研究者詳細 - 中村　栄三

MISC - 中村　栄三

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In-situ U-Pb zircon age dating deciphering the formation event of the omphacite growth over relict edenitic pargasite in omphacite-bearing jadeitite of the Itoigawa-Omi area of the Hida-Gaien belt, central Japan

Keitaro Kunugiza, Eizo Nakamura, Atsushi Goto, Katsura Kobayashi, Tsutomu Ota, Hiroshi Miyajima, Kazumi Yokoyama

JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 112 ( 5 ) 256 - 270 2017年10月

記述言語：英語出版者・発行元：JAPAN ASSOC MINERALOGICAL SCIENCES

Omphacite replacing after relic edenitic pargasite has been found in an omphacite-bearing jadeitite block of the Itoigawa-Omi area in the Hida-Gaien belt. Omphacite occurs sporadically as fine-grained aggregate reaching a few cm in length in a jadeite-albite matrix, and sometimes contains edenitic pargasite as a core. The edenitic pargasite is chemically and optically homogeneous and does not show direct contact with jadeite and albite. An irregular shaped omphacite-diopside mixed area occurs near edenitic pargasite in a coarse omphacite aggregate. The texture suggests that the breakdown of edenitic pargasite was triggered by the addition of a hydrothermal fluid, from which jadeite and albite were precipitated later, passing through diopside and omphacite by the reaction:
NaCa2Mg5(AlSi7)O-22(OH)(2) -> (NaAlSi2O6 + CaMgSi2O6) + CaMgSi2O6+ Mg3SiO5 + H2O.
At the periphery of pseudomorphic omphacite, a hydrothermal fluid removed the breakdown components of the reaction other than omphacite.
New in-situ LA-ICP-MS U-Pb dating revealed that zircons in edenitic pargasite yield apparent age up to similar to 590 Ma, with mean ages of 560 +/- 16 Ma, interpreted as the minimum age of a precursor rock. A zircon age of 519 +/- 21 Ma from jadeitite without omphacite corresponds to a timing of crystallization of omphacite, jadeite, and albite. The studied jadeitite is a typical R-type jadeitite, and the nearly total replacement from a precursor rock to the omphacite-bearing jadeitite has been attributed to hydrothermal activity at Middle Cambrian times.

DOI： 10.2465/jmps.170402a

Silicate-SiO reaction in a protoplanetary disk recorded by oxygen isotopes in chondrules

Ryoji Tanaka, Eizo Nakamura

NATURE ASTRONOMY 1 ( 7 ) 1523 - 1529 2017年7月

記述言語：英語出版者・発行元：NATURE PUBLISHING GROUP

The formation of planetesimals and planetary embryos during the earliest stages of the solar protoplanetary disk largely determined the composition and structure of the terrestrial planets. Within a few million years of the birth of the Solar System, chondrule formation and the accretion of the parent bodies of differentiated achondrites and the terrestrial planets took place in the inner protoplanetary disk(1,2). Here we show that, for chondrules in unequilibrated enstatite chondrites, high-precision Delta O-17 values (where Delta O-17 is the deviation of the delta O-17 value from a terrestrial silicate fractionation line) vary significantly (ranging from -0.49 to + 0.84%) and fall on an array with a steep slope of 1.27 on a three-oxygen-isotope plot. This array can be explained by the reaction between an olivine-rich chondrule melt and an SiO-rich gas derived from vaporized dust and nebular gas. Our study suggests that a large proportion of the building blocks of planetary embryos formed by successive silicate-gas interaction processes: silicate- H2O followed by silicate-SiO interactions under more oxidized and reduced conditions, respectively, within a few million years of the formation of the Solar System.

DOI： 10.1038/s41550-017-0137

Petrologic and geochemical characterization of rift-related magmatism at the northernmost Main Ethiopian Rift: Implications for plume-lithosphere interaction and the evolution of rift mantle sources

