記述言語：英語   掲載種別：研究論文（学術雑誌）  

Bandgap-engineered inorganic and hybrid halide perovskite (HP) films, nanocrystals, and quantum dots (PQDs) are promising for solar cells. Fluctuations of photoinduced electron transfer (PET) rates affect the interfacial charge separation efficiencies of such solar cells. Electron donor- or acceptor-doped perovskite samples help analyze PET and harvest photogenerated charge carriers efficiently. Therefore, PET in perovskite-based donor-acceptor (D-A) systems has received considerable attention. We analyzed the fluctuations of interfacial PET from MAPbBr3 or CsPbBr3 PQDs to classical electron acceptors such as 7,7,8,8-tetracyanoquinodimethane (TCNQ) and 1,2,4,5-tetracyanobenzene (TCNB) at single-particle and ensemble levels. The significantly negative Gibbs free energy changes of PET estimated from the donor-acceptor redox potentials, the donor-acceptor sizes, and the solvent dielectric properties help us clarify the PET in the above D-A systems. The dynamic nature of PET is apparent from the decrease in photoluminescence (PL) lifetimes and PL photocounts of PQDs with an increase in the acceptor concentrations. Also, the acceptor radical anion spectrum helps us characterize the charge-separated states. Furthermore, the PL blinking time and PET rate fluctuations (108 to 107 s-1) provide us with single-molecule level information about interfacial PET in perovskites.

DOI： 10.1039/d3nr01032e

PubMed

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掲載種別：研究論文（学術雑誌）   出版者・発行元：American Chemical Society (ACS)  

DOI： 10.1021/acsnano.2c12670

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-V C H VERLAG GMBH  

Halide perovskites are materials for future optical displays and solar cells. Electron donor-acceptor perovskite heterostructures with distinguishing halide compositions are promising for transporting and harvesting photogenerated charge carriers. Combined e-beam lithography and anion exchange are promising to develop such heterostructures but challenging to prepare multiple heterojunctions at desired locations in single crystals. We demonstrate swift laser trapping-assisted band gap engineering at the desired locations in MAPbBr(3) microrods, microplates, or nanocrystal thin films. The built-in donor-acceptor double and multi-heterojunction structures let us transport and trap photogenerated charge carriers from wide-band gap bromide to narrow-band gap iodide domains. We discuss the charge carrier transport and trapping mechanisms from the viewpoints of engineered bands and band continuity. This work offers a convenient method for designing single-, double- and multi-heterojunction donor-acceptor halide perovskites for photovoltaic, photonic, and electronic applications.

DOI： 10.1002/anie.202215947

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1515/nanoph-2021-0748

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その他リンク： https://www.degruyter.com/document/doi/10.1515/nanoph-2021-0748/pdf

記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1002/smtd.202101228

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その他リンク： https://onlinelibrary.wiley.com/doi/full-xml/10.1002/smtd.202101228

担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Wiley  

DOI： 10.1002/chem.202200288

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掲載種別：研究論文（学術雑誌）   出版者・発行元：Royal Society of Chemistry (RSC)  

We fabricate a novel photoanode consisting of TiO₂/Au nanoparticles (Au-NPs)/Ga₂O₃/TiN/Au film (TAGA), efficiently increasing light absorption and electron transfer from Au-NPs to Ga₂O₃ under modal strong coupling. A TiN thin...

DOI： 10.1039/d2na00768a

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掲載種別：研究論文（学術雑誌）  

DOI： 10.1038/s41467-021-26652-7

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1021/acs.nanolett.1c03324

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1016/j.jphotochemrev.2021.100472

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1021/acsnano.1c07137

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1021/acs.jpcc.1c05788

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1002/anie.202103445

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その他リンク： https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.202103445

記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.3390/nano11071730

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1021/acs.nanolett.1c01114

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1021/acs.nanolett.1c01322

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1021/acs.nanolett.1c00389

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：The Chemical Society of Japan  

DOI： 10.1246/cl.200790

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Royal Society of Chemistry (RSC)  

<p>The near field was tailored to be enhanced at the three-phase boundary of Au-NPs/TiO₂/H₂O for efficient water oxidation.</p>

DOI： 10.1039/d0cc07335k

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Royal Society of Chemistry (RSC)  

<p>A wide range of technologies has been developed for producing hydrogen economically and in greener ways.</p>

DOI： 10.1039/d0na00641f

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Royal Society of Chemistry (RSC)  

<p>The plasmonic Ga₂O₃ photoanode with the interfacial TiO₂ modification provide both a high reduction ability and an oxidation ability.</p>

DOI： 10.1039/d0nr06319c

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Elsevier BV  

DOI： 10.1016/j.nanoen.2020.104965

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AIP Publishing  

The near-field properties and dynamics of plasmonic nanostructures play a crucial role in several fundamental concepts in physics and chemistry, and they are widely relevant in plasmonic applications. Ultrafast photoemission electron microscopy (PEEM) is a novel approach that has been widely applied to probe plasmonic nanostructures from multiple domains. Furthermore, PEEM is the only technique that provides nanometer spatial resolution, sub-femtosecond temporal resolution, and tens to hundreds of millielectron volt energy resolution. This allows for extremely sensitive observations of plasmonic field oscillations, field dephasing, and hot electrons. This Perspective provides a brief overview of the basic principles and main applications of ultrafast PEEM. The research progress of ultrafast PEEM in plasmonics is highlighted from three points of view: near-field imaging, near-field spectroscopy, and ultrafast dynamics. Future applications of PEEM in plasmonics for the probing of plasmonic hot electron dynamics in the energy and time domains are proposed and discussed.

DOI： 10.1063/5.0013659

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：American Chemical Society (ACS)  

Plasmon-induced carrier transfer at metallic nanoparticle/semiconductor heterojunctions has received great attention because of its tremendous potential in applications, such as photocatalysis and photoelectric and energy conversion. The interfacial structure of the heterojunction is known to play an important role in charge transfer as well as the subsequent chemical reactions. Here, we studied the Au nanoparticle (Au-NP)-loaded (100)-, (110)-, and (111)-oriented single-crystalline strontium titanate (STO) as a model to investigate the effects of interfacial structure on the plasmon-induced charge separation between the metallic nanoparticles and semiconductors. Via photoelectrochemical characterizations, we found that the efficiency of the plasmon-induced water oxidation reaction on STO(100) is more than 1.4 times higher than that on the other two orientation facets. This enhancement was demonstrated to stem from the high oxidation ability of plasmon-induced holes captured in the surface states. Furthermore, the molecular processes of water oxidation were investigated by monitoring the surface oxidation status of Au-NP/STO as intermediates of plasmon-induced water oxidation using in situ electrochemical surface-enhanced Raman spectroscopy. The onset potential of Au-O vibrations on Au-NP/STO(100) was determined to be 0.4 V more negative than that of Au-NP/STO(110), further confirming the higher oxidation ability of the plasmon-induced holes. Our observation provides an opportunity to efficiently modulate plasmon-excited hot-carrier reaction processes for photochemical applications through interfacial engineering.

DOI： 10.1021/acsaem.0c00648

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：American Chemical Society (ACS)  

Plasmonic Au/TiO2 thin film works as a stable water oxidation photoanode. Here we show that site-selective deposition of nanosized CoOx as a water oxidation cocatalyst at the edge of Au nanoparticles on the TiO2 film improves the photoelectrochemical water oxidation activity. The nanosized CoOx was deposited by a photoassisted electrochemical method onto the Au/TiO2 thin film. The CoOx loading amount was controllable by changing the amount of electric charge that flowed during the deposition, which influenced the photoelectrochemical performance. Under visible light, the optimized CoOx/Au/TiO2 thin film generated stable photoanodic current, which was similar to 3 times higher than that obtained using Au/TiO2.

DOI： 10.1021/acsaem.0c00857

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掲載種別：研究論文（学術雑誌）   出版者・発行元：American Chemical Society (ACS)  

DOI： 10.1021/acs.nanolett.0c00742

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Wiley  

DOI： 10.1002/ejic.201901260

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その他リンク： http://onlinelibrary.wiley.com/wol1/doi/10.1002/ejic.201901260/fullpdf

担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：American Physical Society (APS)  

Near-field enhancement and dephasing time play critical roles in several applications of localized surface plasmon resonance. Here, using an example gold dimer system, we reveal the correlation between the near-field enhancement and dephasing time via time-resolved photoemission electron microscopy. Compared with isolated particles, dimers with small gap sizes show stronger near-field enhancement and shorter dephasing times. These results are well reproduced by numerical simulations and further explained by a coupled dipole approximation model. The roles of near- and far-field coupling and plasmon localization in balancing near-field enhancement and dephasing time are also unveiled.

DOI： 10.1103/physrevlett.124.163901

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その他リンク： http://harvest.aps.org/v2/journals/articles/10.1103/PhysRevLett.124.163901/fulltext

記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：American Chemical Society (ACS)  

Two-dimensional spiral plasmonic structures have emerged as a versatile approach to generate near-field vortex fields with tunable topological charges. We demonstrate here a far-field approach to observe the chiral second-harmonic generation (SHG) at designated visible wavelengths from a single plasmonic vortex metalens. This metalens comprises an Archimedean spiral slit fabricated on atomically flat aluminum epitaxial film, which allows for precise tuning of plasmonic resonances and subsequent transfer of two-dimensional materials on top of the spiral slit. The nonlinear optical measurements show a giant SHG circular dichroism. Furthermore, we have achieved an enhanced chiral SHG conversion efficiency (about an order of magnitude greater than the bare aluminum lens) from monolayer tungsten disulfide (WS2)/aluminum metalens, which is designed at the C-exciton resonance of WS2. Since the C-exciton is not a valley exciton, the enhanced chiral SHG in this hybrid system originates from the plasmonic vortex field-enhanced SHG under the optical spin-orbit interaction.

DOI： 10.1021/acs.nanolett.0c00645

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：MDPI AG  

Minimum inhibition concentration (MIC) of antibiotic is an effective value to ascertain the agent and minimum dosage of inhibiting bacterial growth. However, current techniques to determine MIC are labor intensive and time-consuming, and require skilled operator and high initial concentration of bacteria. To simplify the operation and reduce the time of inhibition test, we developed a microfluidic system, containing a concentration generator and sub-micro-liter chambers, for rapid bacterial growth and inhibition test. To improve the mixing effect, a micropillar array in honeycomb-structure channels is designed, so the steady concentration gradient of amoxicillin can be generated. The flanged chambers are used to culture bacteria under the condition of continuous flow and the medium of chambers is refreshed constantly, which could supply the sufficient nutrient for bacteria growth and take away the metabolite. Based on the microfluidic platform, the bacterial growth with antibiotic inhibition on chip can be quantitatively measured and MIC can be obtained within six hours using low initial concentration of bacteria. Overall, this microfluidic platform has the potential to provide rapidness and effectiveness to screen bacteria and determine MIC of corresponding antibiotics in clinical therapies.

DOI： 10.3390/mi11020207

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：American Chemical Society (ACS)  

DOI： 10.1021/acs.jpcc.9b10485

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AIP Publishing  

DOI： 10.1063/1.5134900

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Wiley  

DOI： 10.1002/adom.201900580

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その他リンク： https://onlinelibrary.wiley.com/doi/full-xml/10.1002/adom.201900580

記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Elsevier BV  

DOI： 10.1016/j.apmt.2019.05.003

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掲載種別：研究論文（学術雑誌）   出版者・発行元：Wiley  

DOI： 10.1002/cnma.201900273

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Wiley  

DOI： 10.1002/cnma.201900178

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その他リンク： https://onlinelibrary.wiley.com/doi/full-xml/10.1002/cnma.201900178

担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Royal Society of Chemistry (RSC)  

<p>Ammonia photosynthesis under visible light irradiation <italic>via</italic> an associative pathway using a plasmonic photoanode and a zirconium cathode is proposed.</p>

DOI： 10.1039/c9gc01658a

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記述言語：中国語   掲載種別：研究論文（学術雑誌）  

DOI： 10.3788/cjl201946.0508001

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Wiley  

DOI： 10.1002/adom.201801060

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その他リンク： https://onlinelibrary.wiley.com/doi/full-xml/10.1002/adom.201801060

担当区分：最終著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：The Chemical Society of Japan  

The nanostructure control of strong coupling has been less thoroughly investigated in organic semiconductor structures than in resonator structures. We achieved strong coupling by introducing a layered silicate between a silver nanodisk resonator and a porphyrin organic semiconductor, where the porphyrin nanostructure is monomeric and parallel to the silicate surface.

DOI： 10.1246/cl.180925

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Elsevier BV  

The construction of metallic nanostructures with strong near-field enhancement is becoming increasingly significant for the practical use of plasmonic devices, such as plasmonic sensors and light-energy conversion systems. Importantly, the near-field enhancement effect depends on the plasmon dephasing time. Here, we propose a method for controlling plasmon dephasing time by utilizing plasmonic coupling for stronger near-field enhancement. Ordered arrays of stacked nanogap gold (Au) structures composed of a metal/insulator/metal nanostructure were fabricated by electron beam lithography and dry etching processes on a niobium-doped titanium dioxide substrate. The dark plasmon mode was excited by the near-field coupling between the upper and lower Au nanostructures separated by an alumina layer with a thickness of 15 nm. A strong near-field enhancement effect was induced by the localization of the electromagnetic field between the upper and lower Au nanostructures and the longer plasmon dephasing time based on the excitation of the dark plasmon mode. It is noteworthy that the dephasing time of the dark plasmon mode measured by time-resolved photoemission electron microscopy was extended 3-fold compared with that of the plasmon mode of the Au nanoblock, which can be controlled by the structural design of the stacked nanogap Au structures. (C) 2018 Elsevier Ltd. All rights reserved.

DOI： 10.1016/j.apmt.2018.12.004

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Opto-Electronic Advances  

DOI： 10.29026/oea.2019.180030

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Wiley  

DOI： 10.1002/adma.201806479

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その他リンク： https://onlinelibrary.wiley.com/doi/full-xml/10.1002/adma.201806479

担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：American Chemical Society (ACS)  

DOI： 10.1021/acs.jpcc.8b10263

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：MDPI AG  

Capacitively coupled contactless conductivity detection (C4D) is an improved approach to avoid the problems of labor-intensive, time-consuming and insufficient accuracy of plate count as well as the high-cost apparatus of flow cytometry (FCM) in bacterial counting. This article describes a novel electrode-integrated printed-circuit-board (PCB)-based C4D device, which supports the simple and safe exchange of capillaries and improves the sensitivity and repeatability of the contactless detection. Furthermore, no syringe pump is needed in the detection, it reduces the system size, and, more importantly, avoids the effect on the bacteria due to high pressure. The recovered bacteria after C4D detection at excitation of 25 Vpp and 60–120 kHz were analyzed by flow cytometry, and a survival rate higher than 96% was given. It was verified that C4D detection did not influence the bacterial viability. Moreover, bacteria concentrations from 106 cells/mL to 108 cells/mL were measured in a linear range, and relative standard deviation (RSD) is below 0.2%. In addition, the effects on bacteria and C4D from background solutions were discussed. In contrast to common methods used in most laboratories, this method may provide a simple solution to in situ detection of bacterial cultures.

DOI： 10.3390/mi10010055

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掲載種別：研究論文（学術雑誌）  

DOI： 10.1117/12.2527653

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担当区分：最終著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Institute of Electrical and Electronics Engineers ({IEEE})  

DOI： 10.1109/LPT.2018.2877964

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担当区分：責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Springer Science and Business Media LLC  

DOI： 10.1038/s41467-018-07356-x

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その他リンク： http://www.nature.com/articles/s41467-018-07356-x

記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Springer Science and Business Media LLC  

DOI： 10.1038/s41565-018-0208-x

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その他リンク： http://www.nature.com/articles/s41565-018-0208-x.pdf

担当区分：責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：American Chemical Society ({ACS})  

DOI： 10.1021/acs.jpcc.8b05755

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担当区分：最終著者,　責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：American Chemical Society (ACS)  

DOI： 10.1021/acs.jpcc.8b01198

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記述言語：英語   出版者・発行元：American Chemical Society  

Metallic nanoparticles such as silver and gold show localized surface plasmon resonances (LSPRs), which are associated with near-field enhancement effects in the vicinity of nanoparticles. Therefore, strong light-matter interaction is induced by the near-field enhancement effects of LSPRs. Because the resonant wavelength of LSPRs can be easily controlled by the size and shape of the metallic nanoparticles in the visible and near-infrared wavelength range, LSPRs have received considerable attention as optical antennae for light energy conversion systems such as solar cells. LSPRs decay very quickly as a result of light scattering and excitation of electron-hole pairs in the metal itself. However, in addition to the near-field enhancement effect, this light scattering and electron-hole pair excitation, which are known to cause loss of LSPRs, can be utilized as a solar cell enhancement mechanism. Here, we focus on plasmonic solid-state solar cells. The mechanisms of the light scattering by LSPRs, near-field enhancement, and plasmon-induced charge separation based on electron-hole pair excitations can be clarified. We review the related studies from the viewpoint of these mechanisms rather than material science.

