that detects weak stress of 1 kPa with the quick response time less than 1 ms as well as high mechanical toughness (compressive breaking stress of up to 3 MPa). These excellent properties are suitable for applications for mechano‐sensors and displays.</jats:p>

    DOI: 10.1002/ange.202015982

    researchmap

  • Structure-regulated tough elastomers of liquid crystalline inorganic nanosheet/polyurethane nanocomposites

    Toki Morooka, Yutaka Ohsedo, Riki Kato, Nobuyoshi Miyamoto

    Materials Advances   2021

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    <p>Liquid crystalline nanosheet/polyurethane composite elastomers with superior mechanical properties were successfully synthesized using the newly developed<italic>in situ</italic>polymerization technique.</p>

    DOI: 10.1039/d0ma00768d

    researchmap

  • High Virus Removal by Self‐Organized Nanostructured 2D Liquid‐Crystalline Smectic Membranes for Water Treatment

    Daniel Kuo, Miaomiao Liu, K. R. Sunil Kumar, Kazuma Hamaguchi, Kian Ping Gan, Takeshi Sakamoto, Takafumi Ogawa, Riki Kato, Nobuyoshi Miyamoto, Hiroki Nada, Masahiro Kimura, Masahiro Henmi, Hiroyuki Katayama, Takashi Kato

    Small   2020.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    <jats:title>Abstract</jats:title><jats:p>To obtain high quality of drinking water free from biocontaminants is especially important issue. A new strategy employing smectic liquid‐crystalline ionic membranes exhibiting 2D structures of layered nanochannels for water treatment is proposed for efficient virus removal and sufficient water flux. The smectic A (SmA) liquid‐crystalline membranes obtained by in situ polymerization of an ionic mesogenic monomer are examined for removal of three distinct viruses with small size: Qβ bacteriophage, MS2 bacteriophage, and Aichi virus. The semi‐bilayer structure of the SmA significantly obstructs the virus penetration with an average log reduction value of 7.3 log<jats:sub>10</jats:sub> or the equivalent of reducing 18 million viruses down to 1. Furthermore, the layered nanochannels of the SmA liquid crystal allow efficient water permeation compared to other types of liquid‐crystalline membrane consisting of nanopores.</jats:p>

    DOI: 10.1002/smll.202001721

    researchmap

  • Design and phase transition behavior of siloxane-based monomeric and dimeric liquid crystals bearing cholesteryl mesogenic groups

    Kaito Katsuki, Kosuke Kaneko, Kimiyoshi Kaneko, Riki Kato, Nobuyoshi Miyamoto, Tomonori Hanasaki

    Journal of Organometallic Chemistry   2019.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.jorganchem.2019.02.016

    researchmap

  • Liquid Crystalline Colloidal Mixture of Nanosheets and Rods with Dynamically Variable Length

    Riki Kato, Akira Kakugo, Kazuhiro Shikinaka, Yutaka Ohsedo, ARIF MD. RASHEDUL KABIR, Nobuyoshi Miyamoto

    ACS Omega   2018.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsomega.8b01050

    researchmap

▼display all

Awards

  • 論文賞A

    2022.9   日本液晶学会  

     More details

  • 優秀講演賞

    2017.9   日本化学会低次元系光機能材料研究会  

     More details

Research Projects

  • ねじれ棒状液晶性粒子の合成とコレステリック相に基づく構造色の発現

    Grant number:22K14562  2022.04 - 2024.03

    日本学術振興会  科学研究費助成事業  若手研究

    加藤 利喜

      More details

    Grant amount:\4680000 ( Direct expense: \3600000 、 Indirect expense:\1080000 )

    従来の無機物ベースのコロイド液晶は単純な形状の粒子からなり、有機物からなる液晶と比べて単純配向しただけの液晶であったため、機能性に乏しかった。そこで本研究では、生物が鉱物を生み出すバイオミネラリゼーションに倣うことで、構造色を示す新規コロイド液晶の開発を目的とする。具体的にはアミノ酸存在下で結晶成長を行うことによってねじれ棒状粒子を合成し、その形状によって誘起されたコレステリック相による構造色材料の開発を最終目標としている。
    2022年度では、まずバイオミネラリゼーションに倣い、アパタイトベース粒子の合成条件を検討した。その結果、非常に粒径分布の狭い液晶性棒状粒子の合成に成功した。基本的な粒子構造や液晶性の評価を行った。次にアミノ酸存在下でアパタイトベースの粒子を合成することを試みた。すると予想に反してねじれ構造ではなく、長さは850nm、直径150nm程度の紡錘状の粒子を合成することができた。その粒子の形状やサイズはアミノ酸種や濃度などの合成条件によって制御することができ、最大で長さ3μmを超える粒子も合成できた。直径に対する長さのアスペクト比が6程度であったため、比較的高い粒子濃度で液晶相を形成した。さらに、特定の条件下ではその液晶構造に基づいていると思われる構造色を示した。当初の予定であったコレステリック相からなる構造色ではなかったが、新奇構造色材料として粒子の構造、液晶性、構造色についての評価を行った。

    researchmap