D. H. Feyissa, R. Shinjo, H. Kitagawa, D. Meshesha, E. Nakamura

LITHOS 282 240 - 261 2017年6月

記述言語：英語出版者・発行元：ELSEVIER SCIENCE BV

In this paper, we present petrography, K-Ar ages, whole-rock major- and trace-element concentrations, and Sr-Nd-Hf-Pb isotopic ratios of volcanic rocks from Debre Birhan area in the northernmost Main Ethiopian Rift (MER). The K-Ar ages of the mafic series range from 27 to 0.25 Ma, and two felsic rocks yield ages of 0.93 and 0.23 Ma. The mafic volcanics are classified into older and younger series based on their K-Ar ages. The Mg-numbers (Mg# < 60) of both mafic series, along with low Ni and Cr contents, clearly indicate that these lavas have undergone fractionation en route to the surface. Geochemical and isotopic compositions of the older and younger mafic lavas indicate that crustal contamination did not play a significant role in the evolution of their magmas, hence reflect the geochemical characteristics of the sources. The older and younger mafic volcanic rocks display contrasting trace element and isotopic signatures. The older lavas have higher La/Nb, Zr/Nb, Ba/Nb and Sr-87/Sr-86(i) (0.70445-0.70681) and lower epsilon(Hf) (-2.58 to + 6.01) and epsilon(Nd) ( -1.25 to +3.43) and less radiogenic Pb isotopic ratios (Pb-206/(204)Pbi = 17.82-18.64, except TG-54 = 19.1) relative to the younger mafic lavas. Correlations among isotopic ratios and trace element concentrations provide evidence for the involvement of at least three major end-member components (C-1, C-2, and C-3) in the petrogenesis of these mafic lavas. The C-1 end-member component contributes dominantly to younger mafic lavas, and has isotopic composition similar to the common component 'C' deduced from oceanic basalts. The second end-member component (C-2) is represented by lavas near the transition between older and younger, and has isotopic composition similar to that of the seafloor basalts of the Red Sea and the Gulf of Aden. The third end-member component (C-3) is prominent in the older mafic series, and similar isotopically to Pan-African lithosphere. The younger felsic volcanic rocks generally have higher Sr-87/Sr-86(i) (0.70395-0.70689) than younger mafic series (0.70366-0.70454) but Nd, Hf and Pb isotopic ratios similar to those of the younger mafic lavas. The element concentrations and Sr, Nd, Hf and Pb isotopic compositions of the younger felsic rocks are explained by fractional crystallization of mafic melts in shallow-level magma chambers accompanied by limited assimilation of crustal material. Low degrees of partial melting of existing mafic underplate can account for the genesis of the least differentiated (intermediate) lavas, but failed to explain highly evolved younger felsic rocks. (C) 2017 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.lithos.2017.03.011

Post-collisional magmatism of western Chukotka and Early Cretaceous tectonic rearrangement in northeastern Asia

P. L. Tikhomirov, V. Yu Prokof'ev, I. A. Kal'ko, A. V. Apletalin, Yu N. Nikolaev, K. Kobayashi, E. Nakamura

GEOTECTONICS 51 ( 2 ) 131 - 151 2017年3月

記述言語：英語出版者・発行元：MAIK NAUKA/INTERPERIODICA/SPRINGER

The paper presents new data on the isotopic age and chemical composition of volcanic rocks from the Tytyl'veem and Mangazeika basins of western Chukotka superposed on Mesozoides of the Verkhoyansk-Chukotka Tectonic Region. The results of SIMS U-Pb zircon dating (121.4 +/- 2.8 and 118.0 +/- 2.0 Ma) corroborate the Aptian age of the Tytyl'veem Formation. This age, in turn, indicates its formation after closure of the South Anyui ocean (Neocomian), but before origination of the Okhotsk-Chukotka Belt (Albian-Campanian). Post-collisional Aptian igneous rocks are widespread in the northern Verkhoyansk-Chukotka Tectonic Region; the legth of the corresponding igneous province is no less than 1400 km. In geochemical characteristics, the post-collisional volcanic rocks occurring in Western Chukotka are similar with the rocks from Andean-type igneous belts.