DOI： 10.1021/acs.chemrev.7b00235

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出版者・発行元：OSA  

DOI： 10.1364/isuptw.2018.tud3

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

Near-field spectrum measurement techniques, including near-field scanning optical microscopy, electron energy loss spectroscopy, and multiphoton photoemission electron microscopy, are powerful means to investigate near-field interactions directly on closely spaced metallic nanoparticles or a metallic nanostructure coupled with optical modes, such as whispering gallery mode and waveguide mode, which are called coupled plasmonic systems. In the present study, we have successfully measured the near-field spectra of coupled plasmonic systems using a simple photoelectrochemical measurement based on plasmon-induced water oxidation. Coupling was explored between the localized surface plasmon resonance (LSPR.) mode and waveguide mode of periodic gold nanogratings patterned on a thin titanium dioxide waveguide film. It is known that the far-field reflection spectrum of this waveguide-LSPR coupling system shows a complicated shape with multiple peaks, and the coupling has been explored by numerical electromagnetic simulations so far. However, in this study, it was clearly elucidated that an internal quantum efficiency (IQE) spectrum observed in the plasmon-induced photocurrent generation has successfully reproduced the near-field spectrum predicted by electromagnetic simulations under the coupling conditions. The photocurrent generation based on the plasmon-induced charge separation is due to the near-field effect, and it can be considered that the IQE spectrum corresponds to the near-field spectrum. This study paves a new way to indirectly measure the near-field spectrum of plasmonic systems.

DOI： 10.1021/acs.jpcc.7b07707

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：NATURE PUBLISHING GROUP  

Plasmon-induced hot-electron generation has recently received considerable interest and has been studied to develop novel applications in optoelectronics, photovoltaics and green chemistry. Such hot electrons are typically generated from either localized plasmons in metal nanoparticles or propagating plasmons in patterned metal nanostructures. Here we simultaneously generate these heterogeneous plasmon-induced hot electrons and exploit their cooperative interplay in a single metal-semiconductor device to demonstrate, as an example, wavelength-controlled polarity-switchable photoconductivity. Specifically, the dual-plasmon device produces a net photocurrent whose polarity is determined by the balance in population and directionality between the hot electrons from localized and propagating plasmons. The current responsivity and polarity-switching wavelength of the device can be varied over the entire visible spectrum by tailoring the hot-electron interplay in various ways. This phenomenon may provide flexibility to manipulate the electrical output from light-matter interaction and offer opportunities for biosensors, long-distance communications, and photoconversion applications.

DOI： 10.1038/s41467-017-00815-x

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

We investigate the superposition properties of the dipole and quadrupole plasmon modes in the near field both experimentally, by using photoemission electron microscopy (PEEM), and theoretically. In particular, the asymmetric near-field distributions on gold (Au) nanodisks and nanoblocks under oblique incidence with different polarizations are investigated in detail. The results of PEEM measurements show that the evolutions of the asymmetric near-field distributions are different between the excitation with s-polarized and p-polarized light. The experimental results can be reproduced very well by numerical simulations and interpreted as the superposition of the dipole and quadrupole modes with the help of analytic calculations. Moreover, we hypothesize that the electrons collected by PEEM are mainly from the plasmonic hot spots located at the plane in the interface between the Au particles and the substrate in the PEEM experiments. (C) 2017 Chinese Laser Press

DOI： 10.1364/PRJ.5.000187

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ROYAL SOC CHEMISTRY  

In this study, we developed a three-dimensional plasmonic photoanode using titanium dioxide nanotunnels (TNTs) loaded with gold nanoparticles (Au-NPs) for water splitting, to enhance the reaction efficiency. We also optimized the procedure of loading Au-NPs on complex three-dimensional structures. We discuss the correlation between the plasmon-induced charge separation obtained from photoelectrochemical measurement and the morphology of Au-NPs observed by transmission electron microscopy. We have successfully deposited well-dispersed Au-NPs on the walls of TNTs using HAu(OH)(4) as a precursor. The amount of Au-NPs on the TNTs was estimated to be approximately 15-fold larger than that on the thin film titanium dioxide substrate, and the particle size remained small. Photoelectrochemical water splitting was achieved by using a two-electrode system rather than a three-electrode system. Furthermore, stoichiometric water splitting was confirmed by estimating the amounts of the evolved H-2 and O-2 gases under visible light irradiation.

DOI： 10.1039/c6gc03217f

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE BV  

We developed a localized surface plasmon-induced visible light-responsive photoelectrochemical (PEC) biosensor using a titanium dioxide (TiO2) photoelectrode loaded with gold nanoislands (AuNIs) for in situ real-time measurement of biotin-streptavidin association. As a proof of concept, self-assembled thiol-terminated biotin molecules bound on a AuNls/TiO2 photoelectrode were successfully utilized to explore the photocurrent response to streptavidin-modified gold nanoparticle (STA-AuNP) solutions. This plasmon-induced PEC biosensor is simple and easy to miniaturize. Additionally, the PEC biosensor achieves highly sensitive measurements under only visible light irradiation and prevents the UV-induced damage of samples. Furthermore, a novel approach has been proposed to realize the real-time monitoring of biotin-STA binding affinities and kinetics by analyzing the PEC sensing characteristics. This PEC biosensor and novel analysis method could provide a new approach for the specific electrical detection and real-time kinetic measurements for clinical diagnostics and drug development. (C) 2016 The Authors. Published by Elsevier B.V.

DOI： 10.1016/j.aca.2016.12.025

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

We examine the far-field and near-field properties of complementary screens made of nanostructured gold thin films, a rectangular nanowire and a nanovoid, using an aperture-type scanning near-field optical microscope and electromagnetic field calculations, and discuss the applicability of Babinet's principle in the optical region. The far-field transmission spectra of the complementary screens are considerably different from each other. On the other hand, genuine near-field extinction spectra exhibit nearly complementary characteristics. The spatial features of the observed near-field images for the complementary screens show little correlation. We have found from the Fourier analysis of the simulated images that high spatial-frequency components of the electromagnetic fields show mutual spatial correlation. These results suggest that Babinet's principle is applicable to the high spatial-frequency components of electromagnetic fields for the complementary screens. (C) 2017 Optical Society of America

DOI： 10.1364/OE.25.005279

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

We investigated the grating effect in complex gold dolmen structures, in which multiple plasmon modes are present due to plasmon hybridization, experimentally from both the far field and the near field. In particular, the near-field properties were investigated using photoemission electron microscopy, and it was demonstrated that two hybridized plasmon modes on the dolmen structures could be influenced by the grating effect. For comparison, we also investigated the grating effect in arrays of simple nanoblocks and heptamer structures, which were supposed to support a strong bright plasmon mode and a strong dark plasmon mode, respectively, in the near field. We found that the spectral responses of the two hybridized modes on the dolmen structures as the pitch size changed evolved in a manner similar to that of the bright dipole mode on the nanoblocks, whereas the dark mode on the heptamer structures is less sensitive to the pitch size. (C) 2017 Optical Society of America

DOI： 10.1364/OE.25.006883

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：NATURE PUBLISHING GROUP  

Metallic nanostructure-based surface plasmon sensors are capable of real-time, label-free, and multiplexed detections for chemical and biomedical applications. Recently, the studies of aluminum-based biosensors have attracted a large attention because aluminum is a more cost-effective metal and relatively stable. However, the intrinsic properties of aluminum, having a large imaginary part of the dielectric function and a longer evanescent length, limit its sensing capability. Here we show that capped aluminum nanoslits fabricated on plastic films using hot embossing lithography can provide tailorable Fano resonances. Changing height of nanostructures and deposited metal film thickness modulated the transmission spectrum, which varied from Wood's anomaly-dominant resonance, asymmetric Fano profile to surface plasmon-dominant resonance. For biolayer detections, the maximum surface sensitivity occurred at the dip of asymmetric Fano profile. The optimal Fano factor was close to -1.3. The wavelength and intensity sensitivities for surface thickness were up to 2.58 nm/nm and 90%/nm, respectively. The limit of detection (LOD) of thickness reached 0.018 nm. We attributed the enhanced surface sensitivity for capped aluminum nanoslits to a reduced evanescent length and sharp slope of the asymmetric Fano profile. The protein-protein interaction experiments verified the high sensitivity of capped nanostructures. The LOD was down to 236 fg/mL.

DOI： 10.1038/srep44104

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ROYAL SOC CHEMISTRY  

Plasmonics is a highly promising approach to enhancing the light-harvesting properties of hybrid organic/ inorganic perovskite solar cells. In the present work, our cells have a p-i-n inverted planar structure. An ultrathin NiO film with two different thicknesses of 5 and 10 nm prepared by a pulsed laser deposition process on an ITO substrate with a faceted and furrowed surface enabled the formation of a continuous and compact layer of well-crystallized CH3NH3PbI3 via an anti-solvent chlorobenzene process. The coverage mechanism of the NiO film on the ITO was clearly demonstrated through the J-V and external quantum efficiency (EQE) curves. Moreover, the results demonstrated that the gold nanoislands (Au NIs) increased the power conversion efficiency to 5.1%, almost double that of the samples without Au NIs. This result is due to the excitation of surface plasmons, which is characterized by strong scattering and enhancement of the electric field in the vicinity of the Au NIs loaded at the interface between the NiO and perovskite films. Additionally, we observed an enhancement of the EQE at wavelengths shorter than the plasmon resonance peak. In the current state, we speculate that the plasmoelectric potential effect is considered to be a good explanation of the photocurrent enhancement at the off-resonance region. Our work provides good guidance for the design and fabrication of solar-energy-related devices employing NiO electrodes and plasmonic Au NIs.

DOI： 10.1039/c6nr06741g

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出版者・発行元：Royal Society of Chemistry ({RSC})  

DOI： 10.1039/C7SE00220C

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：American Chemical Society  

The studies of nanostructure-based aluminum sensors have attracted huge attention because aluminum is a more cost-effective plasmonic material. However, the intrinsic properties of the aluminum metal, having a large imaginary part of the dielectric function and a longer electromagnetic field decay length and problems of poor long-term chemical stability, limit the surface-sensing capability and applicability of nanostructures. We propose the combination of capped aluminum nanoslits and a thin-capped dielectric layer to overcome these limitations. We show that the dielectric layer can positively enhance the wavelength sensitivities of the Wood's anomaly-dominant resonance and asymmetric Fano resonance in capped aluminum nanoslits. The maximum improvement can be reached by a factor of 3.5. Besides, there is an optimal layer thickness for the surface sensitivity because of the trade-off relationship between the refractive index sensitivity and decay length. We attribute the enhanced surface sensitivity to a reduced evanescent length, which is confirmed by the finite difference time-domain calculations. The protein-protein interaction experiments verify the high-surface sensitivity of the structures, and a limit of quantification (LOQ) of 1 pg/mL antibovine serum albumin is achieved. Such low-cost, highly sensitive aluminum-based nanostructures can benefit various sensing applications.

DOI： 10.1021/acsomega.7b01349

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

CoOx is a promising hole-extracting layer (HEL) for inverted planar perovskite solar cells with device configuration ITO/CoOx/CH3NH3PbI3/PCBM/Ag. The devices fabricated according to a simple solution procedure showed the best photovoltaic performance attaining power conversion efficiency (PCE) of 14.5% under AM 1.5 G 1 sun irradiation, which is significantly superior to those of materials fabricated with a traditional HEL such as PEDOT:PSS (12.2%), NiOx (10.2%), and CuOx (9.4%) under the same experimental conditions. We characterized the chemical compositions with XPS, crystal structures with XRD, and film morphology with SEM/AFM techniques. Photoluminescence (PL) spectra and the corresponding PL decays for perovskite deposited on varied HEL films were recorded to obtain the hole-extracting characteristics, for which the hole extracting times show the order CoOx (2.8 ns) &lt; PEDOT:PSS (17.5 ns) &lt; NiOx (22.8 ns) &lt; CuOx (208.5 ns), consistent with the trend of their photovoltaic performances. The reproducibility and enduring stability of those devices were examined to show the outstanding long-term stability of the devices made of metal oxide HEL, for which the CoOx device retained PCE approximate to 12% for over 1000 h.

DOI： 10.1021/acsami.6b10803

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

The extraordinary optical properties of coupled plasmonic nanostructures make these materials potentially useful in many applications; thus, they have received enormous attention in basic and applied research. Coupled plasmon modes have been characterized predominantly using far-field spectroscopy. In near-field spectroscopy, the spectral response of local field enhancement in coupled plasmonic nanostructures remains largely unexplored, especially experimentally. Here, we investigate the coupled gold dolmen nanostructures in the near field using photoemission electron microscopy, with wavelength tunable femtosecond laser pulses as an excitation source. The spatial evolution of near-field mapping of an individual dolmen structure with the excitation wavelength was successfully obtained. In the near field, we spatially resolved an anti-bonding mode and a bonding mode as the result of plasmon hybridization. Additionally, the quadrupole plasmon mode that could be involved in the formation of a Fano resonance was also revealed by spatially resolved near-field spectra, but it only contributed little to the total near-field enhancement. On the basis of these findings, we obtained a better understanding of the near-field nanostructures, where the plasmon hybridization and the plasmonic Fano resonance were mixed.

DOI： 10.1021/acsnano.6b06206

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

Infrared light has received attention for sensor applications, including fingerprint spectroscopy, in the bioengineering and security fields. Surface plasmon physics enables the operation of a light harvesting optical antenna. Gold nanochains exhibit localized surface plasmon resonance (LSPR) in the infrared region with high frequency selectivity. However, a feasible design for optical antennae with a higher resonant efficiency and frequency selectivity as a function of structural design and periodicity is still unknown. In the present study, we investigated the relationship between the resonant efficiency and frequency selectivity as a function of the structural design of gold nanochains and explored structural periodicity for obtaining highly frequency-selective optical antennae. An optical antenna design with higher resonant efficiency is proposed on the basis of its efficient interaction with non-polarized light. (C) 2016 Optical Society of America

DOI： 10.1364/OE.24.017728

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

We report on the spectral properties of strong coupling between the localized surface plasmon resonances (LSPRs) of aluminum (Al) nanostructures and tetraphenylporphyrin tetrasulfonic acid hydrate (TPPS) J-aggregates. Because of their wide spectral range of LSPR bands from ultraviolet to near-infrared wavelengths by controlling structural size, Al nanodisks can realize strong coupling with different excitons of TPPS J-aggregates. The Rabi splitting energies of the excitons based on Soret and Qbands are 300 and 180 meV, respectively. In addition to extinction spectrum, we have also measured an excitation spectrum to determine the essential absorption of the hybrid states and successfully confirmed a shoulder peak corresponding to a lower branch of hybrid states. In Al nanorod systems, strong coupling with two excitons can also be selectively induced by merely rotating the polarization of the incident light, which constituted a simple platform for the dynamic control of exciton/plasmon coupling states.

DOI： 10.1021/acs.jpclett.6b01224

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：MDPI AG  

We designed and fabricated gold curvilinear nanorod periodical arrays using microfabrication techniques. The gold curvilinear nanorods had two distinct resonant peaks in the near-infrared region between 1630 nm and 3000 nm. Similar peak was observed in gold straight nanorods at specific lengths. At lengths identical to the arc length of the curvilinear nanorod, the peak was in the relative range of 3000 nm, which corresponds to the longitudinal plasmon mode (L-mode). At lengths identical to half of the arc length of the curvilinear nanorod, the peak was close to 1630 nm. Plasmon resonant peaks were tunable in the infrared region by changing the arc length of the curve, the line width, and distance between the curvilinear nanorods. In particular, when two curvilinear nanorods were closely packed in a range of less than 100 nm, the peak wavelength of curvilinear nanorod was shifted due to the plasmonic coupling of each mode.