DOI： 10.1134/S0016852117020054

Trace element and isotopic geochemistry of Cretaceous magmatism in NE Asia: Spatial zonation, temporal evolution, and tectonic controls

Petr L. Tikhomirov, Elena A. Kalinina, Takuya Moriguti, Akio Makishima, Katsura Kobayashi, Eizo Nakamura

LITHOS 264 453 - 471 2016年11月

記述言語：英語出版者・発行元：ELSEVIER SCIENCE BV

Results of a comprehensive geochemical study (major and trace elements, and isotopes of Sr, Nd, Pb, Hf) of Cretaceous volcanic rocks from the Chukotka area in northeastern Russia are presented. Synthesis of available geological and geochronological data suggests diachronous onset of activity of the Okhotsk-Chukotka volcanic belt (OCVB), the largest magmatic province in the region. The OCVB consists of ca. 10(6) km(3) of volcanic rocks. At 106-105 Ma, subduction-related magmatism initiated in the southern and central segments of the OCVB. In the Central and Northern Chukotka areas, where the northern OCVB is exposed, onset of arc magmatism occurred ca. 10 m.y. after extension-related magmatism of the Chaun igneous province at 109-104 Ma. Mafic rocks from the OCVB yield (Sr-87/Sr-86)(80) (Ma) of 0.7033 to 0.7047, epsilon Nd-80 (Ma) of 0.0 to 7.10, epsilon Hf-80 (Ma) of 4.12 to 12.88, ((206)pw(204)pb)(80 Ma) of 18.11 to 18.42, and ((208)pb/(204)pb)(80 Ma) of 37.96 to 38.21. Volcanic rocks from the Chaun province, as well as OCVB rocks from Northern Chukotka, originate from a relatively enriched source and have (Sr-87/Sr-86)(80) (Ma) of 0.7088 to 0.7100, epsilon Nd-80 (Ma) of -5.81 to -3.42, epsilon Hf-80 (Ma) of -3.40 to -0.25, ((206)pb/(204)pb)(80 Ma) of 18.69 to 18.90, and ((208)pb/(204)pb)(80 Ma) of 38.65 to 38.86. No definitive across-arc elemental or isotopic zonation of the OCVB has been revealed, probably because of wide-scale crustal melting and subsequent contamination of mantle-derived melts. However, there is a clear along-arc isotopic zonation. In our interpretation, this results from heterogeneity of the subcontinental lithospheric mantle, which likely was a major contributor to the magma source. The similar isotopic signatures of silicic (dominantly crust-derived) and mafic (mantle-derived) volcanic rocks in each OCVB segment imply that remelting of juvenile mafic underplated material was the main process responsible for the crust-derived magma generation. These data from the major Cretaceous magmatic provinces of northeast Asia are synthesized in context of existing plate tectonic reconstructions. (C) 2016 Elsevier B.V. All rights reserved:

DOI： 10.1016/j.lithos.2016.08.009

The oxygen isotope composition of San Carlos olivine on the VSMOW2-SLAP2 scale

Andreas Pack, Ryoji Tanaka, Markus Hering, Sukanya Sengupta, Stefan Peters, Eizo Nakamura

RAPID COMMUNICATIONS IN MASS SPECTROMETRY 30 ( 13 ) 1495 - 1504 2016年7月

記述言語：英語出版者・発行元：WILEY-BLACKWELL

RATIONALE: The precise determination of Delta'O-17 values in terrestrial material is becoming increasingly important to understand the mass-dependent fractionation processes that cause variations in oxygen isotope ratios. San Carlos olivine is widely used as the reference material for oxygen isotope measurements of terrestrial and extraterrestrial materials. We report new Delta'O-17 values for San Carlos olivine that were independently determined in two different laboratories (Geoscience Center [GZG], University of Gottingen) and Institute for Study of the Earth's Interior [ISEI], Okayama University, Misasa) in direct comparison with VSMOW2 and SLAP2 water standards.
METHODS: The delta O-17 and delta O-18 values of VSMOW2, SLAP2, GISP, and San Carlos olivine were determined relative to reference gas. In both laboratories, water and San Carlos olivine samples were prepared by BrF5 fluorination. In both laboratories, the O-2 released from water and olivine samples was passed through the same purification system and measured using the same mass spectrometer relative to the same reference gas.
RESULTS: In both laboratories, the delta O-17(VSMOW2) and delta O-18 (VSMOW2) scales were slightly compressed with respect to the recommended composition of VSMOW2 and SLAP2. The new Delta'O-17(0.528) value (calculated from the VSMOW2-SLAP2 scaled 6 values) of San Carlos olivine from GZG was -36 +/- 9 ppm and, from ISEI, a value of -40 +/- 7 ppm (1(7 standard deviation) was determined. These values are similar to 50 ppm higher than previously reported from the same laboratories. Possible causes for the observed discrepancies are discussed.
CONCLUSIONS: The results of this study in comparison with previous data from the same laboratories demonstrated that for high accuracy determination of Delta'O-17 values: (i) calibration of the reference gas relative to O-2 released from primary standards (VSMOW2, SLAP2) in the same laboratory is highly recommended, (ii) non-linearity of the mass spectrometer may not only affect delta O-17 and delta O-18 values but also Delta'O-17 values, and (iii) the VSMOW2-SLAP2 scaling should also be applied to analyses of rocks and minerals. Studies that are concerned with small differences in Delta'O-17 at similar delta O-18 values, however, are not affected by non-linearity of the mass spectrometer. Copyright (C) 2016 John Wiley & Sons, Ltd.

DOI： 10.1002/rcm.7582

Comment on "Diverse magmatic effects of subducting a hot slab in SW Japan: Results from forward modeling'' by J.-I. Kimura et al.

Ivan Pineda-Velasco, Tai T. Nguyen, Hiroshi Kitagawa, Eizo Nakamura

GEOCHEMISTRY GEOPHYSICS GEOSYSTEMS 16 ( 9 ) 2848 - 2852 2015年9月

Geochemical heterogeneities in magma beneath Mount Etna recorded by 2001-2006 melt inclusions

Federica Schiavi, Alberto Rosciglione, Hiroshi Kitagawa, Katsura Kobayashi, Eizo Nakamura, Pasquale Mario Nuccio, Luisa Ottolini, Antonio Paonita, Riccardo Vannucci

GEOCHEMISTRY GEOPHYSICS GEOSYSTEMS 16 ( 7 ) 2109 - 2126 2015年7月

記述言語：英語出版者・発行元：AMER GEOPHYSICAL UNION

We present a geochemical study on olivine and clinopyroxene-hosted melt inclusions (MIs) from 2001 to 2006 Etna basaltic lavas and pyroclastites. Three MI suites are distinguished on the basis of trace element fingerprinting. Type-1 MIs (from 2001 Upper South and 2002 Northeast vents) share their trace element signature with low-K lavas erupted before 1971. Critical trace element ratios (e.g., K/La, Ba/Nb), along with Pb isotope data of Type-1 MIs provide evidence for a heterogeneous mantle source resulting from mixing of three end-members with geochemical and isotopic characteristics of EM2, DMM, and HIMU components. Type-1 MIs composition does not support involvement of subduction-related components. Type-2 (from 2001 Lower and 2002 South vents) and Type-3 (2004 eruption) MIs reveal ghost plagioclase signatures, namely lower concentrations in strongly incompatible elements, and positive Sr, Ba, and Eu anomalies. Both Type-1 and Type-2 MIs occur in 2006 olivines, which highlight the occurrence of mixing between Type-1 and Type-2 end-members. Type-2/Type-3 MIs testify to en route processes (plagioclase assimilation and volatile fluxing) peculiar for deep dike fed eruptions. The latter are strongly controlled by tectonics or flank instability that occasionally promote upraise of undegassed, more radiogenic primitive magma, which may interact with plagioclase-rich crystal mush/cumulates before erupting. Type-2/Type-3 MIs approach the less radiogenic Pb isotopic composition of plagioclase from prehistoric lavas, thus suggesting geochemical overprinting of present-day melts by older products released from distinct mantle sources. Our study emphasizes that MIs microanalysis offers new insights on both source characteristics and en route processes, allowing to a link between melt composition and magma dynamics.

DOI： 10.1002/2015GC005786

Evaluation of the applicability of acid leaching for the U-238-Th-230 internal isochron method

Ryoji Tanaka, Tetsuya Yokoyama, Hiroshi Kitagawa, Demissie Bizuneh Tesfaye, Eizo Nakamura