DOI： 10.3390/photonics3020018

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その他リンク： http://orcid.org/0000-0003-1070-387X

記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-V C H VERLAG GMBH  

The generation of ammonia from atmospheric nitrogen and water using sunlight is a preferable approach to obtaining ammonia as an energy carrier and potentially represents a new paradigm for achieving a low-carbon and sustainable-energy society. Herein, we report the selective conversion of dinitrogen into ammonia through plasmon-induced charge separation by using a strontium titanate (SrTiO3) photoelectrode loaded with gold nanoparticles (Au-NPs) and a zirconium/zirconium oxide (Zr/ZrOx) thin film. We observed the simultaneous stoichiometric production of ammonia and oxygen from nitrogen and water under visible-light irradiation.

DOI： 10.1002/anie.201511189

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）  

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

We have successfully fabricated all-solid-state plasmonic photoelectric conversion devices composed of titanium dioxide (TiO2)/nickel oxide (NiO) p-n junctions with gold nanoparticles (Au-NPs) as prototype devices for a plasmonic solar cell. The characteristics of the crystal structures and the photoelectric properties of the all-solid-state devices were demonstrated. We observed that the crystalline structure of the NiO thin film and the interfacial structure of TiO2/Au-NPs/NiO changed significantly during an annealing treatment. Furthermore, the photoelectric conversion devices exhibited plasmon-induced photocurrent generation in the visible-wavelength region. The photo current may result from plasmon-induced charge separation. The photoelectric conversion properties via plasmon-induced charge separation were strongly correlated with the morphology of the TiO2/Au-NPs/NiO interface. The long-term stability of the plasmonic photoelectric conversion device was found to be very high because a stable photocurrent was observed even after irradiation for 3 days.

DOI： 10.1021/acs.jpclett.6b00291

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

Dipole and quadrupole modes are the two lowest orders of localized surface plasmon resonance (LSPR) eigenmodes in metallic nanoparticles. Of these two modes, the quadrupole mode is forbidden for symmetric metallic nanoparticles excited by linearly polarized light at normal incidence. Here, we demonstrate excitation of the quadrupole mode in symmetrical gold (Au) nanoblocks shined with s -polarized light at oblique incidence. In particular, we probe the near -field LSPR in Au nanoblocks using photoemission electron microscopy (PEEM) and find that at oblique incidence, the dipole and quadrupole modes can be selectively excited, in terms of near -field enhancement, by manipulating the light polarization state. More importantly, by time -resolved PEEM measurements, we experimentally demonstrate that the quadrupole mode in symmetrical Au nanoblocks has longer dephasing time than that of the dipole mode.

DOI： 10.1021/acsnano.6b00715

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記述言語：英語   出版者・発行元：WILEY-V C H VERLAG GMBH  

Visible- and near-infrared-light-driven water splitting, which splits water molecules to generate hydrogen and oxygen gases, is a significant subject in artificial photosynthesis with the goal of achieving a low-carbon society. In recent years, considerable attention has been paid to studies on the development of a plasmon-induced water-splitting system responding to visible light. In this review, we categorized water-splitting systems as gold-nanoparticle-loaded semiconductor photocatalytic particles system and metallic-nanoparticles-loaded semiconductor photoelectrode systems, and introduce the latest studies according to these categories. Especially, we describe the studies that optimize a material or a structural design of metallic-nanoparticle-loaded semiconductor photoelectrodes and consider a whole water-splitting system, including a cathode design. Furthermore, we discuss important points when studying plasmon-induced water splitting, and we describe a methodology that enhances plasmon-induced water-splitting efficiency.

DOI： 10.1002/cphc.201500761

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）  

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）  

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記述言語：英語   出版者・発行元：OSA - The Optical Society  

Terahertz (THz) spectroscopy is a promising method to measure the spectrum of low-frequency modes of molecules or ensembles, such as crystals and polymers, including proteins. However, the main drawback of THz spectroscopy is its extremely low sensitivity. In the present study, we report on signal enhancement in THz spectroscopy achieved by depositing amino acid molecules or their derivatives on a gold rod structured silicon substrate whose localized surface plasmon resonance is exhibited in the THz frequency region. The distinct peaks derived from the enhancement of the inherent spectrum based on a molecular crystal were clearly observed when a longitudinal plasmon resonance mode of the gold rod structure was excited and the plasmon resonance band overlapped the molecular/intermolecular vibrational mode. We discuss the mechanism by which surface-enhanced THz spectroscopy was induced from the viewpoint of the enhancement of light-matter coupling due to plasmon excitation and the modulation of the plasmon band by dipole coupling between the plasmon dipole and molecular/intermolecular vibrational modes.

DOI： 10.1364/OE.23.028584

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その他リンク： http://orcid.org/0000-0002-4882-7854

記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ROYAL SOC  

We have successfully developed a plasmon-induced artificial photosynthesis system that uses a gold nanoparticle-loaded oxide semiconductor electrode to produce useful chemical energy as hydrogen and ammonia. The most important feature of this system is that both sides of a strontium titanate single-crystal substrate are used without an electrochemical apparatus. Plasmon-induced water splitting occurred even with a minimum chemical bias of 0.23 V owing to the plasmonic effects based on the efficient oxidation of water and the use of platinum as a co-catalyst for reduction. Photocurrent measurements were performed to determine the electron transfer between the gold nanoparticles and the oxide semiconductor. The efficiency of water oxidation was determined through spectroelectrochemical experiments aimed at elucidating the electron density in the gold nanoparticles. A set-up similar to the water-splitting system was used to synthesize ammonia via nitrogen fixation using ruthenium instead of platinum as a co-catalyst.

DOI： 10.1098/rsfs.2014.0082

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WALTER DE GRUYTER GMBH  

We have successfully demonstrated plasmon-enhanced photocurrent generation using gold nan-oparticle- loaded titanium dioxide single-crystal (TiO2) photoelectrodes with visible-light irradiation. Water molecules serve as an electron source in photocurrent generation, and oxygen evolution occurs due to water oxidation from a gold nanostructured TiO2 photoelectrode as a half reaction of water splitting. On the basis of this property, the photocurrent generation system was applied to the plasmon-induced water-splitting system using both sides of the same strontium titanate (SrTiO3) single-crystal substrate without an electrochemical apparatus. The chamber on the side of the gold nanoparticles was the anode side, whereas the chamber on the side of the platinum plate was the cathode side. Platinum was used as a co-catalyst for hydrogen evolution. Hydrogen and oxygen were separately evolved from the anode and cathode chambers, respectively. Water splitting was induced with a relatively low chemical bias of 0.23 V due to plasmonic effects based on efficient water oxidation. Similar to the artificial photosynthesis system, we have also demonstrated ammonia formation via nitrogen fixation using ruthenium as a co-catalyst via an analogous setup of the water-splitting system.

DOI： 10.1515/pac-2014-1120

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：CHEMICAL SOC JAPAN  

A plasmon-enhanced water splitting system using a gold nanostructured strontium titanate (SrTiO3) single-crystal photoelectrode with a titanium dioxide (TiO2) thin film heterojunction was developed. Simultaneous evolution of hydrogen and oxygen was observed in separate reaction chambers under visible light irradiation. The substrate composed of single-crystal SrTiO3 with a rutile TiO2 thin film heterojunction exhibited enhanced water splitting activity compared with the electrode without the TiO2 thin film because the synergistic effect may prevent the back-electron-transfer reaction.

DOI： 10.1246/cl.150028

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

We explored the performance of hydrogen (H-2) evolution using noble metals or their metal oxides as cocatalysts in the plasmon-induced water-splitting system. Although many studies have employed n-type semiconductor particle systems to investigate cocatalyst effects, evaluating only the catalytic activity of H-2 and oxygen (O-2) evolution has been limited by (1) the difficulty of transferring an electron injected into the conduction band of a semiconductor to a cocatalyst due to the formation of a Schottky barrier when a metallic cocatalyst for H2 evolution contacts the n-type semiconductor and (2) the potential for a reverse water-splitting reaction, which occurs due to the promotion of the reduction of the evolved O-2 by the cocatalyst. To overcome these limitations, in the present study, we eliminated the adverse effect of the Schottky barrier by obtaining ohmic contact between the semiconductor and the metal or metal oxide cocatalysts, and we used two separate reaction chambers for H-2 and O-2 evolution to avoid reverse water-splitting reactions such as H2O2 recombination or the photoreduction of O-2. A 23 nm thick rhodium layer deposited on a platinum board exhibited relatively high performance, a 3-fold increase compared with the absence of a metal or metal oxide cocatalyst thin layer.

DOI： 10.1021/acs.jpcc.5b01720

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-V C H VERLAG GMBH  

A plasmon-induced water splitting system that operates under irradiation by visible light was successfully developed; the system is based on the use of both sides of the same strontium titanate (SrTiO3) single-crystal substrate. The water splitting system contains two solution chambers to separate hydrogen (H-2) and oxygen (O-2). To promote water splitting, a chemical bias was applied by regulating the pH values of the chambers. The quantity of H-2 evolved from the surface of platinum, which was used as a reduction co-catalyst, was twice the quantity of O-2 evolved from an Au-nanostructured surface. Thus, the stoichiometric evolution of H-2 and O-2 was clearly demonstrated. The hydrogen-evolution action spectrum closely corresponds to the plasmon resonance spectrum, indicating that the plasmon-induced charge separation at the Au/SrTiO3 interface promotes water oxidation and the subsequent reduction of a proton on the backside of the SrTiO3 substrate. The chemical bias is significantly reduced by plasmonic effects, which indicates the possibility of constructing an artificial photosynthesis system with low energy consumption.

DOI： 10.1002/anie.201404926

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）   出版者・発行元：Forschungszentrum Jülich GmbH  

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-V C H VERLAG GMBH  

We have successfully developed a plasmon-induced technique for ammonia synthesis that responds to visible light through a strontium titanate (SrTiO3) photoelectrode loaded with gold (Au) nanoparticles. The photoelectrochemical reaction cell was divided into two chambers to separate the oxidized (anodic side) and reduced (cathodic side) products. To promote NH3 formation, a chemical bias was applied by regulating the pHvalue of these compartments, and ethanol was added to the anodic chamber as a sacrificial donor. The quantity of NH3 formed at the ruthenium surface, which was used as a co-catalyst for SrTiO3, increases linearly as a function of time under irradiation with visible light at wavelengths longer than 550nm. The NH3 formation action spectrum approximately corresponds to the plasmon resonance spectrum. We deduced that plasmon-induced charge separation at the Au/SrTiO3 interface promotes oxidation at the anodic chamber and subsequent nitrogen reduction on the cathodic side.

DOI： 10.1002/anie.201404748

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

We report polarized femtosecond laser-light-mediated growth and programmable assembly of photoreduced silver nanoparticles into triply hierarchical micropatterns. Formation of erected arrays of nanoplates with a thickness as small as lambda/27 (lambda, the writing laser wavelength) level is demonstrated. The growth mechanism of nanoplates has been clarified: (i) the excited surface plasmons enhance the local electric field and lead to spatially selective growth of silver atoms at the opposite ends of dipoles induced on early created silver seeds; (ii) the optical attractive force overcomes electrostatic repulsion in the enhanced local electric field to assemble the silver nanoparticles directly. The triply hierarchical micropattern shape and location, the nanoplate orientation, and thickness are all attained in controlled fashion.

DOI： 10.1021/nn5029345

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

We investigate the far-field and near-field properties of aluminum nanorods fabricated by electron beam lithography and exhibiting plasmonic resonance in the near-infrared region. First, we show that plasmonic modes within nanorod arrays can be tuned by geometrical parameters, allowing one to control the system transparency. Next, the light absorption in this structure is closely examined, and we demonstrate that aluminum has great potential due to its unique interband transition at 800 nm. The roles of the dielectric confinement and the coupling between plasmonic resonance and the interband transition are particularly emphasized, as their adjustment can be used to switch from highly scattering particles to absorbing particles without a significant modification of the plasmonic resonance position. Finally, we image the plasmon-generated local field distribution in the aluminum nanostructures and observe, for the first time, the effect of the interband transition on the near-field behavior. The effect of the dielectric confinement is also numerically investigated, as it is shown to play a significant role in near-field enhancement.

DOI： 10.1021/ph500096q

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

Optical properties of single gold nanodiscs were studied by scanning near-field optical microscopy. Near-field transmission spectra of a single nanodisc exhibited multiple plasmon resonances in the visible to near-infrared region. Near-field transmission images observed at these resonance wavelengths show wavy spatial features depending on the wavelength of observation. To clarify physical pictures of the images, theoretical simulations based on spatial correlation between electromagnetic fundamental modes inside and outside of the disc were performed. Simulated images reproduced the observed spatial structures excited in the disc. Mode-analysis of the simulated images indicates that the spatial features observed in the transmission images originate mainly from a few fundamental plasmon modes of the disc. (C) 2014 Optical Society of America

DOI： 10.1364/OE.22.012189

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）  

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

The use of localized surface plasmon resonance induced by Ag nanostructures is a promising way for high-efficiency photoelectric conversion. In plasmonic photoelectric conversion devices, however, the chemical instability of Ag in ambient atmosphere and its immediate deterioration have been a critical issue. Here, we propose a Ag-Co nanostructure array embedded in a TiO2 matrix as a plasmonic resonator that ensures long-term stability. We also developed an electrochemical process to remove surface Co nanoclusters protecting fresh Ag from exposure to air. This enabled us to "unseal" Ag at the desired time. Furthermore, we confirmed photoelectric conversion using Ag-Co-TiO2 nanocomposite films in contact with solution; the photoelectric conversion was substantially enhanced by the plasmon resonance of the Ag nanorods. The Ag nanostructures sealed in a TiO2 matrix are expected to be used in other application fields, such as catalytisis and sensing, in which a fresh Ag surface is needed.

DOI： 10.1021/jz402320p

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：TAYLOR & FRANCIS LTD  

The periodic arrays of gold nanocylinder with 121 nm in diameter, 6.3 nm in gap, and 34 nm in thickness are fabricated on glass by electron-beam lithography and lift-off techniques. Some crystal violet molecules are coated on the array by using the dipping and drawing method. In addition, the surface-enhanced Raman scattering (SERS) spectra of these samples with and without gold nanocylinder arrays are characterized specifically. The largest enhancement factor is obtained when the excitation wavelength corresponds to the peak wavelength of localized surface plasmon resonance (LSPR). The density functional theory and the finite-difference time-domain method are used for the calculations of the extinction spectrum of the arrays and Raman spectra of the crystal violet, respectively. These results unambiguously demonstrate that the periodic arrays of gold nanocylinder have good and effective surface-enhanced properties for Raman scattering of crystal violets, and they also show that the excitation wavelength corresponding to the peak one of the LSPR is one of the major reasons causing SERS.

DOI： 10.1080/09500340.2014.928378

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：CHINESE ACAD SCIENCES, CHANGCHUN INST OPTICS FINE MECHANICS AND PHYSICS  

Localized surface plasmon resonance (LSPR) can be supported by metallic nanoparticles and engineered nanostructures. An understanding of the spatially resolved near-field properties and dynamics of LSPR is important, but remains experimentally challenging. We report experimental studies toward this aim using photoemission electron microscopy (PEEM) with high spatial resolution of sub-10 nm. Various engineered gold nanostructure arrays (such as rods, nanodisk-like particles and dimers) are investigated via PEEM using near-infrared (NIR) femtosecond laser pulses as the excitation source. When the LSPR wavelengths overlap the spectrum of the femtosecond pulses, the LSPR is efficiently excited and promotes multiphoton photoemission, which is correlated with the local intensity of the metallic nanoparticles in the near field. Thus, the local field distribution of the LSPR on different Au nanostructures can be directly explored and discussed using the PEEM images. In addition, the dynamics of the LSPR is studied by combining interferometric time-resolved pump-probe technique and PEEM. Detailed information on the oscillation and dephasing of the LSPR field can be obtained. The results identify PEEM as a powerful tool for accessing the near-field mapping and dynamic properties of plasmonic nanostructures.