CHEMICAL GEOLOGY 396 255 - 264 2015年3月

記述言語：英語出版者・発行元：ELSEVIER SCIENCE BV

The U-238-Th-230 internal isochron method has great potential for determining eruption ages of young volcanic materials if the separated groundmass phases have a sufficiently wide range of U/Th ratios. We examined the fractionation behavior of U and Th in aged (i.e., >0.5 Ma) basaltic samples by 6 M hydrochloric acid leaching to evaluate the applicability of acid-leaching treatment for the U-238-Th-230 internal isochron method. Acid leaching of aged basaltic rocks in U-238-U-234-Th-230 secular equilibrium at the bulk-rock scale results in Th-230-U-238 and U-234-U-238 radioactive disequilibria for both leachates and residues. These radioactive disequilibria can be explained by redistribution of Th-234 (parent of U-234) and Th-230 between acid-soluble and acid-resistant phases due to alpha-recoil. The number of Th-230 atoms redistributed by alpha-recoil can be calculated by using a mass conservation equation for U-234 atoms and by the relative amount of recoiled Th-230 and Th-234, the latter proportional to the kinetic energy of the recoiled nuclide. When the fraction of daughter nuclide U-234 remaining in either the residue or leachate, after alpha-recoil redistribution of U-238, is large enough (>95%), the corrected (Th-230/U-238) values of leachate and residue show radioactive equilibria. This result demonstrates that preferential fractionation between U and Th does not occur during acid leaching for basaltic samples if there is no selective etching of the alpha-recoil track. This study implies that acid-leaching can be used in conjunction with the U-238-Th-230 internal isochron method for dating young volcanic rocks by evaluating the degree of the alpha-recoil redistribution of U-234. (C) 2015 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.chemgeo.2014.12.025

In situ ion-microprobe determination of trace element partition coefficients for hornblende, plagioclase, orthopyroxene, and apatite in equilibrium with natural rhyolitic glass, Little Glass Mountain Rhyofite, California

James G. Brophy, Tsutomu Ota, Tak Kunihro, Tatsuki Tsujimori, Eizo Nakamura

AMERICAN MINERALOGIST 96 ( 11-12 ) 1838 - 1850 2011年11月

記述言語：英語出版者・発行元：MINERALOGICAL SOC AMER

Partially crystalline hornblende gabbro inclusions from the Little Glass Mountain Rhyolite contain euhedral plagioclase, orthopyroxene, hornblende, and apatite crystals in contact with interstitial rhyolitic (71-76% SiO(2)) glass. Textural and mineral compositional data indicate that the gabbros crystallized sufficiently slowly that surface equilibrium was closely approached at the interface between crystals and the liquid. This rare occurrence represents a natural dynamic crystallization experiment with a "run time" that is not realistically achievable in the laboratory. SIMS analysis of mineral rim-glass pairs have permitted the determination of high-quality, equilibrium trace-element partition coefficients for all four minerals. These data augment the limited partition coefficient database for minerals in high-SiO(2) rhyolitic systems. For all minerals, the D values are consistent with those anticipated from crystal-chemical considerations. These data further support a liquid SiO(2) control on the REEs (and presumably other elements) partitioning wherein D values systematically increase with increasing liquid SiO(2) content.

DOI： 10.2138/am.2011.3857

Mineralogical and geochemical constraints on magmatic evolution of Paleocene adakitic andesites from the Yanji area, NE China

Feng Guo, Eizo Nakamura, Weiming Fan, Katsura Kobayashi, Chaowen Li, Xiaofeng Gao

LITHOS 112 ( 3-4 ) 321 - 341 2009年10月

記述言語：英語出版者・発行元：ELSEVIER SCIENCE BV

Paleocene (55-58 Ma) adakitic andesites from the Yanji area of NE China are subdivided into clinopyroxene andesites and amphibole andesites. Relative to the clinopyroxene andesites, the amphibole andesites contain higher SiO(2), K(2)O and lower MgO, FeGr, Al(2)O(3), CaO, TiO(2), Cr, Ni, Sr, Y and Nb, and have evolved Sr-Nd-Pb isotope compositions. Compositional variation between the clinopyroxene andesites and amphibole andesites involves systematic decreases in MgO, Sr/Nd and epsilon(Nd)(t) accompanied by increases in (87)Sr/(86)Sr(i) and (206)Pb/(204)Pb(i), and suggests a role for crustal contamination. The compositional variations recorded in clinopyroxene and amphibole phenocrysts indicate that the primary mantle-derived adakitic magma experienced complex crustal-level processes, including magma mixing, fractional crystallization and crustal contamination or assimilation. The low Na(2)O contents and adakitic trace element features (high Sr/Y and Nd/Yb) in Mg-rich parts of clinopyroxene phenocrysts, and negative Sr and Eu anomalies in the Fe-rich clinopyroxene cores, suggest that all clinopyroxenes crystallized in equilibrium with little or no garnet, and argues against magmatic evolution involving differentiation of basaltic magmas. Combined mineralogical and geochemical data indicate that the clinopyroxene andesites were generated by magma mixing, clinopyroxene fractionation and limited degrees of crustal assimilation; whereas the amphibole andesites underwent magma mixing, fractionation of clinopyroxene + amphibole +/- plagioclase and higher degree of crustal assimilation. The difference in mineralogical assemblage between the two rock types was influenced by magma temperature, i.e., 900-950 degrees C for the amphibole andesites and >950 degrees C for the clinopyroxene andesites. Our results provide the following important constraints on high-MgO adakitic magma (or low-SiO(2) adakite) petrogenesis: (1) the primary magma of such adakites is probably produced through melting of slab melt-modified mantle rather than being a slab melt variably hybridized by peridotite: (2) The complex magmatic evolution recorded in the Yanji adakitic andesites suggests that such adakitic rocks are far from melts in equilibrium with mantle, and magmatic process needs to be carefully examined before the petrogenetic or geodynamic significance can be assessed: (3) The perquisites for creating high-MgO or low-SiO(2) adakites include slab melt-mantle interaction during oceanic slab subduction and melting of this metasomatized mantle, but this melting event need not necessarily be related in time to the subduction event. (C) 2009 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.lithos.2009.03.017