DOI： 10.1038/lsa.2013.74

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：CHINESE ACAD SCIENCES, CHANGCHUN INST OPTICS FINE MECHANICS AND PHYSICS  

Localized surface plasmon resonance (LSPR) can be supported by metallic nanoparticles and engineered nanostructures. An understanding of the spatially resolved near-field properties and dynamics of LSPR is important, but remains experimentally challenging. We report experimental studies toward this aim using photoemission electron microscopy (PEEM) with high spatial resolution of sub-10 nm. Various engineered gold nanostructure arrays (such as rods, nanodisk-like particles and dimers) are investigated via PEEM using near-infrared (NIR) femtosecond laser pulses as the excitation source. When the LSPR wavelengths overlap the spectrum of the femtosecond pulses, the LSPR is efficiently excited and promotes multiphoton photoemission, which is correlated with the local intensity of the metallic nanoparticles in the near field. Thus, the local field distribution of the LSPR on different Au nanostructures can be directly explored and discussed using the PEEM images. In addition, the dynamics of the LSPR is studied by combining interferometric time-resolved pump-probe technique and PEEM. Detailed information on the oscillation and dephasing of the LSPR field can be obtained. The results identify PEEM as a powerful tool for accessing the near-field mapping and dynamic properties of plasmonic nanostructures.

DOI： 10.1038/lsa.2013.74

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：CHINESE ACAD SCIENCES, CHANGCHUN INST OPTICS FINE MECHANICS AND PHYSICS  

Localized surface plasmon resonance (LSPR) can be supported by metallic nanoparticles and engineered nanostructures. An understanding of the spatially resolved near-field properties and dynamics of LSPR is important, but remains experimentally challenging. We report experimental studies toward this aim using photoemission electron microscopy (PEEM) with high spatial resolution of sub-10 nm. Various engineered gold nanostructure arrays (such as rods, nanodisk-like particles and dimers) are investigated via PEEM using near-infrared (NIR) femtosecond laser pulses as the excitation source. When the LSPR wavelengths overlap the spectrum of the femtosecond pulses, the LSPR is efficiently excited and promotes multiphoton photoemission, which is correlated with the local intensity of the metallic nanoparticles in the near field. Thus, the local field distribution of the LSPR on different Au nanostructures can be directly explored and discussed using the PEEM images. In addition, the dynamics of the LSPR is studied by combining interferometric time-resolved pump-probe technique and PEEM. Detailed information on the oscillation and dephasing of the LSPR field can be obtained. The results identify PEEM as a powerful tool for accessing the near-field mapping and dynamic properties of plasmonic nanostructures.

DOI： 10.1038/lsa.2013.74

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

In this study, we demonstrated an improvement in the plasmon-enhanced photocurrent generation due to Fabry-Perot interference of titanium dioxide (TiO2) thin-film electrodes loaded with Au nanoislands (Au-NIs). TiO2 thin films with thicknesses of 215-274 nm, which show obvious Fabry-Perot interference, were deposited via atomic layer deposition (ALD) onto silica glass and were modified by the deposition of Au-NIs onto their surface. Anodic plasmon-enhanced photocurrent generation was observed over the Au-NIs-loaded TiO2 thin-film photoelectrodes. The incident photon to current efficiency (IPCE) action spectra correlated strongly with the Au-NIs plasmon resonance and exhibited a strong dependence on the thickness of the TiO2 thin film. The photocurrent conversion efficiency increased when the transmission constructive interference wavelength overlapped with the Au-NIs plasmon resonance band. This work provides a simple and applicable approach for the further design of low-cost and lightweight plasmon-enhanced energy conversion devices.

DOI： 10.1021/jp408472g

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：NATURE PUBLISHING GROUP  

This paper presents recent investigations of plasmon-enhanced photoelectric conversion and water oxidation by visible and near-infrared light irradiation. Since the discovery of the Honda-Fujishima effect in 1972, significant efforts have been devoted to lengthening the light-energy conversion wavelength. In this context, plasmonic photoelectric conversion has been recently demonstrated at visible-to-near-infrared wavelengths without deteriorating photoelectric conversion by employing titanium dioxide (TiO2) single-crystal photoelectrodes, in which gold nanorods are elaborately arrayed on the surface. A potassium perchlorate aqueous solution was employed as an electrolyte solution without additional electron donors; thus, water molecules provided the electrons. The stoichiometric evolution of oxygen and hydrogen peroxide as a result of the four-or two-electron oxidation of water molecules, respectively, was accomplished with near-infrared light irradiation using the plasmonic optical antenna effect. As there is very little overpotential for water oxidation, these results constitute a significant advancement in this field. In addition, this photoelectric conversion system could potentially be employed in artificial photosynthesis systems that exceed the photosynthetic capabilities of plants by allowing for photoconversion over a wide range of wavelengths.

DOI： 10.1038/am.2013.42

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

The electromagnetic field enhancement effect based on the excitation of localized surface plasmon resonance was developed for various photochemical reaction systems, such as nano-lithography, photovoltaic cells, photocatalysis, and water splitting systems. As with most points characteristic of these surface plasmon-enhanced photochemical reactions, spatially selective photochemical reactions can be induced and photons can be efficiently utilized, a concept that could contribute to the development of green nanotechnology. Electromagnetic field enhancement effects based on plasmon excitation have contributed not only to physical processes, such as excitation efficiency, but also to chemical processes, such as photo-induced electron transfer reactions. This review article describes advanced studies on a wide variety of surface plasmon-enhanced photochemical reactions. © 2013 Elsevier B.V.

DOI： 10.1016/j.jphotochemrev.2013.04.001

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

Gold-bowtie nanostructures are fabricated by electron beam lithography and lift-off techniques. Their optical properties are investigated by both experimental studies and numerical simulations. The influence of sharpness and gap of nano-bowtie on optical properties such as extinction cross section, local electric field intensity, and surface resonance wavelength is explored. The experimental extinction spectra agree well with the simulation results. This investigation may help us to design plasmonic sub-wavelength gold-bowtie nanostructure with desired spectral properties. © 2013 Elsevier B.V.

DOI： 10.1016/j.optcom.2012.12.080

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

Plasmonic chemistry, a new research field dedicated to understanding plasmon-enhanced photochemical reactions, has become a principal area of chemical research, especially in the field of physical chemistry. In this perspective review article, we describe our recent research regarding the development of a fabrication methodology for metallic nanostructures that exhibit localized surface plasmon resonance, the spectral properties of the fabricated metallic nanostructures and their electromagnetic field enhancement effects using two-photon-induced photoluminescence from gold nanoparticles. © 2013 the Owner Societies.

DOI： 10.1039/c2cp43681g

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

Metallic nanoparticles showing localized surface plasmon resonance (LSPR) are efficient elements in the localization of light to nanometer-scale regions and enhance the light-matter interaction. We show that gold nanoisland (Au-NI)-loaded titanium dioxide (TiO2) photoelectrodes exhibited plasmon-enhanced photocurrent generation in the visible wavelength region, and the photocurrent action spectrum was corresponding to the LSPR band. The photocurrent enhancement may result from the plasmon-assisted electron transfer reaction from Au-NI to TiO2. A hole with high oxidation ability was left at the TiO2 surface states near the Au-NIs/TiO2 interface, which has the potential for photocatalytic water oxidation. The photocurrent generation efficiency of Au-NIs/TiO2 photoelectrode is highly dependent on the annealing temperature for the preparation of Au-NIs. High-resolution transmission electron microscopy and electron energy-loss spectroscopy analyses show that the interfacial structure between Au-NI and TiO2 plays a crucial role in the photocurrent generation efficiency and photocatalytic ability. © 2012 American Chemical Society.

DOI： 10.1021/jp3064036

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

DOI： 10.1021/jp400201p

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

We studied optical properties of single elongated rectangular nanovoids opened on a thin gold film by scanning near-field optical microscopy. We found that the luminescence is induced via two-photon absorption of near-infrared pulses when the sample is locally photoexcited inside the void as well as on the film. The luminescence spectrum of the void shows spectral features very similar to those observed for gold nanorods and is attributable to that from gold. On the basis of the near-field two-photon excitation imaging by detecting the luminescence, we visualized the optical fields near the voids. The optical image shows a characteristic spatial feature depending on the dimension of the void. From the dose inspection of the topography and the optical images, we found that excitation probability becomes high at the metal void boundary as well as inside the void. We found an oscillating feature along the long axis of the void. The observed spatial features were qualitatively reproduced by photonic local density-of-states based on electromagnetic calculations, and we conduded that the oscillation observed inside the void is attributed to the electromagnetic modes in the void coupled with the plasmon excitations.

DOI： 10.1021/jp305343g

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

The in situ observation of geometrical and electronic structural dynamics of a single molecule junction is critically important in order to further progress in molecular electronics. Observations of single molecular junctions are difficult, however, because of sensitivity limits. Here, we report surface-enhanced Raman scattering (SERS) of a single 4,4′-bipyridine molecule under conditions of in situ current flow in a nanogap, by using nano-fabricated, mechanically controllable break junction (MCBJ) electrodes. When adsorbed at room temperature on metal nanoelectrodes in solution to form a single molecule junction, statistical analysis showed that nontotally symmetric b1 and b2 modes of 4,4′-bipyridine were strongly enhanced relative to observations of the same modes in solid or aqueous solutions. Significant changes in SERS intensity, energy (wavenumber), and selectivity of Raman vibrational bands that are coincident with current fluctuations provide information on distinct states of electronic and geometrical structure of the single molecule junction, even under large thermal fluctuations occurring at room temperature. We observed the dynamics of 4,4′-bipyridine motion between vertical and tilting configurations in the Au nanogap via b1 and b2 mode switching. A slight increase in the tilting angle of the molecule was also observed by noting the increase in the energies of Raman modes and the decrease in conductance of the molecular junction. © 2012 American Chemical Society.

DOI： 10.1021/ja307821u

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）   出版者・発行元：SPIE-INT SOC OPTICAL ENGINEERING  

Nanoparticles of noble metals show localized surface plasmon resonance. Plasmon resonances which are collective oscillations of conduction electrons give rise to the enhancement of electromagnetic field to the local surface of metallic nanoparticles. Therefore, various plasmonic near-field lithography systems were proposed so far. Here, we report on a plasmon-assisted nanolithography used for the fabrication of nano-patterns with nanometric accuracy. The lithography system can form deep nano-patterns on positive photoresist film using scattering component of multipole plasmon resonances as an exposure light. Two-photon-induced reaction of a photoresist enabled the formation of fine patterns even using plasmonic scattering light.

DOI： 10.1117/12.2003316

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-V C H VERLAG GMBH  

The authors report on surface plasmon-enhanced fluorescence of Eosin Y molecules induced by gold nanostructures. Al2O3 films deposited by atomic layer deposition with sub-nanometer resolution were used as the spacer layer to control the distance between molecules and the gold surface. As the thickness of the Al2O3 film increased, the fluorescence intensity first increased and then decreased. The highest enhancement factor is achieved with a 1 nm Al2O3 film. However, the trend for the fluorescence lifetime is the opposite. It first decreased and then increased. The changes in the fluorescence quantum yield were also calculated. The yield shows a similar trend to the fluorescence intensity. The competition between the surface plasmon-induced increase in the radiative decay rate and the gold-induced fluorescence quenching is responsible for the observed phenomenon. In addition, this competition strongly depends on the thickness of the spacer layer between Eosin Y molecules and the gold surface.

DOI： 10.1002/andp.201200143

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：CHINESE LASER PRESS  

We experimentally verify that surface plasmon (SP) enhances the photoluminescence (PL) of visible light from Tb3+-doped 60SiO(2)-20Al(2)O(3)-20CaF(2):0.3Tb(3+), 20Yb(3+) glass ceramics by using electron beam lithography to fabricate silver nanoparticles on the surface of the glass ceramics. Numerical calculation for the SP enhancement spectroscopy is achieved by using the finite-difference time-domain algorithm. A PL enhancement of Tb3+ by as much as 1.6 times is observed. The PL enhancement is mainly due to the coupling of excitation from F-7(6) to D-5(4) transition dipole of Tb3+ ion with SP mode induced from the silver nanoparticles.

DOI： 10.3788/COL201210.092401

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-V C H VERLAG GMBH  

DOI： 10.1002/adma.201202194

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

We examined the vibrational dynamics of periodic gold pair nanocuboids with various nanogaps and various pair-to-pair separations under 400 nm excitation by near-IR transient absorption spectroscopy. Multi-oscillation behavior of the coherent acoustic phonon vibration was observed for all the gold pair nanocuboid arrays. Two symmetric breathing modes were assigned to the displacement of edge-to-edge and its second harmonic, and the displacement of tip-to-tip of gold nanocuboids. We assigned the driving mechanisms of the edge-to-edge and the tip-to-tip modes to thermal expansion and hot-electron pressure, respectively, due to the different amplitudes and the phase mismatch between both modes. Moreover, Young's modulus of gold nanocuboids was estimated to be 97 GPa by using the measured vibrational periods of the edge mode. A little deviation from the bulk value (78 GPa) was interpreted in terms of an interaction of a gold nanocuboid with a substrate. In addition, the oscillation periods and damping constants of the phonon vibration were similar for all of the arrays, even though localized surface plasmon resonance (LSPR) bands were shifted due to near- and far-field dipole couplings. This phenomenon suggested that the phonon vibration was only influenced by the intrinsic properties of the nanomaterials. Furthermore, the oscillation amplitudes of the bleaching peaks exponentially decayed with the increase of the nanogap. We calculated the LSPR bands of gold pair nanocuboids with structural deformation by finite-difference time-domain simulation, and the estimated spectral shift was in good agreement with the experimental results.

DOI： 10.1021/jp305813w

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：CHEMICAL SOC JAPAN  

We used metallic nanoparticles exhibiting localized surface plasmon resonance and electromagnetic (EM) field enhancement effects induced by plasmon excitation for the photochemical reaction field; this approach makes it possible to increase the probability of an interaction between photons and the materials. EM field enhancement effects induced by gold nanostructures were elucidated using two-photon-induced photoluminescence from nanogap-spaced gold nanoparticles. The photoluminescence was promoted mainly in the surface regions of the gold nanoblocks adjacent to the nanogaps due to the EM field enhancement effect. To elucidate the near-field intensity distribution of the nanogap gold structures, we investigated the photopolymerization of a commercially available negative photoresist assisted by EM field enhancement in the nanogaps separating the gold nanoblocks. Photopolymerization rates were enhanced by several orders of magnitude in the gold nanoblock structures that contained nanogaps narrower than 10 nm. We propose two surface plasmon-assisted nanolithography techniques based on spatially selective photochemical reactions promoted by the EM field enhancement effect. The first method uses ultimate near-field lithography with a local near-field distribution induced in the nanogaps, and the second technique uses the scattering component of multipole plasmon resonance as an exposure mechanism. These lithographic techniques represent a type of application based on plasmon-enhanced chemical reactions.

DOI： 10.1246/bcsj.20120123

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：SPRINGER  

In this paper, we study the nanoscale-focusing effect in the far field for a spiral plasmonic lens with a concentric annular groove by using finite-difference time domain simulation. The simulation result demonstrates that a left-hand spiral plasmonic lens can concentrate an incident right-hand circular polarization light into a focal spot at the exit surface. And this spot can be focused into far field due to constructive interference of the scattered light by the annular groove. The focal length and the focal depth can be adjusted by changing the groove radius and number of grooves within a certain range. These properties make it possible to probe the signal of spiral plasmonic lens in far field by using conventional optical devices.