Accumulation of radium in ferruginous protein bodies formed in lung tissue: association of resulting radiation hotspots with malignant mesothelioma and other malignancies

Eizo Nakamura, Akio Makishima, Kyoko Hagino, Kazunori Okabe

PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES 85 ( 7 ) 229 - 239 2009年7月

記述言語：英語出版者・発行元：JAPAN ACAD

While exposure to fibers and particles has been proposed to be associated with several different lung malignancies including mesothelioma, the mechanism for the carcinogenesis is not fully understood. Along with mineralogical observation, we have analyzed forty-four major and trace elements in extracted asbestos bodies (fibers and proteins attached to them) with coexisting fiber-free ferruginous protein bodies from extirpative lungs of individuals with malignant mesothelioma,. These observations together with patients' characteristics suggest that inhaled iron-rich asbestos fibers and dust particles, and excess iron deposited by continuous cigarette smoking would induce ferruginous protein body formation resulting in ferritin aggregates in lung tissue. Chemical analysis of ferruginous protein bodies extracted from lung tissues reveals anomalously high concentrations of radioactive radium, reaching millions of dines higher concentration than that of seawater. Continuous and prolonged internal exposure to hotspot ionizing radiation from radium and its daughter nuclides could cause strong and frequent DNA damage in lung tissue, initiate different types of tumour cells, including malignant mesothelioma cells, and may cause cancers.

DOI： 10.2183/pjab.85.229

Transitional time of oceanic to continental subduction in the Dabie orogen: Constraints from UPb, LuHf, SmNd and ArAr multichronometric dating

Cheng, H, King, R. L, Nakamura, E, Vervoort, J. D, Zheng, Y.-F, Ota, T, Wu, Y.-B, Kobayashi, K, Zhou, Z.-Y

Lithos, 110, 327-342, 2009. 110 ( 1-4 ) 327 - 342 2009年6月

Elemental and isotopic abundances of lithium in chondrule constituents in the Allende meteorite

Seiji Maruyama, Masaki Watanabe, Tak Kunihiro, Eizo Nakamura

GEOCHIMICA ET COSMOCHIMICA ACTA 73 ( 3 ) 778 - 793 2009年2月

記述言語：英語出版者・発行元：PERGAMON-ELSEVIER SCIENCE LTD

Elemental and isotopic abundances of lithium in chondrule constituents in the Allende CV3 meteorite were determined using secondary ion mass spectrometry. Olivines and mesostasis dominated by a feldspathic phase are depleted in Li (< 1 mu g g(-1) and 0.1-0.6 mu g g(-1), respectively). In contrast, low-Ca pyroxenes and mesostasis dominated by a Na-rich phase are enriched in Li (similar to 1-8 mu g g(-1) and 0.4-3.5 mu g g(-1), respectively) and the interchondrule matrix is generally enriched in Li (similar to 2.0 mu g g(-1) on average). The Li isotopic abundance of olivine ranges from delta(7)Li similar to -32 to 21. The spatial distributions of elemental and isotopic abundances of Li in olivines within individual chondrules exhibit no systematic pattern. This suggests that the distribution of Li in olivine was not disturbed during aqueous alteration or thermal metamorphism on the Allende meteorite parent body. Although mesostasis is the last crystallizing phase from a chondrule melt and is expected to be enriched in Li, in the Allende meteorite it is generally depleted in Li. We suggest that during aqueous alteration on the CV asteroid, Li in mesostasis was leached out by aqueous fluids. The Li-enriched Na-rich mesostasis was probably produced later by infiltration of Na-rich fluids. It seems likely that aqueous fluids sequestered alkali elements from the Allende-chondrite region in the CV parent asteroid, although significant amounts of Li are preserved in ferrous olivine in the interchondrule matrix. (C) 2008 Elsevier Ltd. All rights reserved,

DOI： 10.1016/j.gca.2008.10.039

Determination of Ge, As, Se and Te in Silicate Samples Using lsotope Dilution-Internal Standardisation Octopole Reaction Cell ICP-QMS by Normal Sample Nebulisation, Geostand.

Makishima, A, Nakamura, E

Geoanal. Res. ( 33 ) 369 - 384 2009年

Comprehensive analysis for major, minor and trace element contents and Sr-Nd-Pb-Hf isotope ratios in sediment reference materials, JSd-1 and MAG-1

Nagender Nath, B, Makishima, A, Noordmann, J, Tanaka, R, Nakamura, E

, Geochem. J. ( 43 ) 207 - 216 2009年

Recycled crustal melt injection into lithospheric mantle: implication from cumulative composite and pyroxenite xenoliths,

Zhang, H.-F, Nakamura, E, Kobayashi, K, Ying J.-F, Tang, Y.-J

Int. J. Earth. Sci., ( 98 ) 2009年

Coupled Lu-Hf and Sm-Nd geochronology constrains garnet growth in ultra-high-pressure eclogites from the Dabie orogen

H. Cheng, R. L. King, E. Nakamura, J. D. Vervoort, Z. Zhou

JOURNAL OF METAMORPHIC GEOLOGY 26 ( 7 ) 741 - 758 2008年9月

記述言語：英語出版者・発行元：WILEY-BLACKWELL

Ultra-high-pressure eclogites from the Dabie orogen that formed over a range in temperatures (similar to 600 to > 700 degrees C) have been investigated with combined Lu-Hf and Sm-Nd geochronology. Three eclogites, sampled from Zhujiachong, Huangzhen and Shima, yield Lu-Hf ages of 240.0 +/- 5.0, 224.4 +/- 1.9 and 230.8 +/- 5.0 Ma and corresponding Sm-Nd ages of 222.5 +/- 5.0, 217.6 +/- 6.1 and 224.2 +/- 2.1 Ma respectively. Well-preserved prograde major- and trace-element zoning in garnet in the Zhujiachong eclogite suggests that the Lu-Hf age mostly reflects an early phase of garnet growth that continued over a time interval of c. 17.5 Myr. For the Huangzhen eclogite, despite preserved elemental growth zoning in garnet, textural study reveals that the Lu-Hf age is biased towards a later garnet growth episode rather than representing early growth. The narrow time interval of < 6.6 Myr defined by the difference between Lu-Hf and Sm-Nd ages indicates a short final garnet growth episode and suggests a rapid cooling stage. By contrast, the rather flat element zoning in garnet in the Shima eclogite suggests that Lu-Hf and Sm-Nd ages for this sample have been reset by diffusion and are cooling ages. The new Lu-Hf ages point to an initiation of prograde metamorphism prior to c. 240 Ma for the Dabie orogen, while the exact peak metamorphic timing experienced by specific samples ranges between c. 230 to c. 220 Ma.

DOI： 10.1111/j.1525-1314.2008.00785.x

Metamorphic history and tectonic evolution of the Himalayan UHP eclogites in Kaghan valley, Pakistan

Hafiz Ur Rehman, Hiroshi Yamamoto, M. Ayub Khan Khalil, Eizo Nakamura, Muhammad Zafar, Tahseenullah Khan

JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES 103 ( 4 ) 242 - 254 2008年8月