DOI： 10.1007/s11468-011-9318-0

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

The quantitative determination of the strength of the near-field enhancement in and around nanostructures is essential for optimizing and using these structures for applications. We combine the Gaussian intensity distribution of a laser profile and two-photon-polymerization of SU-8 to a suitable tool for the quantitative experimental measurement of the near-field enhancement of a nanostructure. Our results give a feedback to the results obtained by finite-difference rime-domain (FDTD) simulations. The structures under investigation are gold nanotriangles on a glass substrate with 85 nm side length and a thickness of 40 nm. We compare the threshold fluence for polymerization for areas of the Gaussian intensity profile with and without the near-field enhancement of the nanostructures. The experimentally obtained value of the near-field intensity enhancement is 600 140, independent of the laser power, irradiation time, and spot size. The FDTD simulation shows a pointlike maximum of 2600 at the tip. In a more extended area with an approximate size close to the smallest polymerized structure of 25 nm in diameter, we find a value between 800 and 600. Using our novel approach, we determine the threshold fluence for polymerization of the commercially available photopolymerizable resin SU-8 by a femtosecond laser working at a wavelength of 795 nm and a repetition rate of 82 MHz to be 0.25 J/cm(2) almost independent of the irradiation time and the laser power used. This finding is important for future applications of the method because it enables one to use varying laser systems.

DOI： 10.1021/la300219w

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

We performed a quantitative analysis of plasmon-assisted two-photon photochromic reactions on light-harvesting gold nanodimer structures. Our strategy for the quantitative analysis of two-photon-induced photochemical reactions on gold nanostructures is using not only a confined photochemical reaction chamber but also a solution system. The strong intensification of near-field light at the nanogap positions on gold nanodimer pairs promoted two-photon absorption by a closed-form diarylethene derivative, resulting in highly efficient photochromic conversion to the open-form structure.

DOI： 10.1021/jz300370b

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

We report the stoichiometric evolution of oxygen via water oxidation by irradiating a plasmon-enhanced photocurrent generation system with near-infrared light (lambda: 1000 am), in which gold nanostructures were arrayed on the surface of TiO2 electrode. It is considered that multiple electron holes generated by plasmon-induced charge excitation led to the effective recovery of water oxidation after the electron transfer from gold to TiO2. The proposed system containing a gold nanostructured TiO2 electrode may be a promising artificial photosynthetic system using near-infrared light.

DOI： 10.1021/jz3003316

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE BV  

This paper presents optical property of the periodical bowties structure of Au nanoparticles on glass substrate fabricated by high-resolution electron beam lithography. Numerical calculation is used to examine the shape-induced surface plasmon enhancement and extinction spectroscopy by using Finite-Difference Time Domain algorithm and Lorentz model of surface plasmon. The calculated extinction spectra of the periodical nanoparticles are consistent with the experimental results. The influence of the geometrical shape on the spectral properties of bowtie nanoparticles is discussed. This investigation may help one to design plasmonic sub-wavelength devices with desired spectral properties. (C) 2012 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.optcom.2012.01.032

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：SPRINGER  

The effect of femtosecond laser irradiation on adherent mesenchymal stem cell was investigated with the aim to develop a novel noninvasive cell purification system. A single mesenchymal stem cell was irradiated with a femtosecond laser on the center of the cell using several energy values and the cell lost its replication capacity with one time irradiation with an energy of 2.0 mu J. Besides at a neighbor point in the major axis, when irradiated in the minor axis at a distance shorter than 10 mu m, the cell stopped its replication capacity. The accumulation effect of cell damage caused by multiple laser shots at a neighbor point in the minor axis was correlated with the critical distance at which the cell lost its replication capacity. Finally, a novel equation of laser cell damage as a function of laser pulse energy and laser shot number is proposed.

DOI： 10.1007/s10616-012-9437-2

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：IEICE-INST ELECTRONICS INFORMATION COMMUNICATIONS ENG  

High-performance and low-cost sensors are critical devices for high-throughput analyses of bio-samples in medical diagnoses and life sciences. In this paper, we demonstrate photonic crystal nanolaser sensor, which detects the adsorption of biomolecules from the lasing wavelength shift. It is a promising device, which balances a high sensitivity, high resolution, small size, easy integration, simple setup and low cost. In particular with a nanoslot structure, it achieves a super-sensitivity in protein sensing whose detection limit is three orders of magnitude lower than that of standard surface-plasmon-resonance sensors. Our investigations indicate that the nanoslot acts as a protein condenser powered by the optical gradient force, which arises from the strong localization of laser mode in the nanoslot.

DOI： 10.1587/transele.E95.C.188

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

We report on experimental study of the shrinkage of photopolymerized micro/nanostructures fabricated by femto-second direct laser writing in organic-inorganic resists. Blueshift of the stop-band positions of fabricated photonic crystals during the drying process, which follows the development and rinsing stages, indicates that the drying process plays an important role in the formation of the shrinkage. It is further confirmed that the shrinkage almost completely occurs during the drying process by in situ optical monitoring the structures. These findings will help to better understand, control, and even positively utilize the shrinkage in the applications of the photopolymerization-based direct laser writing technique. (C) 2012 Optical Society of America

DOI： 10.1364/OL.37.000710

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）   出版者・発行元：SPIE-INT SOC OPTICAL ENGINEERING  

Advanced lithography systems, such as ArF immersion lithography, have achieved a 32 nm node(1,2) and are already used in electronic device development. However, the advanced lithography systems are not suitable for fabricating nanostructures, such as rectangular cuboids, triangular prisms, chains, and nanogaps. These nanostructures are being used for various applications that include plasmonic solar cells(3-5) and photonic crystal lasers. (6, 7) In this proceeding, we report an innovative lithography system appropriate for fabricating such nano-patterns with nanometric accuracy based on plasmon-assisted photolithography. The key technology is the two-photon photochemical reaction of a photoresist induced by plasmonic near-field light and propagating light in a photoresist film. This propagating light is a radiation mode from a higher order of localized surface plasmon resonances scattered by metallic nanostructures. The system does not induce nano-pattern deformation at the time of mask release. This system presents a simple alternative for producing nano-patterns instead of using nanoimprinting.

DOI： 10.1117/12.913653

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER INST PHYSICS  

We image gigahertz surface acoustic waves normally incident on a microscopic linear array of triangular holes-a generic "acoustic diode" geometry-with a real-time ultrafast optical technique. Spatiotemporal Fourier transforms reveal wave diffraction orders in k-space. Squared amplitude reflection and transmission coefficients for incidence on both sides of the array are evaluated and compared with numerical simulations. We thereby directly demonstrate acoustic rectification with an asymmetric structure. (C) 2011 American Institute of Physics. [doi:10.1063/1.3662930]

DOI： 10.1063/1.3662930

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER INST PHYSICS  

Modification of photovoltaic devices with metallic nanoparticles is expected to be one of the key methods for development of high performance devices as a future energy source. To clarify the mechanism of photocurrent changes induced by surface plasmon resonances of metal nanoparticles, we measured near-field photocurrent excitation images for a GaAs photodiode modified with gold nanospheres (diameter 100 nm) with a spatial resolution higher than 100 nm. The relationship between the photovoltaic efficiency and the plasmons of the gold nanospheres was investigated through the measurements of incident wavelength and polarization dependence of the near-field photocurrent images. Isolated nanospheres deposited on the GaAs active surface caused local photocurrent suppressions at the plasmon resonance wavelengths. In the case of assemblies (dimers and trimers) of the spheres, a remarkable decrease of photocurrent at the gap site between the spheres was observed. From the results, it turned out that the enhanced optical fields created via the plasmons on the metal nanostructures do not improve the photovoltaic efficiency and that forward scattering of photons by the gold nanoparticles is considered to be more important than the enhanced field effect at the particles for the GaAs photovoltaic device studied. (C) 2011 American Institute of Physics. [doi:10.1063/1.3662114]

DOI： 10.1063/1.3662114

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-BLACKWELL  

Fraction collection of selected components from a complex mixture plays a critical role in biomedical research, environmental analysis, and biotechnology. Here, we introduce a novel electrophoretic chip device based on a signal processing theorem that allows simultaneous space sampling for fractionation of ssDNA target fragments. Ten parallel extraction channels, which covered 1.5-mm-long sampling ranges, were used to facilitate the capturing of fast-moving fragments. Furthermore, the space sampling extraction made it possible to acquire pure collection, even from partly overlapping fragments that had been insufficiently separated after a short electrophoretic run. Fragments of 180, 181, and 182 bases were simultaneously collected, and then the recovered DNA was PCR amplified and assessed by CE analysis. The 181-base target was shown to be isolated in a 70-mm-long separation length within 10?min, in contrast to the &gt;50?min required for the 300-mm-long separation channel in our previous study. This method provides effective combination of time and space, which is a breakthrough in the traditional concept of fraction collection on a chip.

DOI： 10.1002/elps.201100362

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

Ag/Au bimetallic nanoparticles possess the combinatory advantages of Au and Ag nanoparticles and can also be utilized to tune the properties of localized surface plasmon resonance. Ag/Au bilayer nanorods were prepared by electron beam lithography, and their spectral properties were investigated. Compared with Ag monolayer nanorods, Ag/Au bilayer nanorods show broader localized surface plasmon resonance bands, and the longitudinal mode and transverse mode localized surface plasmon bands show blueshift and redshift, respectively. The maximum near-field intensity of the longitudinal mode of the Ag/Au nanorod is less than half that of the Ag/Au nanorod without gold layer. Shape-induced modification of Ag/Au bilayer nanorods on their spectral properties was also discussed. (C) 2011 Optical Society of America

DOI： 10.1364/AO.50.005600

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1364/AO.50.005600

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：IOP PUBLISHING LTD  

A gold/silicon nanocomposite structure (NCS) was formed on a Si(100) surface by nanosecond pulsed laser irradiation. The Au/Si NCS contained both Au nanoparticles (NPs) and Au-Si alloy layers. We report that the use of laser irradiation to form Au NPs comprises two competing processes: a top-down effect involving decomposition into smaller NPs and a bottom-up effect involving self-assembly or self-organization into larger NPs. The formation of the periodic structure involved self-organization, i.e., the bottom-up effect, and was observed in situ using a pulsed-laser-equipped high-voltage electron microscope. The NCS formed by laser irradiation can be controlled by adjusting the laser energy density and the number of laser pulses.

DOI： 10.1088/0957-4484/22/37/375607

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：SPRINGER  

We report on recent insights into the interaction between ultra-fast laser pulses and plasmonic nanoparticles. We discuss femtosecond near-field ablation as a simple but versatile tool for the nanoscale modification of surfaces and the high-resolution measurement of a nanostructure's near field. Two model systems are presented, illustrating the complexity of near-field distributions. Furthermore, finite difference time domain calculations in combination with absorption spectra provide a deeper insight into the factors influencing the near-field distribution. For the first time, an almost perfect agreement between the measured ablation pattern and experiment has been reached for gold triangles with a side length around 500 nm. Additionally, the results from picosecond laser irradiated plasmonic structures display a new regime of nanoscale laser material processing. We present first results showing nanometre confined melting induced by laser pulses.

DOI： 10.1007/s00339-011-6443-8

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE BV  

Metallic bowtie nanostructures as plasmonic nanoantennas can create highly enhanced local fields when resonating with the incident light. With Au bowtie nanostructures fabricated by lithography method, we experimentally observed that the photoluminescence (PL) spatial profile from a single Au bowtie nanoantenna was strongly dependent on the excitation light polarization. While varying the incident light polarization, the spatial distribution of the PL intensity in the nanogap of an Au bowtie changed as predicted by the simulation results on the electromagnetic field enhancement distribution. The polarization feature of the PL intensity relative to the polarization direction of incident excitation light was also discussed. The study may find application in the design of polarization sensitive plasmonic sensors. (C) 2011 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.jlumin.2011.04.001

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC  

Plasmonic spectral properties of silver nanoblocks fabricated by electron beam lithography are investigated. The extinction spectra of silver nanoblocks showed a red shift, broadening, and damping with the passage of storage time. In contrast, silver nanoblocks with titanium coating on the top did not show apparent spectral change even after storage for two months. Morphological change of the silver nanoblocks was characterized by scanning electron microscope. The present work clearly demonstrates that coating titanium on the top of the silver nanostructures is an effective way to prevent them from chemical corrosion and stabilize their plasmonic spectral properties.

DOI： 10.1109/LPT.2011.2158640

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

Microphotonic sensors have been actively studied with increasing demands for label-free biosensing in medical diagnoses and life sciences. For high-throughput and low-cost sensing, a high sensitivity is crucial for eliminating the pre-concentration process, while a simple setup of sensors is also desirable. This paper demonstrates a super-sensitivity for protein, which satisfies these requirements. The key device is a photonic crystal nanolaser, in particular with a nanoslot. Even using a simple setup, the nanolaser achieves an extraordinary-low detection limit for BSA protein, i.e. 255 fM on an average, which cannot be explained by its bulk index sensitivity. The specific adsorption of the protein is observed only around the nanoslot with strong laser intensity. This suggests that the super-sensitivity arises from the effective trapping of protein in the nanoslot. (C) 2011 Optical Society of America

DOI： 10.1364/OE.19.017683

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER INST PHYSICS  

We report an innovative lithography system appropriate for fabricating sharp-edged nanodot patterns with nanoscale accuracy using plasmon-assisted photolithography. The key technology is two-photon photochemical reactions of a photoresist induced by plasmonic near-field light and the scattering component of the light in a photoresist film. The scattering component of the light is a radiation mode from higher order localized surface plasmon resonances scattered by metallic nanostructures. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3606505]

DOI： 10.1063/1.3606505

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1016/j.jphotochem.2011.06.004

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）  

To achieve a future low-carbon society, the effective utilization of photons is essential for the development of technologies based on photochemistry, such as photocatalysis and dye-sensitized solar cells, which have the potential to produce clean energy as well as preserve the environment. Here, we propose that gold nanostructures exhibiting localized surface plasmon (LSP) resonance are promising sites for photochemical reaction fields that increase the interaction between a photon and molecule. These interactions are based on electromagnetic field enhancement effects that are induced by LSP excitations and their localization. In this review, recent studies on the strong coupling field between a photon and molecule for photochemical reactions are discussed. As an outstanding example, this concept was applied to the plasmonic, photoelectric conversion of visible to near-infrared wavelengths using electrodes in which gold nanoblocks were elaborately arrayed on the surface of a single TiO2 crystal. The most important characteristic of this photoelectric conversion is that the photocurrent was stable for more than 200 h without adding the donors, which suggests the possibility that water molecules can act as donors that provide electrons to the d-band holes assisted by the LSP excitation. Therefore, this system has the potential for use in artificial photosynthesis systems with irradiation from near-infrared light. © 2011 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.jphotochem.2011.04.014

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE SA  

Gold pair nanocuboids (size: 150 nm x 150 nm x 20 nm) with different nanogaps ranging from 0 to 10.6 nm were prepared by the electron-beam lithography. Effect of plasmon coupling on coherent acoustic phonon dynamics of gold pair nanocuboids was examined as a function of nanogaps by near-IR transient absorption spectroscopy at 400-nm excitation. The similar oscillation periods of coherent acoustic phonon vibration (88 +/- 1 ps) were observed for all the gold pair nanocubiods irrespective of the nanogaps, which was analyzed by the oscillation of bleaching peaks of SPR bands and the transient absorption dynamics. The coherent acoustic phonon vibration of gold nanocuboids was only influenced by the nanostructure itself, even though SPR band was much influenced due to the dipole coupling between the adjacent Au nanocuboids. In addition, it was revealed that the electron-phonon coupling (similar to 0.7 ps) was followed by the initial size change of gold nanocuboid with the time scale that was a little slower (similar to 1.7 ps) than the electron-phonon coupling. (C) 2011 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.jphotochem.2011.02.023

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE SA  

Photochemically induced protein crystallization byprotein&apos;s multiphoton excitation based on enhanced field of localized surface plasmon resonance (LSPR) of gold nanostructures was investigated. As strong photons-molecules coupling fields, gold nanostructures composed of nanoblocks and gold nanocolloid were used. With gold nanostructures, we could observe enzyme activity decrease by light irradiation that protein does not absorb. Surface observation of gold nanostructure by DFM (non-contact dynamic force microscope) shows that proteins were aggregated at around the nanoblock due to photochemical reaction by enhanced field. Crystallization probability depends on the excitation photon fluence, which indicates 3 photons absorption process occurred. (C) 2011 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.jphotochem.2011.03.012

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）   出版者・発行元：ELSEVIER SCIENCE SA  

To achieve a future low-carbon society, the effective utilization of photons is essential for the development of technologies based on photochemistry, such as photocatalysis and dye-sensitized solar cells, which have the potential to produce clean energy as well as preserve the environment. Here, we propose that gold nanostructures exhibiting localized surface plasmon (LSP) resonance are promising sites for photochemical reaction fields that increase the interaction between a photon and molecule. These interactions are based on electromagnetic field enhancement effects that are induced by LSP excitations and their localization. In this review, recent studies on the strong coupling field between a photon and molecule for photochemical reactions are discussed. As an outstanding example, this concept was applied to the plasmonic, photoelectric conversion of visible to near-infrared wavelengths using electrodes in which gold nanoblocks were elaborately arrayed on the surface of a single TiO2 crystal. The most important characteristic of this photoelectric conversion is that the photocurrent was stable for more than 200 h without adding the donors, which suggests the possibility that water molecules can act as donors that provide electrons to the d-band holes assisted by the LSP excitation. Therefore, this system has the potential for use in artificial photosynthesis systems with irradiation from near-infrared light. (C) 2011 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.jphotochem.2011.04.014

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：SPRINGER  

We report in this paper the near-field distribution in the case of gold triangle arrays by means of two-photon polymerization for a dipole and a quadrupole plasmon mode. In order to link the finite difference in the time domain (FDTD) simulations of the triangle array and the experimental results, extinction spectra for both cases in air and SU-8 environments are shown. In case of the 40-nm thick gold triangles with 85-nm side-length, we show that the calculated and experimentally obtained near-field for the excited dipole mode has the same distribution along the polarization of the exciting laser beam. In case of bigger triangles of 540-nm side-length a quadrupole mode is excited, which leads to a rotation of the near-field distribution by 90A degrees referred to the polarization of the beam. This effect is also shown in the FDTD simulations.

DOI： 10.1007/s11468-010-9189-9

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

The instability of silver nanoblocks under atmospheric conditions is investigated. The localized surface plasmon resonance band of the silver nanoblocks shows a red shift, broadening, and damping with increasing storage time under atmospheric conditions. The change in spectral properties of silver nanoblocks is considered to be due to sulfidation of silver and structural breakage of silver nanoblock based on scanning electron microscope observation and numerical simulation. The effect of aspect ratio of silver nanoblocks on the change in spectral properties of the nanoengineered silver blocks is also discussed. (C) 2011 Optical Society of America

DOI： 10.1364/OE.19.010640

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

We perform direct local-field imaging of a plasmon-resonant gold nanoparticle pair separated by a gap of several nanometers using a scattering-type near-field optical microscope with a sharp silicon tip of atomic force microscope. The sharp tip allows the access for the nanogap and the high spatial resolution. Our results provide experimental evidence that the nanogap structure produces an optical spot with the size of a single nanometer (&lt; 10 nm). This is not only of fundamental importance in the field of nanophotonics, but also provide significant information for the development of plasmonic devices with the nanogap structures. (C) 2011 Optical Society of America

DOI： 10.1364/OE.19.007726

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

We report an anomalous light transmission phenomenon for a nanoaperture on an opaque screen when the aperture is covered with an opaque cap. In conventional optics, light transmission must decrease when the aperture is capped. However, we found that light transmission is enhanced when the nanodisk is in close proximity to the aperture at a wavelength close to the plasmon resonance. This effect even occurs when the disk is larger than the aperture. © 2011 American Chemical Society.

DOI： 10.1021/nl103408h

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

We report an anomalous light transmission phenomenon for a nanoaperture on an opaque screen when the aperture is covered with an opaque cap. In conventional optics, light transmission must decrease when the aperture is capped. However, we found that light transmission is enhanced when the nanodisk is in close proximity to the aperture at a wavelength dose to the plasmon resonance. This effect even occurs when the disk is larger than the aperture.

DOI： 10.1021/nl103408h

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE BV  

High efficiency and high-purity fraction collection is highly sought in analysis of fragments-of-interest from selective polymerase chain reaction (PCR) products generated by High Coverage Gene Expression Profiling (HiCEP) methods. Here we demonstrate a new electrophoretic chip device enabling automatic high-efficient fractionation of multiple ssDNA target fragments during a run of separation. We used thoroughly isolated extraction channels for each selected target to reduce the risk of cross-contamination between targets due to cross-talk of extraction channels. Fragments of 35, 108 and 138 b, were successfully isolated, then the recovery was PCR-amplified and assessed by capillary electrophoresis (CE) analysis. Total impurity level of the targets due to unwanted fragments of 0.7%, 2% and 6% respectively, was estimated. Difficulties in collecting multiple target factions are due to band diffusion and DNA adsorption to the walls for the fragments in the separation channel, which is generated by transferring the DNA target fraction from the extraction section to the target reservoir. Therefore, we have carefully measured band broadening and analyzed its influence on the separation resolution due to the delay. (C) 2010 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.chroma.2010.12.089

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-V C H VERLAG GMBH  

Well defined gold nanostructures of various sizes are fabricated on glass substrates using high-resolution electron-beam lithography/lift-off techniques and detailed surface-enhanced Raman scattering (SERS) properties of crystal violet molecules are studied in order to elucidate electromagnetic (EM) field enhancement effects on the fabricated structures. SERS measurements are performed with high reproducibility using in situ Raman microspectroscopy in aqueous solution. An analysis based on EM theory is performed using field-enhancement factors obtained from finite-difference time-domain (FDTD) simulations and the analysis reproduces experimental results very well. It is noteworthy, furthermore, that the proposed analytic method of EM effects on SERS allows the estimate of the ideal local temperature of gold nanostructures by canceling out the difference in EM field factors at Stokes and anti-Stokes Raman scattering wavelengths. Thus, these experimental results demonstrate that quantitative analysis based on EM theory can be obtained using highly controlled gold nanostructures for SERS measurements with high reproducibility, a result that is promising for the construction of a SERS analysis chip. Although no SERS chip reported so far has been usable for quantitative analysis, this study opens the door for construction of a quantitative SERS chip.

DOI： 10.1002/smll.201001560

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-BLACKWELL  

DOI： 10.1002/anie.201101699

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：TAYLOR & FRANCIS LTD  

The polarization dependence of excitation light for fluorescence enhancement of near-infrared dyes immobilized in hydrophobic DNA thin film on glass substrates with regularly arranged Au nanoblocks was investigated. The enhancement factor for S-polarized excitation was about 1.2 to 1.5 times as large as that for P-polarized excitation. P-polarized light contributed to the excitation of plasmon band both of horizontal and vertical direction of Au nanoblocks. The vertical direction corresponds to the short axis for height direction which has the absorption in visible region did not contribute the excitation of IR780. When the absorption band of Au array and the fluorescence band of IR780 were overlapped, the fluorescence enhancement did not depend on the polarization of excitation light. It is suggested that the fluorescence quenching originates from the energy transfer from the excited state of IR780 to Au nanoblocks or the increased deactivation of excited dye molecules induced by resonance with Au nanoblocks.

DOI： 10.1080/15421406.2011.564085

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ROYAL SOC CHEMISTRY  

We have demonstrated the essential nanogap effects on surface-enhanced Raman scattering (SERS) signals obtained from two diagonally aligned gold nanoparticles with several nanometre separations, which were precisely fabricated on a glass substrate. This is the first proof of principle for extracting the light localization effects on SERS due to the formation of nanogaps from experimentally observed SERS signals.

DOI： 10.1039/c0cc05320a

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：CHEMICAL SOC JAPAN  

Fluorescence intensity of near Infrared dyes immobilized in hydrophobic DNA thin film spin-coated on glass substrates with regularly arranged gold (Au) nanoblocks was about 2 5 times larger than that without Au nanoblocks, strongly suggesting the fluorescence intensity was enhanced by increased electric field intensity of excitation light due to local plasmon resonance of Au nanoblocks

DOI： 10.1246/cl.2010.1218

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

The nonlinear propagation of a single focused femtosecond laser pulse in fused silica has been investigated both experimentally and by numerical simulations. In particular, the filamentation behavior was systematically studied by varying pulse duration. At low pulse energy, the peak plasma density inside the filament first increases to a maximum value with increasing pulse duration and then begins to decrease. At relatively high pulse energy, denser plasma can be induced around the geometrical focus with a certain longer pulse duration, where the peak power is already below the self-focusing critical power and no filament is formed. This pulse duration dependent behavior can be explained by different ionization mechanisms. (c) 2010 Optical Society of America

DOI： 10.1364/OE.18.024495

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-V C H VERLAG GMBH  

DOI： 10.1002/smll.201000511

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

Nanoparticles of noble metals exhibit localized surface plasmons (LSPs) associated with the enhancement of an electromagnetic field due to its localization in nanometric domains at the surface of nanoparticles. We demonstrate the plasmonic photoelectric conversion from visible to near-infrared wavelength without deteriorating photoelectric conversion by using electrodes in which gold nanorods are elaborately arrayed on the surface of a TiO2 single crystal.

DOI： 10.1021/jz1006675

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：JAPAN LASER PROCESSING SOC  

Simple frequency-selective surface (FSS) structures consisting of two-dimensional (2D) triangular lattices of circular apertures with an aperture diameter of about 0.6-0.8 mu m and a lattice period of 1.0 and 2.0 mu m were fabricated by femtosecond laser ablation of thin gold films deposited on glass substrates. The fabricated samples were found to exhibit spectral transmission bands at infrared wavelengths, and significant surface plasmonic (SP) local enhancement of the near-field near the metal's surface according to experimental transmission measurements and theoretical simulation by Finite-Difference Time-Domain (FDTD) technique. These results indicate versatility of femtosecond laser ablation technique for rapid prototyping of metallic FSS and plasmonic structures. DOI:10.2961/jlmn.2010.02.0003

DOI： 10.2961/jlmn.2010.02.0003

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-BLACKWELL  

Nanopatterns of a TiO2-organic hybrid material have been fabricated with the use of a localized surface plasmon (LSP). The TiO2-organic hybrid material was prepared by the sol-gel method and was coated on a glass substrate with gold nanoblocks. After the hybrid films were irradiated with a femtosecond laser, the unreacted parts were removed, leaving the TiO2-organic hybrid materials around the nanoblocks. In the nanopatterns of the TiO2-organic hybrid materials, the pi - pi* transition absorption band of the chelate compound formed between Ti-alkoxide and beta-diketone was excited by the two-photon absorption induced by the LSP of gold nanoblocks, and the chelate compound was decomposed and dissolved in alcohol. It was confirmed that the hybrid material changed to anatase upon sintering above 450 degrees C.

DOI： 10.1111/j.1551-2916.2010.03645.x

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：SPRINGER  

Influence of direct laser writing with femtosecond pulses on electrochemical etching of n-type low conductivity (&gt; 1,000 Omega cm) silicon is demonstrated. It has been shown that thermal 1-A mu m-thick SiO(2) layer on silicon surface can be used as a protective layer in the electrochemical etching process. It has been found that laser ablation changes not only the surface morphology and structure of silicon samples but also the character of their anodic etching in aqueous solution of hydrofluoric acid. Formation of microvoids and caverns of irregular shape has been observed at the laser-ablated sites. It is proposed that the change of silicon conductivity from n- to p-type takes place at the laser fabricated regions. Processes of Si anodic oxidation and electrochemical etching are discussed.

DOI： 10.1007/s10008-009-0852-z

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OSA Publishing  

DOI： 10.1364/OL.35.000940

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE SA  

Photoinduced shape changes of metal nanostructures in halide solutions were investigated using gold and silver nanoblocks (NBs) patterned on a glass substrate, instead of nanoparticles dispersed in solution. It was found that size reduction of the NBs by halide etching was enhanced by photoirradiation. Furthermore, it was revealed that the halide etching efficiency corresponded to the intensity of the electric field induced by localized surface plasmon resonance (LSPR) of the NBs. The enhancement of halide etching by LSPR was explained on the basis of electron transfer reactions from metal NBs. Throughout this study, it was demonstrated that metal NBs fabricated on a substrate constitute a powerful system to investigate photoinduced shape changes of nanostructures, because of their defined shape, position, and configuration. (C) 2010 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.jphotochem.2010.03.007

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：IOP PUBLISHING LTD  

We present a method to fabricate freestanding and movable photonic microstructures by photopolymerization in a zirconium-based sol-gel hybrid resist with femtosecond laser three-dimensional (3D) direct writing. The freestanding microstructures exhibit much less distortion than the conventional structures attached to substrates, especially when made at close to the photopolymerization threshold. A few percent shrinkage which exists rescales the structure and it can lead to the shift of the photonic stop band toward shorter wavelengths. Fabrication of freestanding and freely movable (in micro-fluidic environment) 3D microstructures realizes a simple approach to quantitatively study the shrinkage of photopolymers and to improve the resolution. 3D-movable micro-optical elements with designed photonic properties and micro-devices have potential in opto-fluidics and opto-micro-mechanical applications based on laser trapping and manipulation.

DOI： 10.1088/0960-1317/20/3/035004

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER PHYSICAL SOC  

We demonstrate that the interaction of intense femtosecond pulse with photorefractive crystal at conditions close to the optical-breakdown threshold differs drastically from that of long pulse and cw illumination. Our theoretical estimations show that the high number density of excited electrons modifies the dielectric function leading to the transient negative change in the refractive index, Delta n/n(0)similar to-10(-2) that vanishes on nanosecond time scale. Moreover, the high-frequency laser field, two orders of magnitude larger than the field of spontaneous polarization, prevents the stationary charge distribution during the pulse. The diffusion and recombination of charge carriers continues over a nanosecond time scale, after the end of the pulse. The main driving force for the current after the pulse is the field of spontaneous polarization in the ferroelectric medium: the current terminates when the field of charge separation balances this field. We show here that the stationary modification of refractive index according to this model is then independent of the polarization of the pump light beam, in agreement with experiments, and saturates at Delta n approximate to 10(-3) in semiquantitative fit to the experimental data.

DOI： 10.1103/PhysRevB.81.054113

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

Nanoparticles of noble metals exhibit localized surface plasmons (LSP) associated with enhancement of the electromagnetic field due to its localization in nanometric domains at the surface of nanoparticles. Especially, nanogapmetallic structures show strong enhancement of the electromagnetic field at the nanogap position. This can be achieved up to 10(5) times larger than the incident light field. We have explored the possibility to use the localized field for nanogap-assisted surface plasmon nanolithography. For the purpose, monidisperse arrays consisting of pairs of rectangular gold nanoblocks separated by nanogaps were fabricated on glass substrates using electron beam lithography and lift-off techniques. Nanoblock structures were used as photomasks for contact exposure of thinfilms of positive photoresist on glass substrates. Thus, ordered clusters of nanoparticles separated by nanogaps can provide a stable and versatile platform for further development of optical subwavelength nanolithography. To the best of our knowledge, this is the first proof-of-principle demonstration of such a technique.

DOI： 10.1021/jz9002923

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：JAPAN SOC ANALYTICAL CHEMISTRY  

Nanostructured interdigitated array (IDA) electrodes with different inter-electrode spacing were demonstrated to improve the detection sensitivity of short-lived electroactive species and to follow interfacial dynamics by their surface-enhanced Raman scattering (SERS) functionality. Nanostructured IDA electrodes fabricated using electron beam lithography were used for an electrochemical SERS study of irreversible electroactive species, crystal violet (CV), in an aqueous KCl solution in single and generation-collection (GC) mode experiments. The GC mode enabled us to amplify the SERS intensity. An inter-electrode spacing dependent study found the maximum number of redox cycling, collection efficiency and amplification of the SERS intensity. Its SERS function disclosed the potential-dependent dynamics of CV molecules at the electrode surface, which was not observed in the redox current. Miniaturized nanostructured IDA electrodes are of great importance for developing lab on chip devices, and are useful for analyzing dynamical features within small space/volume domains, which require small amounts and/or concentration of analytes.

DOI： 10.2116/analsci.26.19

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：JAPAN SOC ANALYTICAL CHEMISTRY  

Interdigitated array electrodes with surface-enhanced Raman scattering (SERS) functionality for in situ qualitative and quantitative analysis of electroactive species are demonstrated. Gold nanostructured interdigitated array electrodes (NIDAEs) were fabricated by electron beam lithography, and used for an electrochemical SERS study of K(3)[Fe(CN(6))] in aqueous KClO(4) solution in single and generation-collection modes. The generation-collection mode experiment showed amplification of the SERS band intensity for adsorbed ferricyanide ions at the negative end of the applied potential, while in single mode it was reduced to near zero. This new finding reveals that NIDAEs offer a new opportunity for analytical science by improving analytical sensitivity and detection ability of electroactive species. The electric fields accumulating at nanogaps are promising for manipulating linear and nonlinear optical phenomena. In addition, miniaturized NIDAEs are of great importance for developing lab-on-a-chip devices, and are useful for measurements within small space/volume domains, requiring only small amounts and/or concentrations of analytes.