記述言語：英語出版者・発行元：JAPAN ASSOC MINERALOGICAL SCIENCES

Eclogites of the Kaghan valley, Pakistan Himalaya were investigated petrographically and geochemically. Based on petrography, geochemistry and mineral compositions, metamorphic history and a reasonable tectonic model are proposed. Eclogites exposed in the Kaghan valley are classified into two groups. Group I eclogites appear as massive and Group II are lens-type. Group I eclogites have a mineral assemblage of garnet, omphacitic clinopyroxene, quartz, symplectite with rare epidote and phengite. Accessory minerals include abundent zircon, rutile. ilmenite, and rare apatite. Group II eclogites have a mineral assemblage of garnet, omphacitic clinopyroxene, phengite, quartz/coestie, epidote, and symplectite. In accessory minerals rutile and ilmenite are common while zircon and apatite are rare. Different types of protolith are proposed for these eclogites. Group I eclogitcs have higher FeO and TiO2 contents and trace element contents. and seem to be derived from gabbroic protolith. Group II eclogites have lower FeO and TiO2 and trace element contents and were derived From basalts. Pressure-temperature-time path was constructed for the Kaghan valley eclogites using various mineral assemblages along with textural relationship and inclusions Study. At least three distinct metamorphic stages were identified. The first stage is the prograde garnet growth stage deduced from the inclusion paragenesis in garnet core. The second stage records the ultrahigh-pressure metamorphic stage deduced from the pressence Of coesite inclusions in omphacitic clinopyroxene. The third stage is the decompression stage and is deduced from the quartz-albite-amphibole symplectite portions. These petrological and geochemical results combined with isotopic ages reported elsewhere indicate that basalts and associated gabbroic dikes were emplaced at about 267 Ma when the Indian plate was moving northward and passing above an unknown hot spot. The Closure of the Tethys and initiation of collision of the Indian plate with the Kohistan-Ladakh Island Arc is reported from 65-50 Ma. After that the leading-edge of the Indian plate underwent eclogite facies metamorphism at 49 Ma and when it reached to depths of about 100 kin, the Ultrahigh-pressure metamorphic event took place at 46 Ma.

DOI： 10.2465/jmps.080222

Boron cycling by subducted lithosphere; insights from diamondiferous tourmaline from the Kokchetav ultrahigh-pressure metamorphic belt

Tsutomu Ota, Katsura Kobayashi, Takuya Kunihiro, Eizo Nakamura

GEOCHIMICA ET COSMOCHIMICA ACTA 72 ( 14 ) 3531 - 3541 2008年7月

記述言語：英語出版者・発行元：PERGAMON-ELSEVIER SCIENCE LTD

Subduction of lithosphere, involving surficial materials, into the deep mantle is fundamental to the chemical evolution of the Earth. However, the chemical evolution of the lithosphere during subduction to depth remains equivocal. In order to identify materials subjected to geological processes near the surface and at depths in subduction zones, we examined B and Li isotopes behavior in a unique diamondiferous, K-rich tourmaline (K-tourmaline) from the Kokchetav ultrahigh-pressure metamorphic belt. The K-tourmaline, which includes microdiamonds in its core, is enriched in B-11 relative to B-10 (delta B-11 = -1.2 to +7.7) and Li-7 relative to Li-6 (delta Li-7 = -1.1 to +3.1). It is suggested that the K-tourmaline crystallized at high-pressure in the diamond stability field from a silicate melt generated at high-pressure and temperature conditions of the Kokchetav peak metamorphism. The heavy isotope signature of this K-tourmaline differs from that of ordinary Na-tourmalines in crustal rocks, enriched in the light B isotope (delta B-11 = -16.6 to -2.3), which experienced isotope fractionation through metamorphic dehydration reactions. A possible source of the heavy B-isotope signature is serpentine in the subducted lithospheric mantle. Serpentinization of the lithospheric mantle, with enrichment of heavy B-isotope, can be produced by normal faulting at trench-outer rise or trench slope regions, followed by penetration of seawater into the lithospheric mantle. Serpentine breakdown in the lithospheric mantle subducted in subarc regions likely provided fluids with the heavy B-isotope signature, which was acquired during the serpentinization prior to subduction. The fluids could ascend and cause partial melting of the overlying crustal layer, and the resultant silicate melt could inherit the heavy B-isotope signature. The subducting lithospheric mantle is a key repository for modeling the flux of fluids and associated elements acquired at a near the surface into the deep mantle. (c) 2008 Elsevier Ltd. All rights reserved.

DOI： 10.1016/j.gca.2008.05.002

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