DOI： 10.2116/analsci.26.13

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）   出版者・発行元：SPIE-INT SOC OPTICAL ENGINEERING  

We report maskless microfabrication of periodic structures in thin metallic films by femtosecond laser ablation. Two-dimensional (2D) triangular arrays of circular apertures with diameter of about 0.6 - 0.8 mu m and a lattice period of 1.0 and 2.0 mu m were fabricated by single-and multiple laser pulse ablation of 35 nm thick gold films sputtered on glass substrates. Optical transmission spectra of the fabricated samples exhibit transmission bands at infrared wavelengths. Theoretical modeling of the optical properties by Finite-Difference Time-Domain (FDTD) technique indicates that these bands are associated with localized and propagating surface plasmon (SP) modes. FDTD simulations also indicate substantial resonant enhancement of the near-field intensity at the metal's surface. Laser ablation of thin metallic films is therefore a promising route for fast prototyping of planar metallic micro-and nano-structures applicable as frequency-selective surfaces (FSS) and SP substrates.

DOI： 10.1117/12.843074

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）   出版者・発行元：SPIE  

We present the fabrication of microstructures for photonic and micro-/opto-fluidic applications using femtosecond laser 3D direct writing technique in zirconium-based sol-gel hybrid resist. The advantages and mechanism of photo-polymerization of this new material under fs-pulsed laser exposure are discussed. We suggest and achieve a novel method to fabricate free-standing and movable photonic microstructures, which exhibit much less distortion than the conventional structures attached to substrates, especially when made at close to the photopolymerization threshold. Fabrication of free-movable structures allows us to quantitatively study the shrinkage of photoresist and to improve the resolution. It also contributes to tuning the stop band position of photonic crystals to shorter wavelength. Furthermore, the demonstrated freely-movable property makes it possible to laser trap and manipulate photonic microstructures and have potential application in optofluidics and bio-applications. © 2010 Copyright SPIE - The International Society for Optical Engineering.

DOI： 10.1117/12.840657

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）  

We present the fabrication of photonic microstructures using femtosecond laser direct writing technique in resist. The effect of drying process on photo-polymerized microstructures is investigated. We find that shrinkage mostly arises during the drying process.

DOI： 10.1109/AOM.2010.5713579

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）   出版者・発行元：IEEE  

We have developed photonic crystal nanolaser and applied it to sensing liquids and bio-molecules. In this study, a nano-slot structure is introduced into the nanolaser, which strengthens the mode localization and improves the sensitivity, stability, and resolution as a sensor. As a result, a very low detection limit of 5.1 pg/ml has been achieved for BSA protein. It will be applicable to high-throughput label-free biosensing, while a mechanism of such low detection limit with the nano-slot is of great interest to investigate. ©2010 IEEE.

DOI： 10.1109/ICSENS.2010.5690745

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

We use ultrashort optical pulses to excite and detect vibrations of single silica spheres with a diameter of 5 mu m placed at the surface of an acoustically mismatched substrate. In addition to the photoelastic detection of picosecond longitudinal acoustic pulses propagating inside the bulk, we detect gigahertz acoustic resonances of the sphere through probe beam defocusing. The mode frequencies are in close accord with those calculated from the elastic vibrations of a free sphere. We also record a resonant enhancement in the amplitude of specific modes of two touching spheres. (C) 2009 Optical Society of America

DOI： 10.1364/OL.34.003740

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-V C H VERLAG GMBH  

For the fractionation of fragments of interest from selective PCR products generated by high coverage gene expression profiling (HiCEP) analysis, high-resolution with the ability to discriminate and fractionate fragments differing by one base (base pair) in size is highly required. We report here on a new 4-inch diameter spiral-channel chip device for automatic high-fidelity fractionation. Overlapping DNA fragments of 180, 181 and 182 bases, with only one-base difference in size, were successfully fractionated. The collected fragments were PCR amplified, and then evaluated by size checking analysis, DNA sequencing, and homolog search. The high-resolution fractionation has been achieved because of the combined contributions of (i) the high-resolution separation using a 30 cm long spiral channel, (ii) a blocking technique to avoid contamination from unselected fragments during CE, and (iii) precise micro-scale target extraction. Contaminations due to unselected fractions have been greatly decreased to a negligible level by optimization of the extraction position and extraction time corresponding to the targeted segment only. This technique can be adapted to a wide range of applications, such as protein or cell collections where requirements for the high purity are more important than the amount of recovered fractionated material.

DOI： 10.1002/elps.200900455

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE BV  

We report on structural characterization of void-structures created by a micro-explosion at the locus of a tightly focused femtosecond laser pulse inside the crystalline phase of Al(2)O(3) (R3c space group). The transmission electron microscopy (TEM), micro-X-ray diffraction (XRD) analysis, and Raman scattering revealed a presence of strongly structurally modified amorphous regions around the void-structures. We discuss issues of achieving the required resolution for structural characterization and assignment of newly formed phases of nano-crystallites by TEM, XRD, and Raman scattering from micro-volumes of modified materials enclosed inside the bulk of the host phase. (C) 2009 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.apsusc.2009.04.063

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE BV  

Millimeter-long filaments and accompanying luminous plasma and defect channels created in fused silica (FS) by single focused femtosecond laser pulses with supercritical powers were probed in situ using optical imaging and contact ultrasonic techniques. Above the threshold pulse energy E(opt) = 5 mu J corresponding to a few megawatt power levels pulses collapse due to self-focusing, producing channels filled by electron-hole plasma and luminescent defects, and exhibits predominantly compressive pressure transients. Analysis of the optical and ultrasonic response versus the laser pulse energy suggests that filamentary pulse propagation in the channels occurs with considerable dissipation of about similar to 10 cm (1). The predominant ionization mechanism is most likely associated with avalanche ionization, while the main mechanism of optical absorption is free-carrier absorption via inverse Bremsstrahlung interaction with the polar lattice. (C) 2009 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.apsusc.2009.04.057

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER INST PHYSICS  

Femtosecond laser fabrication of three-dimensional structures for photonics applications is reviewed. Fabrication of photonic crystal structures by direct laser writing and holographic recording by multiple beam interference techniques are discussed. The physical mechanisms associated with structure formation and postfabrication are described. The advantages and limitations of various femtosecond laser microfabrication techniques for the preparation of photonic crystals and elements of microelectromechanical and micro-optofluidic systems are discussed.

DOI： 10.1063/1.3216462

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER PHYSICAL SOC  

We report on the generation of mono- and polychromatic optical phase singularities from micron-sized birefringent droplets. This is done experimentally by using liquid crystal droplets whose three dimensional architecture of the optical axis is controlled within the bulk by surfactant agents. Because of its microscopic size these optical vortex generators are optically trapped and manipulated at will, thus realizing a robust self-aligned micro-optical device for orbital angular momentum conversion. Experimental observations are supported by a simple model of optical spin-orbit coupling in uniaxial dielectrics that emphasizes the prominent role of the transverse optical anisotropy with respect to the beam propagation direction.

DOI： 10.1103/PhysRevLett.103.103903

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE SA  

This work describes fabrication of three-dimensionally nano-textured silicon surface structures metalized by thin gold films,and their application for optical sensing and detection of solute molecules utilizing surface-enhanced Raman scattering (SERS) effect. Two types of sensitive surfaces were prepared by different techniques. The first of them was a checkerboard pattern of 3D nanoblocks defined in compact areas on the surface of a silicon wafer using highly accurate electron-beam lithography (EBL) technique, and fabricated by dry reactive-ion etching (RIE) technique with subsequent metalization of the surface by gold sputtering. The second type of sensitive surface consisted of a square array of nano-apertures. defined on a large area of the silicon surface by a less accurate but simpler ultraviolet holographic lithography, and subsequently fabricated in a sequence of dry and wet etching as well as gold sputtering steps. The fabricated structures were found to exhibit significant near-field enhancement, as evidenced by strong SERS signal from the sensors immersed in aqueous pyridine solutions with concentrations as low as 10(-9) M due to the presence of well-defined 3D periodic texture of the structure. (C) 2008 Elsevier BY. All rights reserved.

DOI： 10.1016/j.jphotochem.2008.10.007

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER INST PHYSICS  

We examined vibrational dynamics of periodic gold single and pair nanocuboids with 9 nm separation at 400 nm excitation by near-IR transient absorption spectroscopy. The similar oscillation periods of coherent phonon vibration (77 +/- 1 ps) were observed for both nanocuboids while the damping of the pair was faster than that of the single. From the analysis of bleaching peak shift and finite-difference time-domain calculation, the lattice change in coherent phonon vibration was estimated to be +/- 1% for a quasiextensional and +/- 3% for an quasibreathing modes of a single nanocuboid.

DOI： 10.1063/1.3202403

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

The optical linear and nonlinear properties of similar to 340-nm-thick Si membranes were investigated. The investigation included both experiments in which the reflection and transmission from the membranes were measured, and finite differences time domain simulations. The linear optical transmission of the Si membranes can be controlled by changing the thickness of a thermally grown oxide on the membrane. Illumination of the membranes with high levels of irradiation leads to optical modifications that are consistent with the formation of amorphous silicon and dielectric breakdown. When irradiated under conditions where dielectric breakdown occurs, the membranes can be ablated in a well-controlled manner. Laser micro-structuring of the membranes by ablation was carried out to make micrometer-sized holes by focused fs-pulses. Ns-pulses were also used to fabricate arrays of holes by proximity-ablation of a closely-packed pattern of colloidal particles. (C) 2009 Optical Society of America

DOI： 10.1364/OE.17.015308

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1021/jp903929e

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

Photopolymerization of commercial photoresist SU-8 assisted by plasmonic near-field enhancement in nanogaps separating gold nanoblocks was investigated. Photopolymerization rates enhanced by orders of magnitude were found in gold nanoblock structures with nanogaps narrower than 10 nm. The mechanisms responsible for local and nonlocal nonlinear photopolymerization of SU-8 are discussed.

DOI： 10.1021/jp901773k

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE BV  

It is demonstrated that the processes leading to nano-void formation under single-pulse tight focusing in dielectrics are described by the same laws used to describe macroscopic explosions but with energies 10(21) times lower and space and time scales reduced by 10(7). (C) 2009 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.jnoncrysol.2009.02.013

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER INST PHYSICS  

Millimeter-long filaments and accompanying luminous plasma and defect channels created in fused silica by single, moderately focused femtosecond laser pulses with supercritical powers were probed in situ using optical imaging and contact ultrasonic techniques. Above the threshold pulse energy E-opt = 5 mu J corresponding to a few megawatt power, the pulses collapse due to self-focusing and the nonlinear focus moves upstream with increasing pulse energy. Behind the focus, elongated, gradually narrowing awl-shaped channels of electron-hole plasma and luminescent defects are produced. In the channels, whose dimensions generally depend on the pulse energy, supercontinuum emission propagating downstream the channels occurs, although its observation requires elevated pulse energies above 25 mu J in order to compensate energy dissipation in the channels. Ultrasonic side-view imaging of the channels, conducted from a few millimeters distance, reveals predominantly compressive pressure transients. The compressive signals are observed above the same threshold pulse energy E-opt, and their amplitude increases linearly with the laser pulse energy, simultaneously exhibiting significant temporal broadening of the corresponding pulsewidths, reflecting square root dependence of the channel length and sublinear (proportional to E-3/4) dependence of the source pressure on the pulse energy. Altogether, these optical and ultrasonic studies demonstrate filamentary pulse propagation with considerable dissipation (similar to 10 cm(-1)) in the awl-shaped subcritical plasma channels rich with generated point defects and optical damage sites. (C) 2009 American Institute of Physics. [DOI: 10.1063/1.3148249]

DOI： 10.1063/1.3148249

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

Gratings were recorded on the surface of nickel by ablation without formation of ripples using an interference of two p-polarized femtosecond laser beams at a pi/4 angle of incidence. The mechanism of ripples' suppression is explained by formation of a polarization grating and by ablation at the locations where the polarization is normal to the Ni surface. The aspect ratio of the ablated grooves was similar to 3 with the period similar to 570 nm at the central wavelength of irradiation of 800 nm. This method is applicable for laser structuring of different materials and a recorded grating structure can be scaled with the irradiation wavelength. (C) 2009 Optical Society of America

DOI： 10.1364/OE.17.004388

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

Lasing in dye solution-embedded inverse silica opal structures was investigated. The opal films were prepared by sedimentation of polystyrene microspheres on a cover glass. The polystyrene structures were inverted using sol-gel infiltration of silica and subsequent removal of polystyrene. Photoluminescence of rhodamine ( rhodamine B, 6G and sulfo-rhodamine 101) dye solutions embedded into the inverse silica opal structures exhibited clear signatures of the lasing via a distributed feedback (DFB) and gain modulation. The refractive index contrast between the dye and the inverse opal was small enough (similar to 0.03%) for the formation of refractive index coupling between the lasing modes. The lasing spectrum exhibited a highly regular periodic structure of modal peaks, rather than the chaotic superposition of peaks reported in previous studies. Lasing modes having a spectral width of about 0.25 nm and a free spectral range of about 0.75 nm appeared at the position of the maximum gain ( the maximum fluorescence of the dye). (c) 2009 Optical Society of America

DOI： 10.1364/OE.17.002976

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

Qualitative resemblance between photopolymerization patterns induced in a commercial photoresist SU-8 by optical near-field of surface plasmons localized on rectangular gold nanorods was observed. This finding indicates the possibility of a fast qualitative near-field imaging by embedding metallic nanoparticle structures into photopolymerizeable media and examining the shapes of polymerized regions using high-resolution electron-scanning or atomic force microscopies following the optical exposure.

DOI： 10.1021/jp809623y

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

A new methodology for nanoscopic molecular filtering was developed using a substrate with a periodic array of metallic nanogates with various widths between 75 and 500 nm. A self-spreading lipid bilayer was employed as the molecular transport and filtering medium. Dye-labeled molecules doped in the self-spreading lipid bilayer were filtered after the spreading less than a few tens of micrometers on the nanogate array. Quantitative analysis of the spreading dynamics suggests that the filtering effect originates from the formation of the chemical potential barrier at the nanogate region, which is believed to be due to structural change such as compression imposed on the spreading lipid bilayer at the gate. A highly localized chemical potential barrier affects the ability of the doped dye-labeled molecules to penetrate the gate. The use of the self-spreading lipid bilayer allows molecular transportation without the use of any external field such as an electric field as is used in electrophoresis. The present system could be applied micro- and nanoscopic device technologies as it provides a completely nonbiased filtering methodology.

DOI： 10.1021/ac802130e

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）  

We report on the incorporation of silicon nanocrystals (nc-Si) into the photo-polymer resist SU8 by direct laser writing using femtosecond laser pulses and on the holographic formation of nano-/micro-textured surfaces by interference of several beams forming patterns with wide range of spatial frequencies. These approaches open possibility for a three-dimensional (3D) architectures of micro-structures potentially useful for active optical and fluidic micro-devices. © The Electrochemical Society.

DOI： 10.1149/1.3104710

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）  

DOI： 10.1109/CLEOE-EQEC.2009.5192211

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）  

DOI： 10.1109/CLEOE-EQEC.2009.5196280

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）   出版者・発行元：SPIE-INT SOC OPTICAL ENGINEERING  

Metalo-dielectric photonic crystals (MDPC) were fabricated by the combination of direct laser writing technique, which was used to prepare initial dielectric templates, and by subsequent metalization of the templates using electroless coating technique. The obtained MDPC structures have adequate structural quality, and exhibit spectral signatures of photonic bands consistent with theoretical expectations. The fabrication process is simple but reliable, and can deliver MDPC structures suitable for operation in the infrared and terahertz spectral ranges.

DOI： 10.1117/12.808725

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）   出版者・発行元：SPIE-INT SOC OPTICAL ENGINEERING  

Generation of free-carrier plasma and filamentation of the ultra-short laser pulse were investigated and modeled. Experimental results of filamentation are supported by numerical model which takes into account accumulation of refractive index modifications due to multi-pulse exposure. A contact acoustic monitoring technique was employed to perform spatially-resolved in situ detection of micro-plasma formation and filamentation of focused femtosecond laser pulses with critical and sub-critical powers in glass. The recorded acoustic signals reveal free-carrier generation mechanisms associated with the formation of plasma and filamentation of the propagating laser pulses. Optical opacity of the plasma region, which sets in at the irradiance of a few kJ/cm(3) (close to the dielectric breakdown threshold) using pulse focusing optics with numerical aperture NA = 0.75, reveals its critical character, and allows the estimation of acoustic pressure in the similar to GPa range. The pressure depended on the irradiance as P similar to I-0.59. In the case of loose focusing (NA = 0.035) filamentation of fs-pulses occurred at sub-critical plasma density with P similar to I. Detection and interpretation of these acoustic signatures thus enable real-time in situ monitoring of optical ionization, pulse filamentation in bulk dielectrics under the irradiation by femtosecond laser pulses.

DOI： 10.1117/12.808856

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：TAYLOR & FRANCIS LTD  

We report on optically induced rotations of nematic liquid crystal droplets. We show experimentally that bipolar nematic liquid crystal droplets trapped in laser tweezers having circular polarization can exhibit nonlinear rotational motion, unlike optically trapped solid birefringent micro-plates. Such nonlinear rotations are retrieved by analyzing the polarization dynamics analysis of the light beam after it has passed through the droplet. The occurrence of complex dynamics is only found for large enough trapping power and droplet diameter. The analogy with optically induced nonlinear rotations in nematic liquid crystal films is briefly discussed.

DOI： 10.1080/15421400903050780

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE BV  

We have generated hard X-rays by front- and back-side femtosecond laser irradiation of PbO-rich glass. The actual Pb content of glasses was corroborated by Pb M-line emission intensities with an uncertainty of less than 20%. The elements K and As at concentrations of a few mol% were detected. X-ray generation by back-side irradiation helped to avoid an air breakdown; however, self-focusing and filamentation limited the achievable light intensity and effectiveness of X-ray generation. Characteristics and mechanisms of X-ray generation from the front- and back-side of glasses are discussed. (C) 2008 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.jnoncrysol.2008.09.013

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-V C H VERLAG GMBH  

We report on wet etching of photomodified regions in crystalline sapphire using KOH solution. Tightly focused femtosecond laser pulses (150 fs at 800 nm wavelength) were used to create void structures enclosed in an amorphised sapphire shell inside the bulk of a crystalline host. The diameter of the amorphous regions can be controlled by pulse energy and was typically 0.5-1.5 mu m. The etching rate depends on the distance between adjacent irradiation spots, pulse energy, concentration of etchant and ultrasonic agitation.

DOI： 10.1002/pssr.200802203

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：SPRINGER  

The high-temperature annealing (1500 degrees C for 15 min) of the shock-amorphized and compressed sapphire around the voids rendered the amorphous sapphire insoluble in aqueous solution of hydrofluoric acid. There were no observable back relaxation and reflow of the compressed amorphous phase. The overlapping of femtosecond pulses by &gt; 70% of the focal diameter also made the photomodified regions insoluble in aqueous solution of hydrofluoric acid. Femtosecond laser cutting of hard dielectric materials is discussed.

DOI： 10.1007/s00339-008-4763-0

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-BLACKWELL  

A microchannel chip has been used to fractionate selected segments from an electrophoretic flow of separated fragments. A sample, which covers the size from 35 to 670 bp, was initially separated using an 8.8-cm-long channel at the electric field strength of 100 V/cm. The target fragment of 318 bp was selected and extracted from the separation channel. High-resolution fractionation was achieved by introducing new procedures for blocking, extraction, and segment transfer. Fractionation quality with and without blocking were compared using a 310 Genetic Analyzer (Applied Biosystems). The results show that no contamination was found in the sample, which was fractionated with blocking; however, a contamination by short segments was found in the sample, which was fractionated without blocking. Furthermore, fractionation by the chip was found to be of higher fidelity than that by the polyacrylamide slab gel, which displayed a small overlapped peak after the target peak. Compared with the traditional method, our chips enable faster and high-fidelity fractionation, thus providing a new toot for bioanalysis and other applications.

DOI： 10.1002/elps.200700904

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：SPRINGER  

We study experimentally the formation of refractive index voxels (volume elements) in photorefractive LiNbO3 and LiTaO3 crystals illuminated with high irradiance femtosecond laser pulses. We used 150 fs pulses at 800 nm wavelength (energy 6-50 nJ) tightly focused inside the crystals in a single shot regime. This resulted in a formation of a micrometer size region of elevated refractive index, which may be used as memory bits in information storage/retrieval application. The maximum refractive index change of 5x10(-4) was recorded in undoped LiNbO3 at an average light intensity of similar to TW/cm(2) that is close to the breakdown threshold. A simple setup for photorefractive recording and in situ monitoring of the refractive index changes has been proposed.

DOI： 10.1007/s00339-008-4641-9

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

Lasing from zirconia inverse opal photonic crystal structures infiltrated by solutions of rhodamine dyes was found to exhibit single-mode lasing peaks with spectral width less than 1 nm and quality factor in excess of 4000. The lasing occurs within the approximate range of high-reflectance spectral region associated with photonic stop band along &lt; 111 &gt; crystallographic direction, but its wavelength is not fixed to the corresponding Bragg wavelength of the periodic structure, and depends on the spectral position of the gain band. This lasing regime can be useful for realizing tunable single-mode photonic crystal lasers. (c) 2008 Optical Society of America.

DOI： 10.1364/OE.16.013676

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

The chirp effect on a X-ray emission intensity from a CsCl aqueous solution jet irradiated by femtosecond pulses was systematically studied. The p-polarized chirped pulses were more efficient as compared with the shortest pulses determined by the spectral bandwidth. The negatively-chirped pulses of approximately 240 fs duration produced up to 10 times larger X-ray intensity as compared with the transform-limited 160 fs pulses. The angular dependence of X-ray generation can be explained by the resonant absorption. Numerical simulations of electron density evolution due to the avalanche and multi-photon absorption supports qualitatively well the experimental observations. (c) 2008 Optical Society of America.

DOI： 10.1364/OE.16.012650

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：BENTHAM SCIENCE PUBL LTD  

We investigate functional capabilities of large arrays of gold and silver nanorods as elements of plasmonic devices. The samples were fabricated by electron beam lithography and lift-off techniques on glass substrates. The areas patterned by the nanorods or other nanoparticles can be large, with dimensions of up to about one centimeter. Structural and optical characterization has allowed confirmation of a high homogeneity of the fabricated ensembles of nanorods, and a high sensitivity of their longitudinal extinction bands to the variations of the nanorod length and the refractive index of the environment. Applications of nanorods as refractive-index sensors is discussed.

DOI： 10.2174/157341308785161046

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC  

This paper describes femtosecond laser lithography of 3-D photonic crystal templates in commercial photoresist SU-8 and replication of these templates with silicon. Using this approach, silicon-based photonic crystals having 3-D square spiral architecture and exhibiting photonic stop gaps near the 2.5-mu m wavelength were fabricated. Possibilities to use a multiple-beam interference technique for two-photon absorption templating of photonic crystals are explored.

DOI： 10.1109/JSTQE.2008.922909

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：SPRINGER  

A morphological parameter of polygonal index was defined as the ratio of cell adhesion area versus the square of the major cell axis, and cells that had an adhesion area larger than 4000 mu m(2) and a polygonal index larger than 0.3 were considered large polygonal cells. Cell morphology tended to change from fibroblast-like to polygonal and the percentage of the large polygonal cells increased almost in proportion to aggrecan mRNA expression level during the differentiation culture of mesenchymal stem cells (MSCs) to chondrocytes. Approximately 80% of the large polygonal cells were negative for MSC marker (CD90, CD166) expression and the aggrecan mRNA expression level of the large polygonal cells was markedly higher than that of cells with other morphologies.

DOI： 10.1007/s10529-008-9683-8

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER CHEMICAL SOC  

We demonstrate the possibility to achieve optical triggering of photochemical reactions via two-photon absorption using incoherent light sources. This is accomplished by the use of arrays of gold nanoparticles, specially tailored with high precision to obtain high near-field intensity enhancement.

DOI： 10.1021/ja801262r

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE BV  

We report on a three-dimensional single-shot optical recording by 150 fs pulses at 800 nm wavelength in Fe-doped and stoichiometric undoped LiNbO3. The highest refractive index modulation of similar to 10(-3) per single pulse has been achieved at close to the dielectric breakdown irradiance of similar to TW/cm(2), and was found to be independent of polarization of the writing beam. The quasi-permanent and rewritable bits have been demonstrated in Fe-doped LiNbO3. Recording in undoped stoichiometric LiNbO3 was of transient nature with full optical contrast recovery on a 0.1-1 s scale. The observed refractive index modulation is explainable by the photovoltaic effect in LiNbO3. (c) 2007 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.cap.2007.10.072

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE BV  

Formation of three-dimensional (3D) patterns of 0.2-0.5 mu m diameter voids inside a transparent solid has been demonstrated. The nano-voids could be created with a spacing similar to 2 mu m thus suggesting the possibility of permanent 3D optical memory with density similar to 100 Gbit/cm(3). Extremely high pressures of similar to 10 TPa and temperatures up to 10(5) K can be produced by a single sub-picosecond laser pulse tightly focused inside transparent dielectrics. Analysis of the size of the void and the shock affected zone as a function of the deposited energy shows that the experimental results can be explicitly understood on the basis of conservation laws and be modeled by plasma hydrodynamics. Therefore, the size of the void can be controlled and predicted by proper focusing conditions and laser parameters. (c) 2007 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.cap.2007.10.071

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

Laser manipulation of trapped radial 4′ -n-pentyl-4-cyanobiphenyl (5CB) nematic liquid-crystal droplets induced by molecular reordering is presented. We show experimentally that optical tweezers having linear, elliptical, or circular polarization can break the radial symmetry of the initial molecular organization inside a radial nematic droplet. Static distorted or twisted deformation modes and steady or unsteady nonlinear rotational dynamics are observed. Statics results are analyzed in terms of light-induced radial or left-right symmetry breaking effects associated with optical reorientation. The dynamical observations are compared with simulations from a slab analog model, for which orientational processes driven by optical nonlinearities can be accurately described. This study confirms that light-induced bulk reordering is an essential ingredient towards the understanding of the behavior of radial nematic liquid-crystal droplets in laser tweezers, as suggested by previous studies. © 2008 The American Physical Society.

DOI： 10.1103/PhysRevE.77.041704

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

A coupled mechanism for molecular aggregation in a thin water solution film by laser-tweezers is suggested based on (i) simulation of light intensity distribution and (ii) order of magnitude analysis of heat and mass transport induced by Marangoni convection. The analysis suggests that the laser induced temperature distribution develops within 1 ms and Marangoni convection flow commences within 0.01-1 s, which increases by 1-2 orders of magnitude the mass transfer of dissolved molecules into the laser focus where they are trapped and aggregate by attractive van der Waals forces. This mechanism, considered for the particular case of polymer assembly, suggests that it can also be successfully applied for assembling other types of clusters and molecular aggregates from solutions. (C) 2008 Optical Society of America.

DOI： 10.1364/OE.16.005673

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：AMER INST PHYSICS  

Contact acoustic technique has been employed to perform spatially resolved in situ detection of microplasma formation and filamentation of tightly focused femtosecond laser pulses with supercritical pulse powers in bulk dielectrics, via corresponding acoustic emission. Investigation of acoustic generation mechanisms related to the plasma formation and filamentation effects reveals the critical character of the opaque microplasma and provides estimates of its gigapascal-level pressures and energy densities of a few kJ/cm(3). The acoustic measurement enables real-time in situ monitoring and revealing of basic mechanisms of ionization and filamentation in bulk dielectrics. (C) 2008 American Institute of Physics.

DOI： 10.1063/1.2894506

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ELSEVIER SCIENCE BV  

We demonstrate a method of capillary force reduction during wet processing of three-dimensional structures photo-polymerized in resist by femtosecond pulses. A rinse in water was added as the final step of wet processing for recovery of free-standing photo-polymerized structures with feature sizes of similar to 100 nm. The hydrophobicity of resist was utilized for reduction of the capillary drainage force. We show a possibility of holographical recording of a three-dimensional woodpile structure, which has a good permeability and can be fabricated by the proposed modified wet processing. (c) 2007 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.jnoncrysol.2006.11.048

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：WILEY-V C H VERLAG GMBH  

Gold nanostructures consisting of nanoblocks separated by a few nanometer-wide gaps were fabricated, and found to exhibit strong photoluminescence due to enhancement of the optical near-field localized in the nanogaps. The fabricated structures demonstrate a nanostructured metallic material capable of efficient photoluminescence, whose efficiency can be adjusted by tailoring the nanogap width.

DOI： 10.1002/adma.200602680

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記述言語：英語   掲載種別：研究論文（国際会議プロシーディングス）   出版者・発行元：SPIE-INT SOC OPTICAL ENGINEERING  

We present experimental and theoretical study of refractive index modification induced by femtosecond laser pulses in photorefractive crystals. The single pulses with central wavelength of 800 nm, pulse duration of 150 fs, and energy in the range of 6-130 nJ, tightly focused into the bulk of Fe-doped LiNbO3 and stoichiometric LiTaO3 crystals induce refractive index change of up to about 10(-3) within the volume of about (2.0 x 2.0 x 8.0) mu m(3). The photomodification is independent of the polarization orientation with respect to the crystalline c-axis. The recorded region can be erased optically by a defocused low-intensity single pulse of the same laser. Recording and erasure can be repeated at the same position many times without loss of quality. These findings demonstrate the basic functionality of the ultrafast three-dimensional all-optical rewritable memory. Theoretically they are interpreted by taking into account electron photogeneration and recombination as well as formation of a space-charge field. The presented analysis indicates dominant role of photovoltaic effect for our experimental conditions, and suggests methods for controlling various parameters of the photomodified regions.

DOI： 10.1117/12.759232

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記述言語：英語   掲載種別：論文集(書籍)内論文   出版者・発行元：SPRINGER-VERLAG BERLIN  

Optical techniques for three-dimensional micro- and nanostructuring of transparent and photo-sensitive materials are reviewed with emphasis on methods of manipulation of the optical field, such as beam focusing, the use of ultrashort pulses, and plasmonic and near-field effects. The linear and nonlinear optical response of materials to classical optical fields as well as exploitation of the advantages of quantum lithography are discussed.

DOI： 10.1007/12_2007_122

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

We report on excitation of photoluminescence via two-photon absorption (2PA) in dye-doped liquid crystal droplets using tightly focused cw-laser illumination at 1064nm wavelength. The photoluminescence of the 2PA dye C40H54N2O2 (MBAPB) dispersed inside the 7CB liquid crystal host increases as square of the laser tweezers' irradiance. The 2PA cross-section of MBAPB was measured by femtosecond Z-scan method. The polarization and temperature dependence of the photoluminescence corroborated the presence on the dye's molecular alignment inside the nonpolar liquid crystal host. The molecular alignment via the host-dye interaction can be used for the laser manipulation of micro-objects (e.g., doped liquid crystal droplets) in micro-fluidic/mechanical applications.

DOI： 10.1080/15421400802218785

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1063/1.2822825

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：OPTICAL SOC AMER  

Periodically corrugated chains of gold nanoblocks, fabricated with high precision by electron-beam lithography and lift-off techniques, were found to exhibit optical signatures of particle plasmon states in which relative contribution of longitudinal multipolar plasmons is significantly lower than that in equivalent rectangular gold nanorods. Plasmonic response of periodic chains is dominated by dipolar plasmon modes, which in the absence of multipolar exciations are seen as background-free and spectrally well-resolved extinction peaks at infrared (IR) wavelengths. This observation may help improve spectral parameters of IR plasmonic sub-wavelength antennae. Comparative studies of plasmon damping and dephasing in corrugated chains of nanoblocks and smooth rectangular nanorods are also presented. (C) 2007 Optical Society of America.

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